The Solid Flame Phenomenon: A Novel Perspective

Mukasyan, Alexander S.; Shuck, Christopher E.; Pauls, Joshua M.; Manukyan, Khachatur V.; Moskovskikh, Dmitry O.; Rogachev, Alexander S.

doi:10.1002/adem.201701065

The Solid Flame Phenomenon: A Novel Perspective

Journal Article · Mon Feb 12 00:00:00 EST 2018 · Advanced Engineering Materials

DOI:https://doi.org/10.1002/adem.201701065· OSTI ID:1420187

Mukasyan, Alexander S. ^[1]; Shuck, Christopher E. ^[1]; Pauls, Joshua M. ^[1]; Manukyan, Khachatur V. ^[2]; Moskovskikh, Dmitry O. ^[3]; Rogachev, Alexander S. ^[4]

Department of Chemical and Biomolecular Engineering University of Notre Dame Notre Dame IN 46556 USA
Department of Physics University of Notre Dame Notre Dame IN 46556 USA
National University of Science and Technology MISiS Moscow 119049 Russia
National University of Science and Technology MISiS Moscow 119049 Russia, Merzhanov Institute of Structural Macrokinetics Russian Academy of Sciences Chernogolovka Moscow Region 142342 Russia

In this paper, the authors overview previous publications and present novel results related to self‐sustained solid‐state reactions: the solid flame. Due to recent advances in the fabrication of nano‐structured reactive media, this phenomenon, which is first reported fifty years ago, has found a new perspective for a wide variety of exothermic systems. These fundamental findings permit novel routes for synthesis of advanced engineering materials with controlled microstructure, as well as for design of high‐energy density systems with tuned parameters for energy release.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: NA0002377

OSTI ID:: 1420187

Alternate ID(s):: OSTI ID: 1537339

Journal Information:: Advanced Engineering Materials, Journal Name: Advanced Engineering Materials Journal Issue: 8 Vol. 20; ISSN 1438-1656

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (32)

