Structural dependence of crystallization in glasses along the nepheline (NaAlSiO 4 ) ‐ eucryptite (LiAlSiO 4 ) join

Marcial, José; Kabel, Joey; Saleh, Muad; Washton, Nancy; Shaharyar, Yaqoot; Goel, Ashutosh; McCloy, John S.

doi:10.1111/jace.15439

Title: Structural dependence of crystallization in glasses along the nepheline (NaAlSiO ₄ ) ‐ eucryptite (LiAlSiO ₄ ) join

Journal Article · Thu Feb 01 00:00:00 EST 2018 · Journal of the American Ceramic Society

DOI:https://doi.org/10.1111/jace.15439· OSTI ID:1419091

^[1]; Kabel, Joey ^[2]; Saleh, Muad ^[1]; Washton, Nancy ^[3]; Shaharyar, Yaqoot ^[4];

^[4];

^[5]

Materials Science and Engineering Program Washington State University Pullman Washington
School of Mechanical &, Materials Engineering Washington State University Pullman Washington
Pacific Northwest National Laboratory Richland Washington
Department of Materials Science and Engineering Rutgers‐The State University of New Jersey Piscataway New Jersey
Materials Science and Engineering Program Washington State University Pullman Washington, School of Mechanical &, Materials Engineering Washington State University Pullman Washington, Pacific Northwest National Laboratory Richland Washington

Abstract Lithium and sodium aluminosilicates are important glass‐forming systems for commercial glass‐ceramics, as well as being important model systems for ion transport in battery studies. In addition, uncontrolled crystallization of LiAlSiO ₄ (eucryptite) in high‐Li ₂ O compositions, analogous to the more well‐known problem of NaAlSiO ₄ (nepheline) crystallization, can cause concerns for long‐term chemical durability in nuclear waste glasses. To study the relationships between glass structure and crystallization, nine glasses were synthesized in the Li _x Na _1‐ _x AlSiO ₄ series, from x = 0 to x = 1. Raman spectra, nuclear magnetic resonance ( NMR ) spectroscopy (Li‐7, Na‐23, Al‐27, Si‐29), and X‐ray diffraction were used to study the quenched and heat‐treated glasses. It was found that different LiAlSiO ₄ and NaAlSiO ₄ crystal phases crystallize from the glass depending on the Li/Na ratio. Raman and NMR spectra of quenched glasses suggest similar structures regardless of alkali substitution. Li‐7 and Na‐23 NMR spectra of the glass‐ceramics near the endmember compositions show evidence of several differentiable sites distinct from known Li _x Na _1‐ _x AlSiO ₄ crystalline phases, suggesting that these measurements can reveal subtle chemical environment differences in mixed‐alkali systems, similar to what has been observed for zeolites.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: DE‐AC05‐76RL01830

OSTI ID:: 1419091

Journal Information:: Journal of the American Ceramic Society, Journal Name: Journal of the American Ceramic Society Vol. 101 Journal Issue: 7; ISSN 0002-7820

Publisher:: Wiley-BlackwellCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 23 works

Citation information provided by
Web of Science

References (70)

