Exchange Bias Effects in Iron Oxide-Based Nanoparticle Systems

Phan, Manh-Huong; Alonso, Javier; Khurshid, Hafsa; Lampen-Kelley, Paula; Chandra, Sayan; Stojak Repa, Kristen; Nemati, Zohreh; Das, Raja; Iglesias, Óscar; Srikanth, Hariharan

doi:10.3390/nano6110221

Title: Exchange Bias Effects in Iron Oxide-Based Nanoparticle Systems

Journal Article · Wed Nov 23 00:00:00 EST 2016 · Nanomaterials

DOI:https://doi.org/10.3390/nano6110221· OSTI ID:1419687

Phan, Manh-Huong; Alonso, Javier; Khurshid, Hafsa; Lampen-Kelley, Paula; Chandra, Sayan; Stojak Repa, Kristen; Nemati, Zohreh; Das, Raja; Iglesias, Óscar; Srikanth, Hariharan

The exploration of exchange bias (EB) on the nanoscale provides a novel approach to improving the anisotropic properties of magnetic nanoparticles for prospective applications in nanospintronics and nanomedicine. However, the physical origin of EB is not fully understood. Recent advances in chemical synthesis provide a unique opportunity to explore EB in a variety of iron oxide-based nanostructures ranging from core/shell to hollow and hybrid composite nanoparticles. Experimental and atomistic Monte Carlo studies have shed light on the roles of interface and surface spins in these nanosystems. This review paper aims to provide a thorough understanding of the EB and related phenomena in iron oxide-based nanoparticle systems, knowledge of which is essential to tune the anisotropic magnetic properties of exchange-coupled nanoparticle systems for potential applications.

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Research Organization:: Univ. of South Florida, Tampa, FL (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-07ER46438

OSTI ID:: 1419687

Alternate ID(s):: OSTI ID: 1361639

Journal Information:: Nanomaterials, Journal Name: Nanomaterials Vol. 6 Journal Issue: 12; ISSN 2079-4991

Publisher:: MDPI AGCopyright Statement

Country of Publication:: Switzerland

Language:: English

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Cited by: 110 works

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Role of surface disorder on the magnetic properties and hysteresis of nanoparticles Iglesias, Òscar; Labarta, Amı́lcar Physica B: Condensed Matter, Vol. 343, Issue 1-4 https://doi.org/10.1016/j.physb.2003.08.109	journal	January 2004
Exchange bias of <mml:math altimg="si0008.gif" overflow="scroll" xmlns:xocs="http://www.elsevier.com/xml/xocs/dtd" xmlns:xs="http://www.w3.org/2001/XMLSchema" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://www.elsevier.com/xml/ja/dtd" xmlns:ja="http://www.elsevier.com/xml/ja/dtd" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:tb="http://www.elsevier.com/xml/common/table/dtd" xmlns:sb="http://www.elsevier.com/xml/common/struct-bib/dtd" xmlns:ce="http://www.elsevier.com/xml/common/dtd" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:cals="http://www.elsevier.com/xml/common/cals/dtd" xmlns:sa="http://www.elsevier.com/xml/common/struct-aff/dtd"><mml:msub><mml:mrow><mml:mi>MnFe</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mn>4</mml:mn></mml:mrow></mml:msub><mml:mo>@</mml:mo><mml:mi>γ</mml:mi><mml:msub><mml:mrow><mml:mi>Fe</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:math> and <mml:math altimg="si0009.gif" overflow="scroll" xmlns:xocs="http://www.elsevier.com/xml/xocs/dtd" xmlns:xs="http://www.w3.org/2001/XMLSchema" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://www.elsevier.com/xml/ja/dtd" xmlns:ja="http://www.elsevier.com/xml/ja/dtd" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:tb="http://www.elsevier.com/xml/common/table/dtd" xmlns:sb="http://www.elsevier.com/xml/common/struct-bib/dtd" xmlns:ce="http://www.elsevier.com/xml/common/dtd" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:cals="http://www.elsevier.com/xml/common/cals/dtd" xmlns:sa="http://www.elsevier.com/xml/common/struct-aff/dtd"><mml:msub><mml:mrow><mml:mi>CoFe</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mn>4</mml:mn></mml:mrow></mml:msub><mml:mo>@</mml:mo><mml:mi>γ</mml:mi><mml:msub><mml:mrow><mml:mi>Fe</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:math> core/shell nanoparticles Cabreira-Gomes, R.; G. Silva, F.; Aquino, R. Journal of Magnetism and Magnetic Materials, Vol. 368 https://doi.org/10.1016/j.jmmm.2014.03.003	journal	November 2014
Electronic Conduction of Magnetite (Fe3O4) and its Transition Point at Low Temperatures Verwey, E. J. W. Nature, Vol. 144, Issue 3642 https://doi.org/10.1038/144327b0	journal	August 1939

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Strong interfacial coupling through exchange interactions in soft/hard core–shell nanoparticles as a function of cationic distribution Sartori, Kevin; Cotin, Geoffrey; Bouillet, Corinne Nanoscale, Vol. 11, Issue 27 https://doi.org/10.1039/c9nr02323b	journal	January 2019
Role of spin disorder in magnetic and EMI shielding properties of Fe3O4/C/PPy core/shell composites Shukla, Vineeta Journal of Materials Science, Vol. 55, Issue 7 https://doi.org/10.1007/s10853-019-04198-w	journal	November 2019
Laser Ablation Synthesis, Structure, and Exchange Bias of Mn4C/MnO Powders Yao, Lu-Lu; Si, Ping-Zhan; Ge, Hong-Liang Journal of Electronic Materials, Vol. 48, Issue 3 https://doi.org/10.1007/s11664-018-6604-z	journal	August 2018
Readiness of Magnetic Nanobiosensors for Point-of-Care Commercialization Denmark, Daniel J.; Bustos-Perez, Xiomar; Swain, Anand Journal of Electronic Materials, Vol. 48, Issue 8 https://doi.org/10.1007/s11664-019-07275-7	journal	May 2019
Investigation of metallic nanoparticles adsorbed on the QCM sensor by SEM and AFM techniques Bucurica, Ioan Alin; Popescu, Ion V.; Radulescu, Cristiana Bulletin of Materials Science, Vol. 41, Issue 3 https://doi.org/10.1007/s12034-018-1600-8	journal	May 2018
Polymer-coated cobalt ferrite nanoparticles: synthesis, characterization, and toxicity for hyperthermia applications Nam, P. H.; Lu, L. T.; Linh, P. H. New Journal of Chemistry, Vol. 42, Issue 17 https://doi.org/10.1039/c8nj01701h	journal	January 2018
Spatial focusing of magnetic particle hyperthermia Myrovali, Eirini; Maniotis, Nikos; Samaras, Theodoros Nanoscale Advances, Vol. 2, Issue 1 https://doi.org/10.1039/c9na00667b	journal	January 2020
Mössbauer Studies of Core-Shell FeO/Fe3O4 Nanoparticles Kamzin, A. S.; Valiullin, A. A.; Khurshid, H. Physics of the Solid State, Vol. 60, Issue 2 https://doi.org/10.1134/s1063783418020129	journal	February 2018
Direct Laser Writing of Magneto-Photonic Sub-Microstructures for Prospective Applications in Biomedical Engineering Au, Thi; Trinh, Duc; Tong, Quang Nanomaterials, Vol. 7, Issue 5 https://doi.org/10.3390/nano7050105	journal	May 2017

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