Efficient Capture of Perrhenate and Pertechnetate by a Mesoporous Zr Metal–Organic Framework and Examination of Anion Binding Motifs

Drout, Riki J.; Otake, Kenichi; Howarth, Ashlee J.; Islamoglu, Timur; Zhu, Lin; Xiao, Chengliang; Wang, Shuao; Farha, Omar K.

doi:10.1021/acs.chemmater.7b04619

Title: Efficient Capture of Perrhenate and Pertechnetate by a Mesoporous Zr Metal–Organic Framework and Examination of Anion Binding Motifs

Journal Article · Wed Jan 10 00:00:00 EST 2018 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.7b04619· OSTI ID:1420780

Drout, Riki J. ^[1]; Otake, Kenichi ^[1]; Howarth, Ashlee J. ^[1]; Islamoglu, Timur ^[1]; Zhu, Lin ^[2]; Xiao, Chengliang ^[2]; Wang, Shuao ^[2]; Farha, Omar K. ^[3]

Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Soochow Univ., Suzhou (China). School of Radiological and Interdisciplinary Sciences (RAD-X); Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Suzhou (China)
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; King Abdulaziz Univ., Jeddah (Saudi Arabia). Dept. of Chemistry

At the Hanford Site in southeastern Washington state, the U.S. Department of Energy intends to treat 56 million gallons of legacy nuclear waste by encasing it in borosilicate glass via vitrification. This process ineffectively captures radioactive pertechnetate (TcO₄–) because of the ion’s volatility, thereby requiring a different remediation method for this long-lived (t_1/2 = 2.1 × 10⁵ years), environmentally mobile species. Currently available sorbents lack the desired combination of high uptake capacity, fast kinetics, and selectivity. Here, we evaluate the ability of the chemically and thermally robust Zr₆-based metal–organic framework (MOF), NU-1000, to capture perrhenate (ReO₄–), a pertechnetate simulant, and pertechnetate. Our material exhibits an excellent perrhenate uptake capacity of 210 mg/g, reaches saturation within 5 min, and maintains perrhenate uptake in the presence of competing anions. Additionally, experiments with pertechnetate confirm perrhenate is a suitable surrogate. Single-crystal X-ray diffraction indicates both chelating and nonchelating perrhenate binding motifs are present in both the small pore and the mesopore of NU-1000. Postadsorption diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) further elucidates the uptake mechanism and powder X-ray diffraction (PXRD) and Brunauer–Emmett–Teller (BET) surface area analysis confirm the retention of crystallinity and porosity of NU-1000 throughout adsorption.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Northwestern Univ., Evanston, IL (United States). Actinide Center of Excellence

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: NA0003763

OSTI ID:: 1420780

Journal Information:: Chemistry of Materials, Vol. 30, Issue 4; Related Information: The Supporting Information is available on the ACS Publications website at DOI: 10.1021/acs.chemmater.7b04619.Adsorption capacity data, PXRD patterns, nitrogen adsorption isotherms, and DRIFTS spectra (PDF)Crystallographic data (TXT); ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 108 works

Citation information provided by
Web of Science

References (58)

