Carbon-Nanotube-Based Thermoelectric Materials and Devices

Blackburn, Jeffrey L.; Ferguson, Andrew J.; Cho, Chungyeon; Grunlan, Jaime C.

doi:10.1002/adma.201704386

Carbon-Nanotube-Based Thermoelectric Materials and Devices

Journal Article · Sun Jan 21 23:00:00 EST 2018 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201704386· OSTI ID:1419418

Blackburn, Jeffrey L. ^[1]; Ferguson, Andrew J. ^[1]; Cho, Chungyeon ^[2]; Grunlan, Jaime C. ^[2]

National Renewable Energy Lab. (NREL), Golden, CO (United States)
Texas A & M Univ., College Station, TX (United States)

Conversion of waste heat to voltage has the potential to significantly reduce the carbon footprint of a number of critical energy sectors, such as the transportation and electricity-generation sectors, and manufacturing processes. Thermal energy is also an abundant low-flux source that can be harnessed to power portable/wearable electronic devices and critical components in remote off-grid locations. As such, a number of different inorganic and organic materials are being explored for their potential in thermoelectric-energy-harvesting devices. Carbon-based thermoelectric materials are particularly attractive due to their use of nontoxic, abundant source-materials, their amenability to high-throughput solution-phase fabrication routes, and the high specific energy (i.e., W g-1) enabled by their low mass. Single-walled carbon nanotubes (SWCNTs) represent a unique 1D carbon allotrope with structural, electrical, and thermal properties that enable efficient thermoelectric-energy conversion. Here, the progress made toward understanding the fundamental thermoelectric properties of SWCNTs, nanotube-based composites, and thermoelectric devices prepared from these materials is reviewed in detail. This progress illuminates the tremendous potential that carbon-nanotube-based materials and composites have for producing high-performance next-generation devices for thermoelectric-energy harvesting.

View Accepted Manuscript (DOE)

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Energy Efficiency and Renewable Energy (EERE), NREL Laboratory Directed Research and Development (LDRD)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1419418

