Two-dimensional limit of crystalline order in perovskite membrane films

Hong, Seung Sae; Yu, Jung Ho; Lu, Di; Marshall, Ann F.; Hikita, Yasuyuki; Cui, Yi; Hwang, Harold Y.

doi:10.1126/sciadv.aao5173

Title: Two-dimensional limit of crystalline order in perovskite membrane films

Journal Article · Fri Nov 17 00:00:00 EST 2017 · Science Advances

DOI:https://doi.org/10.1126/sciadv.aao5173· OSTI ID:1419318

^[1]; Yu, Jung Ho ^[2]; Lu, Di ^[2]; Marshall, Ann F. ^[3]; Hikita, Yasuyuki ^[4];

^[1];

^[1]

Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
Stanford Univ., Stanford, CA (United States)
Stanford Nano Shared Facilities, Stanford, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States)

Long-range order and phase transitions in two-dimensional (2D) systems—such as magnetism, superconductivity, and crystallinity—have been important research topics for decades. The issue of 2D crystalline order has reemerged recently, with the development of exfoliated atomic crystals. Understanding the dimensional limit of crystalline phases, with different types of bonding and synthetic techniques, is at the foundation of low-dimensional materials design. We study ultrathin membranes of SrTiO₃, an archetypal perovskite oxide with isotropic (3D) bonding. Atomically controlled membranes are released after synthesis by dissolving an underlying epitaxial layer. Although all unreleased films are initially single-crystalline, the SrTiO₃ membrane lattice collapses below a critical thickness (5 unit cells). This crossover from algebraic to exponential decay of the crystalline coherence length is analogous to the 2D topological Berezinskii-Kosterlitz-Thouless (BKT) transition. Finally, the transition is likely driven by chemical bond breaking at the 2D layer-3D bulk interface, defining an effective dimensional phase boundary for coherent crystalline lattices.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: award357195; Stanford Nano Shared Facilities (SNSF), Award ECCS-1542152; award342082; AC02-76SF00515; award342083; GBMF4415

OSTI ID:: 1419318

Journal Information:: Science Advances, Vol. 3, Issue 11; ISSN 2375-2548

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 84 works

Citation information provided by
Web of Science

References (31)