Nepheline crystallization in boron-rich alumino-silicate glasses as investigated by multi-nuclear NMR, Raman, & Mössbauer spectroscopies McCloy, John; Washton, Nancy; Gassman, Paul Journal of Non-Crystalline Solids, Vol. 409 https://doi.org/10.1016/j.jnoncrysol.2014.11.013	journal	February 2015
Solid-state nuclear magnetic resonance investigation of cation siting in LiNaLSX zeolites Feuerstein, M.; Engelhardt, G.; McDaniel, P. L. Microporous and Mesoporous Materials, Vol. 26, Issue 1-3 https://doi.org/10.1016/S1387-1811(98)00211-X	journal	December 1998
Phase Equilibria in the System Lithium Metasilicate-beta-Eucryptite Krishna Murthy, M.; Hummel, F. A. Journal of the American Ceramic Society, Vol. 37, Issue 1 https://doi.org/10.1111/j.1151-2916.1954.tb13971.x	journal	January 1954
High-resolution 23Na, 27Al and 29Si NMR spectroscopy of framework Aluminosilicate glasses Oestrike, Richard; Yang, Wang-hong; Kirkpatrick, R. James Geochimica et Cosmochimica Acta, Vol. 51, Issue 8 https://doi.org/10.1016/0016-7037(87)90269-9	journal	August 1987
Glass-Ceramics by Photosensitive Processes Borrelli, Nicholas F. International Journal of Applied Glass Science, Vol. 6, Issue 3 https://doi.org/10.1111/ijag.12130	journal	August 2015
Cristobalite-Related Phases in the NaAlO2–NaAlSiO4 System. II. A Commensurately Modulated Cubic Structure Withers, R. L.; Thompson, J. G.; Melnitchenko, A. Acta Crystallographica Section B Structural Science, Vol. 54, Issue 5 https://doi.org/10.1107/S0108768197019939	journal	October 1998
Characterisation of sodium cations in dehydrated zeolite NaX by 23Na NMR spectroscopy Feuerstein, M.; Hunger, M.; Engelhardt, G. Solid State Nuclear Magnetic Resonance, Vol. 7, Issue 2 https://doi.org/10.1016/S0926-2040(96)01246-5	journal	November 1996
Magic angle spinning NMR observation of sodium site exchange in nepheline at 500° C Stebbins, Jonathan F.; Farnan, Ian; Williams, Evan H. Physics and Chemistry of Minerals, Vol. 16, Issue 8 https://doi.org/10.1007/BF00209699	journal	November 1989
Radiation effects and tolerance mechanism in β-eucryptite Narayanan, Badri; Reimanis, Ivar E.; Huang, Hanchen Journal of Applied Physics, Vol. 113, Issue 3 https://doi.org/10.1063/1.4775838	journal	January 2013
Submixture model to predict nepheline precipitation in waste glasses Vienna, John D.; Kroll, Jared O.; Hrma, Pavel R. International Journal of Applied Glass Science, Vol. 8, Issue 2 https://doi.org/10.1111/ijag.12207	journal	May 2016
Nepheline structural and chemical dependence on melt composition Marcial, José; Crum, Jarrod; Neill, Owen American Mineralogist, Vol. 101, Issue 2 https://doi.org/10.2138/am-2016-5370	journal	February 2016
Insight into sodium silicate glass structural organization by multinuclear NMR combined with first-principles calculations Angeli, Frédéric; Villain, Olivier; Schuller, Sophie Geochimica et Cosmochimica Acta, Vol. 75, Issue 9 https://doi.org/10.1016/j.gca.2011.02.003	journal	May 2011
Lithium conductivity in glasses of the Li ₂ O–Al ₂ O ₃ –SiO ₂ system Ross, Sebastian; Welsch, Anna-Maria; Behrens, Harald Physical Chemistry Chemical Physics, Vol. 17, Issue 1 https://doi.org/10.1039/C4CP03609C	journal	January 2015
Thermal transformation of zeolite Li-A(BW). The crystal structure of γ-eucryptite, a polymorph of LiAlSiO4 Norby, P. Zeolites, Vol. 10, Issue 3 https://doi.org/10.1016/0144-2449(90)90045-S	journal	March 1990
Site Preferences in the Mixed Cation Zeolite, Li,Na-Chabazite: A Combined Solid-State NMR and Neutron Diffraction Study Smith, Luis J.; Eckert, Hellmut; Cheetham, Anthony K. Journal of the American Chemical Society, Vol. 122, Issue 8 https://doi.org/10.1021/ja992882b	journal	March 2000
Elucidating the Effect of Iron Speciation (Fe ²⁺ /Fe ³⁺ ) on Crystallization Kinetics of Sodium Aluminosilicate Glasses Shaharyar, Yaqoot; Cheng, Justin Y.; Han, Edmund Journal of the American Ceramic Society, Vol. 99, Issue 7 https://doi.org/10.1111/jace.14239	journal	April 2016