Alternate ID(s):: OSTI ID: 1417708

Report Number(s):: NREL/JA--5900-70041

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 11 Vol. 30; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Thermoelectric Power of p -Doped Single-Wall Carbon Nanotubes and the Role of Phonon Drag Vavro, J.; Llaguno, M. C.; Fischer, J. E. Physical Review Letters, Vol. 90, Issue 6 https://doi.org/10.1103/PhysRevLett.90.065503	journal	February 2003
Modulation of Thermoelectric Power of Individual Carbon Nanotubes Small, Joshua P.; Perez, Kerstin M.; Kim, Philip Physical Review Letters, Vol. 91, Issue 25 https://doi.org/10.1103/PhysRevLett.91.256801	journal	December 2003
Measuring the Thermal Conductivity of a Single Carbon Nanotube Fujii, Motoo; Zhang, Xing; Xie, Huaqing Physical Review Letters, Vol. 95, Issue 6 https://doi.org/10.1103/PhysRevLett.95.065502	journal	August 2005
Quasi-ballistic carbon nanotube array transistors with current density exceeding Si and GaAs Brady, Gerald J.; Way, Austin J.; Safron, Nathaniel S. Science Advances, Vol. 2, Issue 9 https://doi.org/10.1126/sciadv.1601240	journal	September 2016
Band Gap Fluorescence from Individual Single-Walled Carbon Nanotubes O'Connell, Michael J.; Bachilo, Sergei M.; Huffman, Chad B. Science, Vol. 297, Issue 5581, p. 593-596 https://doi.org/10.1126/science.1072631	journal	July 2002
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Nanomaterials in transistors: From high-performance to thin-film applications Franklin, A. D. Science, Vol. 349, Issue 6249 https://doi.org/10.1126/science.aab2750	journal	August 2015
Complex thermoelectric materials Snyder, G. Jeffrey; Toberer, Eric S. Materials for Sustainable Energy https://doi.org/10.1142/9789814317665_0016	book	October 2010
Review—Organic Materials for Thermoelectric Energy Generation Cowen, Lewis M.; Atoyo, Jonathan; Carnie, Matthew J. ECS Journal of Solid State Science and Technology, Vol. 6, Issue 3 https://doi.org/10.1149/2.0121703jss	journal	January 2017
Thermal conductivity and phonon transport in empty and water-filled carbon nanotubes Thomas, John A.; Iutzi, Ryan M.; McGaughey, Alan J. H. Carnegie Mellon University https://doi.org/10.1184/r1/6490211	text	January 2010
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N-Type Thermoelectric Performance of Functionalized Carbon Nanotube-Filled Polymer Composites Freeman, Dallas D.; Choi, Kyungwho; Yu, Choongho PLoS ONE, Vol. 7, Issue 11 https://doi.org/10.1371/journal.pone.0047822	journal	November 2012
Temperature Gradient Measurements by Using Thermoelectric Effect in CNTs-Silicone Adhesive Composite Chani, Muhammad Tariq Saeed; Karimov, Kh. S.; Asiri, Abdullah M. PLoS ONE, Vol. 9, Issue 4 https://doi.org/10.1371/journal.pone.0095287	journal	April 2014
Thermoelectrics: Direct Solar Thermal Energy Conversion Tritt, Terry M.; Böttner, Harald; Chen, Lidong MRS Bulletin, Vol. 33, Issue 4 https://doi.org/10.1557/mrs2008.73	journal	April 2008
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Segregated network polymer/carbon nanotubes composites Mierczynska, A.; Friedrich, J.; Maneck, H. Open Chemistry, Vol. 2, Issue 2 https://doi.org/10.2478/BF02475579	journal	June 2004
BiCuSeO oxyselenides: new promising thermoelectric materials [BiCuSeO оксиселенид - жаңа келешегi жоғары термоэлектрлiк материал ретiнде] Faiz, A.; Abuova, F.; Shaken, N. Bulletin of L.N. Gumilyov Eurasian National University. PHYSICS. ASTRONOMY Series, Vol. 128, Issue 3 https://doi.org/10.32523/2616-68-36-2019-128-3-160-165	journal	January 2019
Review on Polymers for Thermoelectric Applications Culebras, Mario; Gómez, Clara; Cantarero, Andrés Materials, Vol. 7, Issue 9 https://doi.org/10.3390/ma7096701	journal	September 2014
Melt-mixed thermoplastic composites containing carbon nanotubes for thermoelectric applications Luo, Jinji; Krause, Beate; Pötschke, Petra AIMS Materials Science, Vol. 3, Issue 3 https://doi.org/10.3934/matersci.2016.3.1107	journal	January 2016
Diameter dependence of thermoelectric power of semiconducting carbon nanotubes Hung, Nguyen T.; Nugraha, Ahmad R. T.; Hasdeo, Eddwi H. arXiv https://doi.org/10.48550/arxiv.1508.05727	text	January 2015
Giant Seebeck coefficient in semiconducting single-wall carbon nanotube film Nakai, Yusuke; Honda, Kazuya; Yanagi, Kazuhiro Applied Physics Express, Vol. 7, Issue 2 https://doi.org/10.7567/APEX.7.025103	journal	January 2014
Thermoelectric properties of single-wall carbon nanotube films: Effects of diameter and wet environment Hayashi, Daisuke; Ueda, Tomohiro; Nakai, Yusuke Applied Physics Express, Vol. 9, Issue 2 https://doi.org/10.7567/APEX.9.025102	journal	January 2016
Improvement of thermoelectric performance of single-wall carbon nanotubes by heavy doping: Effect of one-dimensional band multiplicity Hayashi, Daisuke; Nakai, Yusuke; Kyakuno, Haruka Applied Physics Express, Vol. 9, Issue 12 https://doi.org/10.7567/APEX.9.125103	journal	November 2016

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