The biogeochemistry of technetium: A review of the behavior of an artificial element in the natural environment Icenhower, J. P.; Qafoku, N. P.; Zachara, J. M. American Journal of Science, Vol. 310, Issue 8 https://doi.org/10.2475/08.2010.02	journal	October 2010
The nature of the volatile technetium species formed during vitrification of borosilicate glass Childs, Bradley C.; Poineau, Frederic; Czerwinski, Kenneth R. Journal of Radioanalytical and Nuclear Chemistry, Vol. 306, Issue 2 https://doi.org/10.1007/s10967-015-4203-5	journal	May 2015
Chemistry of Technetium and Rhenium Species during Low-Level Radioactive Waste Vitrification Darab, John G.; Smith, Peter A. Chemistry of Materials, Vol. 8, Issue 5 https://doi.org/10.1021/cm950418+	journal	January 1996
Behavior of technetium in nuclear waste vitrification processes Pegg, Ian L. Journal of Radioanalytical and Nuclear Chemistry, Vol. 305, Issue 1 https://doi.org/10.1007/s10967-014-3900-9	journal	January 2015
Removal of TcO ₄ ⁻ ions from solution: materials and future outlook Banerjee, Debasis; Kim, Dongsang; Schweiger, Michael J. Chemical Society Reviews, Vol. 45, Issue 10 https://doi.org/10.1039/C5CS00330J	journal	January 2016
Development of Bifunctional Anion-Exchange Resins with Improved Selectivity and Sorptive Kinetics for Pertechnetate: Batch-Equilibrium Experiments Bonnesen, Peter V.; Brown, Gilbert M.; Alexandratos, Spiro D. Environmental Science & Technology, Vol. 34, Issue 17 https://doi.org/10.1021/es990858s	journal	September 2000
Rhenium(VII) and technetium(VII) separation from aqueous solutions using a polyethylenimine–epichlorohydrin resin Sarri, S.; Misaelides, P.; Zamboulis, D. Journal of Radioanalytical and Nuclear Chemistry, Vol. 307, Issue 1 https://doi.org/10.1007/s10967-015-4213-3	journal	May 2015
Reductive Immobilization of Rhenium in Soil and Groundwater Using Pyrite Nanoparticles Ding, Qingwei; Ding, Feng; Qian, Tianwei Water, Air, & Soil Pollution, Vol. 226, Issue 12 https://doi.org/10.1007/s11270-015-2588-y	journal	November 2015
Perrhenate sorption kinetics in zerovalent iron in high pH and nitrate media Lenell, Brian A.; Arai, Yuji Journal of Hazardous Materials, Vol. 321 https://doi.org/10.1016/j.jhazmat.2016.09.024	journal	January 2017
Inorganic tin aluminophosphate nanocomposite for reductive separation of pertechnetate Levitskaia, Tatiana G.; Chatterjee, Sayandev; Pence, Natasha K. Environmental Science: Nano, Vol. 3, Issue 5 https://doi.org/10.1039/C6EN00130K	journal	January 2016
Reductive immobilization of Re(VII) by graphene modified nanoscale zero-valent iron particles using a plasma technique Li, Jie; Chen, Changlun; Zhang, Rui Science China Chemistry, Vol. 59, Issue 1 https://doi.org/10.1007/s11426-015-5452-4	journal	November 2015
Removal of TcO ₄ ^– from Representative Nuclear Waste Streams with Layered Potassium Metal Sulfide Materials Neeway, James J.; Asmussen, R. Matthew; Lawter, Amanda R. Chemistry of Materials, Vol. 28, Issue 11 https://doi.org/10.1021/acs.chemmater.6b01296	journal	May 2016
Molecular recognition of pertechnetate and perrhenate Katayev, Evgeny A.; Kolesnikov, Grigory V.; Sessler, Jonathan L. Chemical Society Reviews, Vol. 38, Issue 6 https://doi.org/10.1039/b806468g	journal	January 2009
Removal of Pertechnetate-Related Oxyanions from Solution Using Functionalized Hierarchical Porous Frameworks Banerjee, Debasis; Elsaidi, Sameh K.; Aguila, Briana Chemistry - A European Journal, Vol. 22, Issue 49 https://doi.org/10.1002/chem.201603908	journal	October 2016
Zirconium-Based Metal–Organic Framework for Removal of Perrhenate from Water Banerjee, Debasis; Xu, Wenqian; Nie, Zimin Inorganic Chemistry, Vol. 55, Issue 17 https://doi.org/10.1021/acs.inorgchem.6b01004	journal	August 2016
Reversible, Selective Trapping of Perchlorate from Water in Record Capacity by a Cationic Metal–Organic Framework Colinas, Ian R.; Silva, Rachel C.; Oliver, Scott R. J. Environmental Science & Technology, Vol. 50, Issue 4 https://doi.org/10.1021/acs.est.5b03455	journal	January 2016
A Water-Stable Cationic Metal-Organic Framework as a Dual Adsorbent of Oxoanion Pollutants Desai, Aamod V.; Manna, Biplab; Karmakar, Avishek Angewandte Chemie International Edition, Vol. 55, Issue 27 https://doi.org/10.1002/anie.201600185	journal	February 2016
Postsynthetic Tuning of Metal–Organic Frameworks for Targeted Applications Islamoglu, Timur; Goswami, Subhadip; Li, Zhanyong Accounts of Chemical Research, Vol. 50, Issue 4 https://doi.org/10.1021/acs.accounts.6b00577	journal	February 2017
Efficient and Selective Uptake of TcO ₄ ^– by a Cationic Metal–Organic Framework Material with Open Ag ⁺ Sites Sheng, Daopeng; Zhu, Lin; Xu, Chao Environmental Science & Technology, Vol. 51, Issue 6 https://doi.org/10.1021/acs.est.7b00339	journal	March 2017