Principles of combustion of tantalum-carbon mixtures Shkiro, V. M.; Nersisyan, G. A.; Borovinskaya, I. P. Combustion, Explosion, and Shock Waves, Vol. 14, Issue 4 https://doi.org/10.1007/BF00742950	journal	July 1978
The role of gas-phase transport in combustion of the tantalum-carbon system Merzhanov, A. G.; Rogachev, A. S.; Mukas'yan, A. S. Journal of Engineering Physics, Vol. 59, Issue 1 https://doi.org/10.1007/BF00871314	journal	July 1990
Die Dreistoffe: Titan—Bor—Kohlenstoff und Titan—Bor—Stickstoff Nowotny, H.; Benesovsky, F.; Brukl, C. Monatshefte für Chemie und verwandte Teile anderer Wissenschaften, Vol. 92, Issue 2 https://doi.org/10.1007/BF01153899	journal	March 1961
The N-Ti (Nitrogen-Titanium) system Wriedt, H. A.; Murray, J. L. Bulletin of Alloy Phase Diagrams, Vol. 8, Issue 4 https://doi.org/10.1007/BF02869274	journal	August 1987
Combustion of heterogeneous nanostructural systems (Review) Rogachev, A. S.; Mukasyan, A. S. Combustion, Explosion, and Shock Waves, Vol. 46, Issue 3 https://doi.org/10.1007/s10573-010-0036-2	journal	May 2010
Combustion synthesis: mechanically induced nanostructured materials Mukasyan, Alexander S.; Rogachev, Alexander S. Journal of Materials Science, Vol. 52, Issue 20 https://doi.org/10.1007/s10853-017-1075-9	journal	April 2017
The diffusivity of carbon in silicon Newman, R. C.; Wakefield, J. Journal of Physics and Chemistry of Solids, Vol. 19, Issue 3-4 https://doi.org/10.1016/0022-3697(61)90032-4	journal	May 1961
Electrotransport of carbon in niobium and tantalum Schmidt, F. A.; Carlson, O. N. Journal of the Less Common Metals, Vol. 26, Issue 2 https://doi.org/10.1016/0022-5088(72)90044-6	journal	February 1972
Self-sustaining reactions induced by ball milling Takacs, Laszlo Progress in Materials Science, Vol. 47, Issue 4 https://doi.org/10.1016/S0079-6425(01)00002-0	journal	January 2002
Structure evolution and reaction mechanism in the Ni/Al reactive multilayer nanofoils Rogachev, A. S.; Vadchenko, S. G.; Baras, F. Acta Materialia, Vol. 66 https://doi.org/10.1016/j.actamat.2013.11.045	journal	March 2014
The role of fracture in the impact initiation of Ni-Al intermetallic composite reactives during dynamic loading Beason, M. T.; Gunduz, I. E.; Son, S. F. Acta Materialia, Vol. 133 https://doi.org/10.1016/j.actamat.2017.05.042	journal	July 2017
Combustion synthesis and characterization of TaC, TaC/TaSi2, and TaC/TaB nanoparticles Lee, Young-Jun; Kim, Seung Hyun; Lee, Tae-Hyuk Chemical Engineering Science, Vol. 107 https://doi.org/10.1016/j.ces.2013.12.015	journal	April 2014
Solid-flame: Experimental validation Shuck, Christopher E.; Manukyan, Khachatur V.; Rouvimov, Sergei Combustion and Flame, Vol. 163 https://doi.org/10.1016/j.combustflame.2015.10.025	journal	January 2016
Formation of NiAl intermetallic by gradual and explosive exothermic reaction mechanism during ball milling Moshksar, M. M.; Mirzaee, M. Intermetallics, Vol. 12, Issue 12 https://doi.org/10.1016/j.intermet.2004.03.018	journal	December 2004
Combustion synthesis of tantalum carbides TaC and Ta2C Yeh, C. L.; Liu, E. W. Journal of Alloys and Compounds, Vol. 415, Issue 1-2 https://doi.org/10.1016/j.jallcom.2005.07.058	journal	May 2006
Milling criteria for the synthesis of nanocrystalline NiAl by mechanical alloying Joardar, J.; Pabi, S. K.; Murty, B. S. Journal of Alloys and Compounds, Vol. 429, Issue 1-2 https://doi.org/10.1016/j.jallcom.2006.04.045	journal	February 2007
Influence of the high energy ball milling on structure and reactivity of the Ni+Al powder mixture Rogachev, A. S.; Shkodich, N. F.; Vadchenko, S. G. Journal of Alloys and Compounds, Vol. 577 https://doi.org/10.1016/j.jallcom.2013.06.114	journal	November 2013
Spark plasma sintering of SiC powders produced by different combustion synthesis routes Moskovskikh, Dmitry O.; Lin, Ya-Cheng; Rogachev, Alexander S. Journal of the European Ceramic Society, Vol. 35, Issue 2 https://doi.org/10.1016/j.jeurceramsoc.2014.09.014	journal	February 2015
Dynamics of phase transformation during thermal explosion in the Al–Ni system: Influence of mechanical activation Mukasyan, A. S.; White, J. D. E.; Kovalev, D. Y. Physica B: Condensed Matter, Vol. 405, Issue 2 https://doi.org/10.1016/j.physb.2009.10.001	journal	January 2010
Reactive Ni/Al Nanocomposites: Structural Characteristics and Activation Energy Shuck, Christopher E.; Mukasyan, Alexander S. The Journal of Physical Chemistry A, Vol. 121, Issue 6 https://doi.org/10.1021/acs.jpca.6b12314	journal	February 2017
Ni/Al Energetic Nanocomposites and the Solid Flame Phenomenon Shuck, Christopher E.; Pauls, Joshua M.; Mukasyan, Alexander S. The Journal of Physical Chemistry C, Vol. 120, Issue 47 https://doi.org/10.1021/acs.jpcc.6b09754	journal	November 2016
Thermal and Impact Reaction Initiation in Ni/Al Heterogeneous Reactive Systems Reeves, Robert V.; Mukasyan, Alexander S.; Son, Steven F. The Journal of Physical Chemistry C, Vol. 114, Issue 35 https://doi.org/10.1021/jp104686z	journal	August 2010
Tailored Reactivity of Ni+Al Nanocomposites: Microstructural Correlations Manukyan, Khachatur V.; Mason, B. Aaron; Groven, Lori J. The Journal of Physical Chemistry C, Vol. 116, Issue 39 https://doi.org/10.1021/jp303407e	journal	September 2012
Thermal Explosion in Al−Ni System: Influence of Mechanical Activation White, Jeremiah D. E.; Reeves, Robert V.; Son, Steven F. The Journal of Physical Chemistry A, Vol. 113, Issue 48 https://doi.org/10.1021/jp905175c	journal	December 2009
Ignition dynamics and activation energies of metallic thermites: From nano- to micron-scale particulate composites Hunt, Emily M.; Pantoya, Michelle L. Journal of Applied Physics, Vol. 98, Issue 3, Article No. 034909 https://doi.org/10.1063/1.1990265	journal	August 2005
Mechanochemistry and mechanical activation of solids Boldyrev, Vladimir V. Russian Chemical Reviews, Vol. 75, Issue 3 https://doi.org/10.1070/RC2006v075n03ABEH001205	journal	March 2006
Solid Flames: Discoveries, Concepts, and Horizons of Cognition Merzhanov, A. G. Combustion Science and Technology, Vol. 98, Issue 4-6 https://doi.org/10.1080/00102209408935417	journal	July 1994
X-ray nanotomography and focused-ion-beam sectioning for quantitative three-dimensional analysis of nanocomposites Shuck, Christopher E.; Frazee, Mathew; Gillman, Andrew Journal of Synchrotron Radiation, Vol. 23, Issue 4 https://doi.org/10.1107/S1600577516007992	journal	June 2016
Catalytically Assisted Self-Propagating High-Temperature Synthesis of Tantalum Carbide Powders Kim, Troy; Wooldridge, Margaret S. Journal of the American Ceramic Society, Vol. 84, Issue 5 https://doi.org/10.1111/j.1151-2916.2001.tb00777.x	journal	May 2001
Direct Combustion Synthesis of Silicon Carbide Nanopowder from the Elements Mukasyan, Alexander S.; Lin, Ya-Cheng; Rogachev, Alexander S. Journal of the American Ceramic Society, Vol. 96, Issue 1 https://doi.org/10.1111/jace.12107	journal	December 2012
Self-propagating high-temperature synthesis of silicon carbide nanopowders Moskovskikh, D. O.; Mukasyan, A. S.; Rogachev, A. S. Doklady Physical Chemistry, Vol. 449, Issue 1 https://doi.org/10.1134/S0012501613030032	journal	March 2013
A time-resolved diffraction study of the Ta–C solid combustion system Larson, E. M.; Wong, Joe; Holt, J. B. Journal of Materials Research, Vol. 8, Issue 7 https://doi.org/10.1557/JMR.1993.1533	journal	July 1993

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