Temperature Dependence of Uranium and Vanadium Adsorption on Amidoxime-Based Adsorbents in Natural Seawater

Kuo, Li-Jung; Gill, Gary A.; Tsouris, Costas; Rao, Linfeng; Pan, Horng-Bin; Wai, Chien M.; Janke, Christopher J.; Strivens, Jonathan E.; Wood, Jordana R.; Schlafer, Nicholas; D'Alessandro, Evan K.

doi:10.1002/slct.201701895

Title: Temperature Dependence of Uranium and Vanadium Adsorption on Amidoxime-Based Adsorbents in Natural Seawater

Journal Article · Tue Jan 16 00:00:00 EST 2018 · Chemistry Select

DOI:https://doi.org/10.1002/slct.201701895· OSTI ID:1421330

Kuo, Li-Jung ^[1]; Gill, Gary A. ^[1]; Tsouris, Costas ^[2]; Rao, Linfeng ^[3]; Pan, Horng-Bin ^[4]; Wai, Chien M. ^[4]; Janke, Christopher J. ^[2]; Strivens, Jonathan E. ^[1]; Wood, Jordana R. ^[1]; Schlafer, Nicholas ^[1]; D'Alessandro, Evan K. ^[5]

Marine Sciences Laboratory, Pacific Northwest National Laboratory, Sequim WA 98382 USA
Oak Ridge National Laboratory, Oak Ridge TN 37831 USA
Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley CA 94720 USA
Department of Chemistry, University of Idaho, Moscow ID 83844 USA
Rosensteil School of Marine and Atmospheric Chemistry, University of Miami, Miami FL 33149 USA

The apparent enthalpy and entropy of the complexation of uranium (VI) and vanadium (V) with amidoxime ligands grafted onto polyethylene fiber was determined using time series measurements of adsorption capacities in natural seawater at three different temperatures. The complexation of uranium was highly endothermic, while the complexation of vanadium showed minimal temperature sensitivity. Amidoxime-based polymeric adsorbents exhibit significantly increased uranium adsorption capacities and selectivity in warmer waters.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE)

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1421330

Report Number(s):: PNNL-SA-126070; AF5855000

Journal Information:: Chemistry Select, Vol. 3, Issue 2; ISSN 2365-6549

Publisher:: Wiley

Country of Publication:: United States

Language:: English

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A highly efficient uranium grabber derived from acrylic fiber for extracting uranium from seawater Pan, Horng-Bin; Wai, Chien M.; Kuo, Li-Jung Dalton Transactions, Vol. 49, Issue 9 https://doi.org/10.1039/c9dt04562g	journal	January 2020
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