Identifying the Recognition Site for Selective Trapping of ⁹⁹ TcO ₄ ^– in a Hydrolytically Stable and Radiation Resistant Cationic Metal–Organic Framework Zhu, Lin; Sheng, Daopeng; Xu, Chao Journal of the American Chemical Society, Vol. 139, Issue 42 https://doi.org/10.1021/jacs.7b08632	journal	October 2017
Application of layered double hydroxides for removal of oxyanions: A review Goh, Kok-Hui; Lim, Teik-Thye; Dong, Zhili Water Research, Vol. 42, Issue 6-7 https://doi.org/10.1016/j.watres.2007.10.043	journal	March 2008
Enhanced immobilization of ReO4− by nanoscale zerovalent iron supported on layered double hydroxide via an advanced XAFS approach: Implications for TcO4− sequestration Sheng, Guodong; Tang, Yanna; Linghu, Wensheng Applied Catalysis B: Environmental, Vol. 192 https://doi.org/10.1016/j.apcatb.2016.04.001	journal	September 2016
Design and synthesis of an exceptionally stable and highly porous metal-organic framework Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe Nature, Vol. 402, Issue 6759, p. 276-279 https://doi.org/10.1038/46248	journal	November 1999
Introduction to Metal–Organic Frameworks Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M. Chemical Reviews, Vol. 112, Issue 2, p. 673-674 https://doi.org/10.1021/cr300014x	journal	September 2011
Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit? Farha, Omar K.; Eryazici, Ibrahim; Jeong, Nak Cheon Journal of the American Chemical Society, Vol. 134, Issue 36, p. 15016-15021 https://doi.org/10.1021/ja3055639	journal	August 2012
Chemical, thermal and mechanical stabilities of metal–organic frameworks Howarth, Ashlee J.; Liu, Yangyang; Li, Peng Nature Reviews Materials, Vol. 1, Issue 3 https://doi.org/10.1038/natrevmats.2015.18	journal	February 2016
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel Science, Vol. 295, Issue 5554, p. 469-472 https://doi.org/10.1126/science.1067208	journal	January 2002
Hydrogen storage in metal–organic frameworks Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R. Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314 https://doi.org/10.1039/b802256a	journal	January 2009
Carbon Dioxide Capture in Metal–Organic Frameworks Sumida, Kenji; Rogow, David L.; Mason, Jarad A. Chemical Reviews, Vol. 112, Issue 2, p. 724-781 https://doi.org/10.1021/cr2003272	journal	September 2011
Selective gas adsorption and separation in metal–organic frameworks Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504 https://doi.org/10.1039/b802426j	journal	January 2009
Metal–organic framework materials as catalysts Lee, JeongYong; Farha, Omar K.; Roberts, John Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459 https://doi.org/10.1039/b807080f	journal	January 2009
Porous metal–organic-framework nanoscale carriers as a potential platform for drug delivery and imaging Horcajada, Patricia; Chalati, Tamim; Serre, Christian Nature Materials, Vol. 9, Issue 2 https://doi.org/10.1038/nmat2608	journal	December 2009
Metal–Organic Framework Materials as Chemical Sensors Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K. Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125 https://doi.org/10.1021/cr200324t	journal	September 2011
Metal–organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents Bobbitt, N. Scott; Mendonca, Matthew L.; Howarth, Ashlee J. Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/C7CS00108H	journal	January 2017
Metal–organic frameworks for applications in remediation of oxyanion/cation-contaminated water Howarth, Ashlee J.; Liu, Yangyang; Hupp, Joseph T. CrystEngComm, Vol. 17, Issue 38 https://doi.org/10.1039/C5CE01428J	journal	January 2015
The dual capture of As ^V and As ^III by UiO-66 and analogues Audu, Cornelius O.; Nguyen, Huong Giang T.; Chang, Chih-Yi Chemical Science, Vol. 7, Issue 10 https://doi.org/10.1039/C6SC00490C	journal	January 2016
Are Zr ₆ -based MOFs water stable? Linker hydrolysis vs. capillary-force-driven channel collapse Mondloch, Joseph E.; Katz, Michael J.; Planas, Nora Chemical Communications, Vol. 50, Issue 64 https://doi.org/10.1039/C4CC02401J	journal	January 2014
Water-Stable Zirconium-Based Metal-Organic Framework Material with High-Surface Area and Gas-Storage Capacities Gutov, Oleksii V.; Bury, Wojciech; Gomez-Gualdron, Diego A. Chemistry - A European Journal, Vol. 20, Issue 39 https://doi.org/10.1002/chem.201402895	journal	August 2014
High Efficiency Adsorption and Removal of Selenate and Selenite from Water Using Metal–Organic Frameworks Howarth, Ashlee J.; Katz, Michael J.; Wang, Timothy C. Journal of the American Chemical Society, Vol. 137, Issue 23 https://doi.org/10.1021/jacs.5b03904	journal	June 2015