Control of Nepheline Crystallization in Nuclear Waste Glass Fox, Kevin M.; Edwards, Thomas B.; Peeler, David K. International Journal of Applied Ceramic Technology, Vol. 5, Issue 6 https://doi.org/10.1111/j.1744-7402.2008.02250.x	journal	November 2008
The mixed alkali effect in lithium-sodium aluminosilicate glasses Lapp, Josef C.; Shelby, James E. Journal of Non-Crystalline Solids, Vol. 95-96 https://doi.org/10.1016/S0022-3093(87)80695-6	journal	December 1987
Advances in understanding the structure of borosilicate glasses: A Raman spectroscopy study Manara, D.; Grandjean, A.; Neuville, D. R. American Mineralogist, Vol. 94, Issue 5-6 https://doi.org/10.2138/am.2009.3027	journal	May 2009
Compositional and Stability Relationships Among the Lithium Aluminosilicates: Eucryptite, Spodumene, and Petalite Roy, Rustum; Roy, Della M.; Osborn, E. F. Journal of the American Ceramic Society, Vol. 33, Issue 5 https://doi.org/10.1111/j.1151-2916.1950.tb12780.x	journal	May 1950
23Na NMR chemical shifts and local Na coordination environments in silicate crystals, melts and glasses Xue, Xianyu; Stebbins, JonathanF. Physics and Chemistry of Minerals, Vol. 20, Issue 5 https://doi.org/10.1007/BF00215100	journal	October 1993
Structural characterization of lithium aluminosilicate glass and glass ceramics derived from spodumene mineral Nordmann, A.; Cheng, Y.; Bastow, T. J. Journal of Physics: Condensed Matter, Vol. 7, Issue 16 https://doi.org/10.1088/0953-8984/7/16/007	journal	April 1995
Interstitial cristobalite-type compounds (Na2O)≤0.33Na[AlSiO4] Klingenberg, R.; Felsche, J. Journal of Solid State Chemistry, Vol. 61, Issue 1 https://doi.org/10.1016/0022-4596(86)90004-6	journal	January 1986
Structure of mineral glasses—II. The SiO2NaAlSiO4 join Taylor, Mark; Brown, Gordon E. Geochimica et Cosmochimica Acta, Vol. 43, Issue 9 https://doi.org/10.1016/0016-7037(79)90141-8	journal	September 1979
Inhomogeneous distribution of Na+ in alkali silicate glasses Tokuda, Yomei; Oka, Takanori; Takahashi, Masahide Journal of the Ceramic Society of Japan, Vol. 119, Issue 1396 https://doi.org/10.2109/jcersj2.119.909	journal	January 2011
Silicate structures of the cristobalite type: III. Structural relationship of high-cristobalite, α-carnegieite, and Na₂CaSiO₄ Barth, Tom. F. W.; Posnjak, E. Zeitschrift für Kristallographie - Crystalline Materials, Vol. 81, Issue 1-6 https://doi.org/10.1524/zkri.1932.81.1.376	journal	October 1932
Cristobalite-Related Phases in the NaAlO2–NaAlSiO4 System. I. Two Tetragonal and Two Orthorhombic Structures Thompson, J. G.; Withers, R. L.; Melnitchenko, A. Acta Crystallographica Section B Structural Science, Vol. 54, Issue 5 https://doi.org/10.1107/S0108768197019927	journal	October 1998
Characterization of Li Cations in Zeolite LiX by Solid-State NMR Spectroscopy and Neutron Diffraction Feuerstein, M.; Lobo, R. F. Chemistry of Materials, Vol. 10, Issue 8 https://doi.org/10.1021/cm980112d	journal	August 1998
Structural characterization of pure Na-nephelines synthesized by zeolite conversion route Dimitrijevic, Radovan; Dondur, Vera; Vulic, Predrag Journal of Physics and Chemistry of Solids, Vol. 65, Issue 10 https://doi.org/10.1016/j.jpcs.2004.03.005	journal	October 2004
Examination of the mixed-alkali effect in (Li,Na) disilicate glasses by nuclear magnetic resonance and conductivity measurements Ali, F.; Chadwick, A. V.; Greaves, G. N. Solid State Nuclear Magnetic Resonance, Vol. 5, Issue 1 https://doi.org/10.1016/0926-2040(95)00033-M	journal	October 1995
Effects of cation field strength on the structure of aluminoborosilicate glasses: High-resolution 11B, 27Al and 23Na MAS NMR Wu, Jingshi; Stebbins, Jonathan F. Journal of Non-Crystalline Solids, Vol. 355, Issue 9 https://doi.org/10.1016/j.jnoncrysol.2009.01.025	journal	April 2009
