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Title: Oil/water/rock wettability: Influencing factors and implications for low salinity water flooding in carbonate reservoirs

Abstract

Wettability of the oil/brine/rock system is an essential petro-physical parameter which governs subsurface multiphase flow behaviour and the distribution of fluids, thus directly affecting oil recovery. Recent studies [1–3] show that manipulation of injected brine composition can enhance oil recovery by shifting wettability from oil-wet to water-wet. However, what factor(s) control system wettability has not been completely elucidated due to incomplete understanding of the geochemical system. To isolate and identify the key factors at play we used in this paper SO 4 2—free solutions to examine the effect of salinity (formation brine/FB, 10 times diluted formation brine/10 dFB, and 100 times diluted formation brine/100 dFB) on the contact angle of oil droplets at the surface of calcite. We then compared contact angle results with predictions of surface complexation by low salinity water using PHREEQC software. We demonstrate that the conventional dilution approach likely triggers an oil-wet system at low pH, which may explain why the low salinity water EOR-effect is not always observed by injecting low salinity water in carbonated reservoirs. pH plays a fundamental role in the surface chemistry of oil/brine interfaces, and wettability. Our contact angle results show that formation brine triggered a strong water-wet system (35°) atmore » pH 2.55, yet 100 times diluted formation brine led to a strongly oil-wet system (contact angle = 175°) at pH 5.68. Surface complexation modelling correctly predicted the wettability trend with salinity; the bond product sum ([>CaOH 2 +][–COO -] + [>CO 3 -][–NH +] + [>CO 3 -][–COOCa +]) increased with decreasing salinity. Finally, at pH < 6 dilution likely makes the calcite surface oil-wet, particularly for crude oils with high base number. Yet, dilution probably causes water wetness at pH > 7 for crude oils with high acid number.« less

Authors:
ORCiD logo [1]; ORCiD logo [1];  [2];  [3];  [2]
  1. Curtin Univ., Kensington, WA (Australia). Dept. of Petroleum Engineering; Southwest Petroleum Univ., Chengdu (China). State Key Lab. of Oil and Gas Reservoir Geology and Exploitation
  2. Curtin Univ., Kensington, WA (Australia). Dept. of Petroleum Engineering
  3. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Southwest Petroleum Univ., Chengdu (China); Curtin Univ., Kensington, WA (Australia)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA); Southwest Petroleum Univ. (China)
OSTI Identifier:
1421633
Report Number(s):
SAND2017-13621J
Journal ID: ISSN 0016-2361; PII: S0016236117312747
Grant/Contract Number:  
NA0003525; PLN201603
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Fuel
Additional Journal Information:
Journal Volume: 215; Journal ID: ISSN 0016-2361
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
02 PETROLEUM; 04 OIL SHALES AND TAR SANDS; low salinity water flooding; carbonate reservoirs; wettability; contact angle; surface complexation modelling

Citation Formats

Chen, Yongqiang, Xie, Quan, Sari, Ahmad, Brady, Patrick V., and Saeedi, Ali. Oil/water/rock wettability: Influencing factors and implications for low salinity water flooding in carbonate reservoirs. United States: N. p., 2017. Web. doi:10.1016/j.fuel.2017.10.031.
Chen, Yongqiang, Xie, Quan, Sari, Ahmad, Brady, Patrick V., & Saeedi, Ali. Oil/water/rock wettability: Influencing factors and implications for low salinity water flooding in carbonate reservoirs. United States. doi:10.1016/j.fuel.2017.10.031.
Chen, Yongqiang, Xie, Quan, Sari, Ahmad, Brady, Patrick V., and Saeedi, Ali. Tue . "Oil/water/rock wettability: Influencing factors and implications for low salinity water flooding in carbonate reservoirs". United States. doi:10.1016/j.fuel.2017.10.031.
@article{osti_1421633,
title = {Oil/water/rock wettability: Influencing factors and implications for low salinity water flooding in carbonate reservoirs},
author = {Chen, Yongqiang and Xie, Quan and Sari, Ahmad and Brady, Patrick V. and Saeedi, Ali},
abstractNote = {Wettability of the oil/brine/rock system is an essential petro-physical parameter which governs subsurface multiphase flow behaviour and the distribution of fluids, thus directly affecting oil recovery. Recent studies [1–3] show that manipulation of injected brine composition can enhance oil recovery by shifting wettability from oil-wet to water-wet. However, what factor(s) control system wettability has not been completely elucidated due to incomplete understanding of the geochemical system. To isolate and identify the key factors at play we used in this paper SO42—free solutions to examine the effect of salinity (formation brine/FB, 10 times diluted formation brine/10 dFB, and 100 times diluted formation brine/100 dFB) on the contact angle of oil droplets at the surface of calcite. We then compared contact angle results with predictions of surface complexation by low salinity water using PHREEQC software. We demonstrate that the conventional dilution approach likely triggers an oil-wet system at low pH, which may explain why the low salinity water EOR-effect is not always observed by injecting low salinity water in carbonated reservoirs. pH plays a fundamental role in the surface chemistry of oil/brine interfaces, and wettability. Our contact angle results show that formation brine triggered a strong water-wet system (35°) at pH 2.55, yet 100 times diluted formation brine led to a strongly oil-wet system (contact angle = 175°) at pH 5.68. Surface complexation modelling correctly predicted the wettability trend with salinity; the bond product sum ([>CaOH2+][–COO-] + [>CO3-][–NH+] + [>CO3-][–COOCa+]) increased with decreasing salinity. Finally, at pH < 6 dilution likely makes the calcite surface oil-wet, particularly for crude oils with high base number. Yet, dilution probably causes water wetness at pH > 7 for crude oils with high acid number.},
doi = {10.1016/j.fuel.2017.10.031},
journal = {Fuel},
number = ,
volume = 215,
place = {United States},
year = {Tue Nov 21 00:00:00 EST 2017},
month = {Tue Nov 21 00:00:00 EST 2017}
}

Journal Article:
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