Efficient extraction of sulfate from water using a Zr-metal–organic framework Howarth, Ashlee J.; Wang, Timothy C.; Al-Juaid, Salih S. Dalton Transactions, Vol. 45, Issue 1 https://doi.org/10.1039/C5DT04163E	journal	January 2016
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297 https://doi.org/10.1021/ja4050828	journal	May 2013
Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000 Wang, Timothy C.; Vermeulen, Nicolaas A.; Kim, In Soo Nature Protocols, Vol. 11, Issue 1 https://doi.org/10.1038/nprot.2016.001	journal	December 2015
Crystal structure determination and refinement via SIR2014 Burla, Maria Cristina; Caliandro, Rocco; Carrozzini, Benedetta Journal of Applied Crystallography, Vol. 48, Issue 1 https://doi.org/10.1107/S1600576715001132	journal	January 2015
Crystal structure refinement with SHELXL Sheldrick, George M. Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053229614024218	journal	January 2015
Docosahexaenoic Acid Ethyl Ester Enhances 6-Hydroxydopamine-Induced Neuronal Damage by Induction of Lipid Peroxidation in Mouse Striatum Kabuto, Hideaki; Amakawa, Masao; Mankura, Mitsumasa Neurochemical Research, Vol. 34, Issue 7 https://doi.org/10.1007/s11064-008-9909-0	journal	February 2009
Structure validation in chemical crystallography Spek, Anthony L. Acta Crystallographica Section D Biological Crystallography, Vol. 65, Issue 2, p. 148-155 https://doi.org/10.1107/S090744490804362X	journal	January 2009
Organic modification of bentonite and its application for perrhenate (an analogue of pertechnetate) removal from aqueous solution Yaming, Li; Mingliang, Bi; Zhipeng, Wang Journal of the Taiwan Institute of Chemical Engineers, Vol. 62 https://doi.org/10.1016/j.jtice.2016.01.018	journal	May 2016
Synthesis and Host−Guest Properties of Multi-Crown Dendrimers towards Sodium Pertechnetate and Mercury(II) Chloride Stephan, Holger; Spies, Hartmut; Johannsen, Bernd European Journal of Inorganic Chemistry, Vol. 2001, Issue 11 https://doi.org/10.1002/1099-0682(200111)2001:11<2957::AID-EJIC2957>3.0.CO;2-Y	journal	November 2001
A New Paradigm for Anion Trapping in High Capacity and Selectivity: Crystal-to-Crystal Transformation of Cationic Materials Fei, Honghan; Bresler, Marc R.; Oliver, Scott R. J. Journal of the American Chemical Society, Vol. 133, Issue 29 https://doi.org/10.1021/ja204577p	journal	July 2011
Exceptional Perrhenate/Pertechnetate Uptake and Subsequent Immobilization by a Low-Dimensional Cationic Coordination Polymer: Overcoming the Hofmeister Bias Selectivity Zhu, Lin; Xiao, Chengliang; Dai, Xing Environmental Science & Technology Letters, Vol. 4, Issue 7 https://doi.org/10.1021/acs.estlett.7b00165	journal	May 2017
A new imidazolium-based polymeric ionic liquid gel with high adsorption capacity for perrhenate Han, Dong; Li, Xingxiao; Peng, Jing RSC Advances, Vol. 6, Issue 73 https://doi.org/10.1039/C6RA12239F	journal	January 2016
NDTB-1: A Supertetrahedral Cationic Framework That Removes TcO ₄ ⁻ from Solution Wang, Shuao; Alekseev, Evgeny V.; Diwu, Juan Angewandte Chemie International Edition, Vol. 49, Issue 6 https://doi.org/10.1002/anie.200906397	journal	February 2010
Selectivity, Kinetics, and Efficiency of Reversible Anion Exchange with TcO4− in a Supertetrahedral Cationic Framework Wang, Shuao; Yu, Ping; Purse, Bryant A. Advanced Functional Materials, Vol. 22, Issue 11 https://doi.org/10.1002/adfm.201103081	journal	March 2012
Removal of Pertechnetate from Simulated Nuclear Waste Streams Using Supported Zerovalent Iron Darab, John G.; Amonette, Alexandra B.; Burke, Deborah S. D. Chemistry of Materials, Vol. 19, Issue 23 https://doi.org/10.1021/cm0607379	journal	November 2007
Compositional and structural control on anion sorption capability of layered double hydroxides (LDHs) Wang, Yifeng; Gao, Huizhen Journal of Colloid and Interface Science, Vol. 301, Issue 1 https://doi.org/10.1016/j.jcis.2006.04.061	journal	September 2006
Chalcogen-Based Aerogels As Sorbents for Radionuclide Remediation Riley, Brian J.; Chun, Jaehun; Um, Wooyong Environmental Science & Technology, Vol. 47, Issue 13 https://doi.org/10.1021/es400595z	journal	June 2013
Porous Zr2SC-carbon composite microspheres: Possible radiation tolerant sorbents and transmutation hosts for technetium-99 Scales, Nicholas; Chen, Jun; Aughterson, Robert D. Microporous and Mesoporous Materials, Vol. 259 https://doi.org/10.1016/j.micromeso.2017.09.033	journal	March 2018
Detoxification of a Sulfur Mustard Simulant Using a BODIPY-Functionalized Zirconium-Based Metal–Organic Framework Atilgan, Ahmet; Islamoglu, Timur; Howarth, Ashlee J. ACS Applied Materials & Interfaces, Vol. 9, Issue 29 https://doi.org/10.1021/acsami.7b05494	journal	July 2017