Crystallization of iron-containing sodium aluminosilicate glasses in the NaAlSiO ₄ -NaFeSiO ₄ join : CRYSTALLIZATION NAALSIO Ahmadzadeh, Mostafa; Marcial, José; McCloy, John Journal of Geophysical Research: Solid Earth, Vol. 122, Issue 4 https://doi.org/10.1002/2016JB013661	journal	April 2017
Al,Si order in the crystal structure of α-eucryptite (LiAlSiO ₄ ) Daniels, Peter; Fyfe, Colin A. American Mineralogist, Vol. 86, Issue 3 https://doi.org/10.2138/am-2001-2-310	journal	March 2001
Average and super structure of β eucryptite (LiAlSiO ₄ ) Part I. Average structure* Tscherry, V.; Schulz, H.; Laves, F. Zeitschrift für Kristallographie, Vol. 135, Issue 3-4 https://doi.org/10.1524/zkri.1972.135.3-4.161	journal	July 1972
Local cation environments in mixed alkali silicate glasses studied by multinuclear single and double resonance magic-angle spinning NMR Gee, Becky; Janssen, Michael; Eckert, Hellmut Journal of Non-Crystalline Solids, Vol. 215, Issue 1 https://doi.org/10.1016/S0022-3093(97)00037-9	journal	July 1997
A Reinvestigation of Low-Carnegieite by XRD, NMR, and TEM Thompson, John G.; Withers, Ray L.; Whittaker, Andrew K. Journal of Solid State Chemistry, Vol. 104, Issue 1 https://doi.org/10.1006/jssc.1993.1141	journal	May 1993
Thirty-year quest for structure–nucleation relationships in oxide glasses Zanotto, E. D.; Tsuchida, J. E.; Schneider, J. F. International Materials Reviews, Vol. 60, Issue 7 https://doi.org/10.1080/09506608.2015.1114706	journal	October 2015
High-resolution aluminum-27 NMR of aluminosilicates Lippmaa, E.; Samoson, A.; Magi, M. Journal of the American Chemical Society, Vol. 108, Issue 8 https://doi.org/10.1021/ja00268a002	journal	April 1986
Cation Distribution in Mixed-Alkali Silicate Glasses. NMR Studies by ²³ Na−{ ⁷ Li} and ²³ Na−{ ⁶ Li} Spin Echo Double Resonance Gee, Becky; Eckert, Hellmut The Journal of Physical Chemistry, Vol. 100, Issue 9 https://doi.org/10.1021/jp9521722	journal	January 1996
Viscosity Behavior and Mixed Alkali Effect of Alkali Aluminosilicate Glass Melts Kim, Ki-Dong; Lee, Seung-Heun Journal of the Ceramic Society of Japan, Vol. 105, Issue 1226 https://doi.org/10.2109/jcersj.105.827	journal	January 1997
Leaching of Devitrified Glass Containing Simulated SRP Nuclear Waste Jantzen, Carol M.; Bickford, Dennis F. MRS Proceedings, Vol. 44 https://doi.org/10.1557/PROC-44-135	journal	January 1984
Crystal structure of hexagonal trinepheline; a new synthetic NaAlSiO ₄ modification Kahlenberg, V.; Bohn, H. American Mineralogist, Vol. 83, Issue 5-6 https://doi.org/10.2138/am-1998-5-623	journal	June 1998
Properties and structure of (1−x)Li2O–xNa2O–Al2O3–4SiO2 glass systems Wang, Moo-Chin; Cheng, Chih-Wei; Shih, Ping-Yu Journal of Non-Crystalline Solids, Vol. 353, Issue 22-23 https://doi.org/10.1016/j.jnoncrysol.2006.09.040	journal	July 2007
Nepheline Crystallization in High-Alumina High-Level Waste Glass Marcial, José; McCloy, John; Neill, Owen MRS Proceedings, Vol. 1744 https://doi.org/10.1557/opl.2015.382	journal	January 2015
The Crystal Chemistry of Nepheline Tait, K. T.; Sokolova, E.; Hawthorne, F. C. The Canadian Mineralogist, Vol. 41, Issue 1 https://doi.org/10.2113/gscanmin.41.1.61	journal	February 2003
6Li nuclear magnetic resonance chemical shifts, coordination number and relaxation in crystalline and glassy silicates Xu, Z.; Stebbins, Jonathan F. Solid State Nuclear Magnetic Resonance, Vol. 5, Issue 1 https://doi.org/10.1016/0926-2040(95)00026-M	journal	October 1995
An XRD and Electron Diffraction Study of Cristobalite-Related Phases in the NaAlO2–NaAlSiO4System Thompson, John G.; Melnitchenko, Alexandra; Palethorpe, Stephen R. Journal of Solid State Chemistry, Vol. 131, Issue 1 https://doi.org/10.1006/jssc.1997.7295	journal	June 1997
Structural Origin of the Thermal and Diffusion Behaviors of Lithium Aluminosilicate Crystal Polymorphs and Glasses Ren, Mengguo; Du, Jincheng Journal of the American Ceramic Society, Vol. 99, Issue 8 https://doi.org/10.1111/jace.14292	journal	May 2016