The structure of suspended graphene sheets Meyer, Jannik C.; Geim, A. K.; Katsnelson, M. I. Nature, Vol. 446, Issue 7131, p. 60-63 https://doi.org/10.1038/nature05545	journal	March 2007
Screw dislocations in high-Tc films Gerber, C.; Anselmetti, D.; Bednorz, J. G. Nature, Vol. 350, Issue 6316 https://doi.org/10.1038/350279a0	journal	March 1991
Berezinskii–Kosterlitz–Thouless crossover in a trapped atomic gas Hadzibabic, Zoran; Krüger, Peter; Cheneau, Marc Nature, Vol. 441, Issue 7097 https://doi.org/10.1038/nature04851	journal	June 2006
Absence of Ferromagnetism or Antiferromagnetism in One- or Two-Dimensional Isotropic Heisenberg Models Mermin, N. D.; Wagner, H. Physical Review Letters, Vol. 17, Issue 22 https://doi.org/10.1103/PhysRevLett.17.1133	journal	November 1966
Melting and the vector Coulomb gas in two dimensions Young, A. P. Physical Review B, Vol. 19, Issue 4 https://doi.org/10.1103/PhysRevB.19.1855	journal	February 1979
Liquid-gated interface superconductivity on an atomically flat film Ye, J. T.; Inoue, S.; Kobayashi, K. Nature Materials, Vol. 9, Issue 2 https://doi.org/10.1038/nmat2587	journal	November 2009
Synthesis of freestanding single-crystal perovskite films and heterostructures by etching of sacrificial water-soluble layers Lu, Di; Baek, David J.; Hong, Seung Sae Nature Materials, Vol. 15, Issue 12 https://doi.org/10.1038/nmat4749	journal	September 2016
Study of the Superfluid Transition in Two-Dimensional ${}^{4}{He}$ Films Bishop, D. J.; Reppy, J. D. Physical Review Letters, Vol. 40, Issue 26 https://doi.org/10.1103/PhysRevLett.40.1727	journal	June 1978
Size Dependence of Structural Metastability in Semiconductor Nanocrystals Chen, C. Science, Vol. 276, Issue 5311 https://doi.org/10.1126/science.276.5311.398	journal	April 1997
Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials Coleman, J. N.; Lotya, M.; O'Neill, A. Science, Vol. 331, Issue 6017, p. 568-571 https://doi.org/10.1126/science.1194975	journal	February 2011
Intrinsic ripples in graphene Fasolino, A.; Los, J. H.; Katsnelson, M. I. Nature Materials, Vol. 6, Issue 11 https://doi.org/10.1038/nmat2011	journal	September 2007
Stripe-like nanoscale structural phase separation in superconducting BaPb1−xBixO3 Giraldo-Gallo, P.; Zhang, Y.; Parra, C. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9231	journal	September 2015
Ordering, metastability and phase transitions in two-dimensional systems Kosterlitz, J M; Thouless, D J Journal of Physics C: Solid State Physics, Vol. 6, Issue 7, p. 1181-1203 https://doi.org/10.1088/0022-3719/6/7/010	journal	April 1973
Grains and grain boundaries in single-layer graphene atomic patchwork quilts Huang, Pinshane Y.; Ruiz-Vargas, Carlos S.; van der Zande, Arend M. Nature, Vol. 469, Issue 7330, p. 389-392 https://doi.org/10.1038/nature09718	journal	January 2011
Defects in flexible membranes with crystalline order Seung, H. S.; Nelson, David R. Physical Review A, Vol. 38, Issue 2 https://doi.org/10.1103/PhysRevA.38.1005	journal	July 1988
Possibility of Vortex-Antivortex Pair Dissociation in Two-Dimensional Superconductors Beasley, M. R.; Mooij, J. E.; Orlando, T. P. Physical Review Letters, Vol. 42, Issue 17, p. 1165-1168 https://doi.org/10.1103/PhysRevLett.42.1165	journal	April 1979
Superconducting Interfaces Between Insulating Oxides Reyren, N.; Thiel, S.; Caviglia, A. D. Science, Vol. 317, Issue 5842 https://doi.org/10.1126/science.1146006	journal	August 2007
Theory of Two-Dimensional Melting Halperin, B. I.; Nelson, David R. Physical Review Letters, Vol. 41, Issue 2 https://doi.org/10.1103/PhysRevLett.41.121	journal	July 1978
Kosterlitz-Thouless Transition in Proximity-Coupled Superconducting Arrays Resnick, D. J.; Garland, J. C.; Boyd, J. T. Physical Review Letters, Vol. 47, Issue 21 https://doi.org/10.1103/PhysRevLett.47.1542	journal	November 1981
The rise of graphene Geim, A. K.; Novoselov, K. S. Nature Materials, Vol. 6, Issue 3, p. 183-191 https://doi.org/10.1038/nmat1849	journal	March 2007
All-Oxide Crystalline Microelectromechanical Systems: Bending the Functionalities of Transition-Metal Oxide Thin Films Pellegrino, Luca; Biasotti, Michele; Bellingeri, Emilio Advanced Materials, Vol. 21, Issue 23 https://doi.org/10.1002/adma.200803360	journal	June 2009
Two-Dimensional Dielectric Nanosheets: Novel Nanoelectronics From Nanocrystal Building Blocks Osada, Minoru; Sasaki, Takayoshi Advanced Materials, Vol. 24, Issue 2, p. 210-228 https://doi.org/10.1002/adma.201103241	journal	October 2011
SrTiO3() surface structures under oxidizing conditions Erdman, N.; Marks, L. D. Surface Science, Vol. 526, Issue 1-2 https://doi.org/10.1016/S0039-6028(02)02573-6	journal	February 2003
Ripples and Layers in Ultrathin MoS ₂ Membranes Brivio, Jacopo; Alexander, Duncan T. L.; Kis, Andras Nano Letters, Vol. 11, Issue 12 https://doi.org/10.1021/nl2022288	journal	December 2011
Two-dimensional melting Strandburg, Katherine J. Reviews of Modern Physics, Vol. 60, Issue 1 https://doi.org/10.1103/RevModPhys.60.161	journal	January 1988
Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene Lee, C.; Wei, X.; Kysar, J. W. Science, Vol. 321, Issue 5887, p. 385-388 https://doi.org/10.1126/science.1157996	journal	July 2008
Atomic Control of the SrTiO₃ Crystal Surface Kawasaki, M.; Takahashi, K.; Maeda, T. Science, Vol. 266, Issue 5190, p. 1540-1542 https://doi.org/10.1126/science.266.5190.1540	journal	December 1994
Absence of Ferromagnetism or Antiferromagnetism in One- or Two-Dimensional Isotropic Heisenberg Models Mermin, N. D.; Wagner, H. Physical Review Letters, Vol. 17, Issue 26 https://doi.org/10.1103/physrevlett.17.1307	journal	December 1966
Experimental observation of two-stage melting in a classical two-dimensional screened Coulomb system Murray, C. A.; Van Winkle, D. H. Physical Review Letters, Vol. 58, Issue 12 https://doi.org/10.1103/physrevlett.58.1200	journal	March 1987
Localized Metallic Conductivity and Self-Healing during Thermal Reduction of ${SrTiO}_{3}$ Szot, K.; Speier, W.; Carius, R. Physical Review Letters, Vol. 88, Issue 7 https://doi.org/10.1103/physrevlett.88.075508	journal	February 2002
Intrinsic ripples in graphene Fasolino, A.; Los, J. H.; Katsnelson, M. I. arXiv https://doi.org/10.48550/arxiv.0704.1793	text	January 2007