Cited By (11)

High Uptake of ReO ₄ ⁻ and CO ₂ Conversion by a Radiation‐Resistant Thorium–Nickle [Th ₄₈ Ni ₆ ] Nanocage‐Based Metal–Organic Framework Xu, Hang; Cao, Chun‐Shuai; Hu, Han‐Shi Angewandte Chemie, Vol. 131, Issue 18 https://doi.org/10.1002/ange.201901786	journal	April 2019
Successful Decontamination of ⁹⁹ TcO ₄ ⁻ in Groundwater at Legacy Nuclear Sites by a Cationic Metal‐Organic Framework with Hydrophobic Pockets Sheng, Daopeng; Zhu, Lin; Dai, Xing Angewandte Chemie, Vol. 131, Issue 15 https://doi.org/10.1002/ange.201814640	journal	March 2019
Successful Decontamination of ⁹⁹ TcO ₄ ⁻ in Groundwater at Legacy Nuclear Sites by a Cationic Metal-Organic Framework with Hydrophobic Pockets Sheng, Daopeng; Zhu, Lin; Dai, Xing Angewandte Chemie International Edition, Vol. 58, Issue 15 https://doi.org/10.1002/anie.201814640	journal	March 2019
Optimizing radionuclide sequestration in anion nanotraps with record pertechnetate sorption Sun, Qi; Zhu, Lin; Aguila, Briana Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09630-y	journal	April 2019
Synthesis of novel nanomaterials and their application in efficient removal of radionuclides Wang, Xiangxue; Chen, Long; Wang, Lin Science China Chemistry, Vol. 62, Issue 8 https://doi.org/10.1007/s11426-019-9492-4	journal	June 2019
Green applications of metal–organic frameworks Ajoyan, Zvart; Marino, Paola; Howarth, Ashlee J. CrystEngComm, Vol. 20, Issue 39 https://doi.org/10.1039/c8ce01002a	journal	January 2018
Selective and efficient removal of perrhenate by an imidazolium based hexapodal receptor in water medium Ghosh, Rajib; Ghosh, Tamal Kanti; Ghosh, Pradyut Dalton Transactions, Vol. 49, Issue 10 https://doi.org/10.1039/d0dt00365d	journal	January 2020
A Ca ²⁺ MOF combining highly efficient sorption and capability for voltammetric determination of heavy metal ions in aqueous media Pournara, Anastasia D.; Margariti, Antigoni; Tarlas, Georgios D. Journal of Materials Chemistry A, Vol. 7, Issue 25 https://doi.org/10.1039/c9ta03337h	journal	January 2019
Efficient extraction of inorganic selenium from water by a Zr metal–organic framework: investigation of volumetric uptake capacity and binding motifs Drout, Riki J.; Howarth, Ashlee J.; Otake, Ken-ichi CrystEngComm, Vol. 20, Issue 40 https://doi.org/10.1039/c8ce00992a	journal	January 2018
Atomic‐ and Molecular‐Level Design of Functional Metal–Organic Frameworks (MOFs) and Derivatives for Energy and Environmental Applications Yilmaz, Gamze; Peh, Shing Bo; Zhao, Dan Advanced Science, Vol. 6, Issue 21 https://doi.org/10.1002/advs.201901129	journal	August 2019
High Uptake of ReO ₄ ⁻ and CO ₂ Conversion by a Radiation-Resistant Thorium-Nickle [Th ₄₈ Ni ₆ ] Nanocage-Based Metal-Organic Framework Xu, Hang; Cao, Chun-Shuai; Hu, Han-Shi Angewandte Chemie International Edition, Vol. 58, Issue 18 https://doi.org/10.1002/anie.201901786	journal	March 2019

Similar Records

Pertechnetate/perrhenate–capped Zr/Hf–Dihydroxide Dimers: Elucidating Zr–TcO₄ Co–Mobility in the Nuclear Fuel Cycle

Journal Article · Mon Dec 18 00:00:00 EST 2023 · Chemistry - A European Journal · OSTI ID:1420780

Shohel, Mohammad; Bustos, Jenna; Roseborough, Alexander; +1 more

Elucidating Actinide–Pertechnetate and Actinide–Perrhenate Bonding via a Family of Th–TcO₄ and Th–ReO₄ Frameworks and Solutions

Journal Article · Wed Jun 21 00:00:00 EDT 2023 · Inorganic Chemistry · OSTI ID:1420780

Shohel, Mohammad; Bustos, Jenna; Stroscio, Gautam D.; +2 more

Exploiting π–π Interactions to Design an Efficient Sorbent for Atrazine Removal from Water

Journal Article · Fri Feb 01 00:00:00 EST 2019 · ACS Applied Materials and Interfaces · OSTI ID:1420780

Akpinar, Isil; Drout, Riki J.; Islamoglu, Timur; +3 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
metal-organic framework
capture
perrhenate
pertechnetate

Title: Efficient Capture of Perrhenate and Pertechnetate by a Mesoporous Zr Metal–Organic Framework and Examination of Anion Binding Motifs

Citation Formats

References (58)

Cited By (11)

Linked Research (1)

Similar Records

Related Subjects