Cited By (10)

Hydrogenation Dynamics of Electrically Controlled Metal–Insulator Transition in Proton‐Gated Transparent and Flexible WO ₃ Transistors Xu, Dong‐Dong; Deng, Xing; Zhao, Yi‐Feng Advanced Functional Materials, Vol. 29, Issue 34 https://doi.org/10.1002/adfm.201902497	journal	June 2019
Synergetic Behavior in 2D Layered Material/Complex Oxide Heterostructures Kang, Kyeong Tae; Park, Jeongmin; Suh, Dongseok Advanced Materials, Vol. 31, Issue 34 https://doi.org/10.1002/adma.201803732	journal	December 2018
Ferroelectric Domain Wall Motion in Freestanding Single‐Crystal Complex Oxide Thin Film Bakaul, Saidur R.; Kim, Jaegyu; Hong, Seungbum Advanced Materials, Vol. 32, Issue 4 https://doi.org/10.1002/adma.201907036	journal	December 2019
Giant Uniaxial Strain Ferroelectric Domain Tuning in Freestanding PbTiO ₃ Films Han, Lu; Fang, Yanhan; Zhao, Yunqi Advanced Materials Interfaces, Vol. 7, Issue 7 https://doi.org/10.1002/admi.201901604	journal	April 2020
Freestanding crystalline oxide perovskites down to the monolayer limit Ji, Dianxiang; Cai, Songhua; Paudel, Tula R. Nature, Vol. 570, Issue 7759 https://doi.org/10.1038/s41586-019-1255-7	journal	June 2019
Self-assembled multiferroic perovskite–spinel nanocomposite thin films: epitaxial growth, templating and integration on silicon Kim, Dong Hun; Ning, Shuai; Ross, Caroline A. Journal of Materials Chemistry C, Vol. 7, Issue 30 https://doi.org/10.1039/c9tc02033k	journal	January 2019
Non-Ohmic conduction in exfoliated La _0.7 Ca _0.3 MnO ₃ thin films Park, Jungsik; Shin, Jae Hoon; Song, Kyung Applied Physics Letters, Vol. 116, Issue 2 https://doi.org/10.1063/1.5127355	journal	January 2020
Wrinkle-free atomically thin CdS nanosheets for photocatalytic hydrogen evolution Pan, Ziwei; Li, Junnan; Zhou, Kebin Nanotechnology, Vol. 29, Issue 21 https://doi.org/10.1088/1361-6528/aab4d5	journal	March 2018
Freestanding crystalline YB a 2 C u 3 O 7 − x heterostructure membranes Chen, Zhuoyu; Wang, Bai Yang; Goodge, Berit H. Physical Review Materials, Vol. 3, Issue 6 https://doi.org/10.1103/physrevmaterials.3.060801	journal	June 2019
Synergetic Behavior in 2D Layered Material/Complex Oxide Heterostructures Kang, Kyeong Tae; Park, Jeongmin; Suh, Dongseok arXiv https://doi.org/10.48550/arxiv.1905.02930	text	January 2019

Similar Records

New coherent states in periodic arrays of ultrasmall Josephson junctions

Journal Article · Thu Sep 01 00:00:00 EDT 1988 · Phys. Rev. B: Condens. Matter; (United States) · OSTI ID:1419318

Jacobs, L; Jose, J V; Novotny, M A; +1 more

Vogel-Fulcher-Tamman criticality of 3D superinsulators

Journal Article · Wed Oct 24 00:00:00 EDT 2018 · Scientific Reports · OSTI ID:1419318

Diamantini, M. C.; Gammaitoni, L.; Trugenberger, C. A.; +1 more

Berezinskii-Kosterlitz-Thouless crossover in a photonic lattice

Journal Article · Sat Jan 15 00:00:00 EST 2011 · Physical Review. A · OSTI ID:1419318

Small, Eran; Pugatch, Rami; Silberberg, Yaron

Related Subjects

36 MATERIALS SCIENCE

Title: Two-dimensional limit of crystalline order in perovskite membrane films

Citation Formats

References (31)

Cited By (10)

Similar Records

Related Subjects