The thermal transformation of Na LiA zeolites. A new polymorph in the system Li2OAl2O3SiO2 Dondur, Vera; Dimitrijević, Radovan Journal of Solid State Chemistry, Vol. 63, Issue 1 https://doi.org/10.1016/0022-4596(86)90150-7	journal	June 1986
Electron microscopy of Li ₂ O–Al ₂ O ₃ –SiO ₂ glass ceramics Gai, P. L.; Chen, Q. Q. Acta Crystallographica Section A, Vol. 38, Issue 5 https://doi.org/10.1107/S0567739482001491	journal	September 1982
A theoretical study of structural factors correlated with ²³ Na NMR parameters Liu, Yun; Tossell, John; Nekvasil, Hanna American Mineralogist, Vol. 89, Issue 8-9 https://doi.org/10.2138/am-2004-8-920	journal	August 2004
Nepheline gradient solid solutions Ota, Toshitaka; Yamai, Iwao; Hayashi, Takashi Journal of Materials Science, Vol. 30, Issue 10 https://doi.org/10.1007/BF00362155	journal	May 1995
Temperature-induced amorphization of Na-zeolite A: A view from multi-nuclear high-resolution solid-state NMR Kim, H. N.; Lee, S. K. American Mineralogist, Vol. 99, Issue 10 https://doi.org/10.2138/am-2014-4928	journal	October 2014
Percolation channels: a universal idea to describe the atomic structure and dynamics of glasses and melts Le Losq, Charles; Neuville, Daniel R.; Chen, Wenlin Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-16741-3	journal	November 2017
Effect of the substitution of boron for aluminium in the β-eucryptite LiAlSiO4 structure Mazza, Daniele; Lucco-Borlera, Maria Journal of the European Ceramic Society, Vol. 13, Issue 1 https://doi.org/10.1016/0955-2219(94)90059-0	journal	January 1994
Melt structure in the system nepheline-diopside Sykes, Dan; Scarfe, Christopher M. Journal of Geophysical Research, Vol. 95, Issue B10 https://doi.org/10.1029/JB095iB10p15745	journal	January 1990
The crystallisation of glasses based on the eutectic compositions in the system Li2O-Al2O3-SiO2: Part 2 Lithium metasilicate-?-eucryptite Barry, T. I.; Clinton, D.; Lay, L. A. Journal of Materials Science, Vol. 5, Issue 2 https://doi.org/10.1007/BF00554629	journal	February 1970
Structural Characterisation of Kaolinite:NaCl Intercalate and its Derivatives Thompson, John G. Clays and Clay Minerals, Vol. 40, Issue 4 https://doi.org/10.1346/CCMN.1992.0400401	journal	January 1992
Modulation wave approach to the structural parameterization and Rietveld refinement of low carnegieite Withers, R. L.; Thompson, J. G. Acta Crystallographica Section B Structural Science, Vol. 49, Issue 4 https://doi.org/10.1107/S010876819300134X	journal	August 1993
Thermochemistry of Charge-Coupled Substitutions in Silicate Glasses: The Systems M _l/n ⁿ⁺ AlO ₂ -SiO ₂ (M = Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Pb) Roy, Bimalendu N.; Navrotsky, Alexandra Journal of the American Ceramic Society, Vol. 67, Issue 9 https://doi.org/10.1111/j.1151-2916.1984.tb19603.x	journal	September 1984
Li+ ion mobility in eucryptite phases Donduft, Vera; Dimitrijević, Radovan; Petranović, Nadežda Journal of Materials Science, Vol. 23, Issue 11 https://doi.org/10.1007/BF01106839	journal	November 1988
The nepheline-kalsilite system; Part I, X-ray data for the crystalline phases Smith, J. V.; Tuttle, O. F. American Journal of Science, Vol. 255, Issue 4 https://doi.org/10.2475/ajs.255.4.282	journal	April 1957
283. The hydrothermal chemistry of silicates. Part I. Synthetic lithium aluminosilicates Barrer, R. M.; White, E. A. D. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9510001267	journal	January 1951
A neutron diffraction and Rietveld analysis of cooperative Li motion in beta-eucryptite Sartbaeva, Asel; Redfern, Simon A. T.; Lee, William T. Journal of Physics: Condensed Matter, Vol. 16, Issue 29 https://doi.org/10.1088/0953-8984/16/29/018	journal	July 2004
Molecular dynamics simulations of liquids and glasses in the system NaAlSiO ₄ -SiO ₂ ; methodology and melt structures Stein, Daniel J.; Spera, Frank J. American Mineralogist, Vol. 80, Issue 5-6 https://doi.org/10.2138/am-1995-5-601	journal	June 1995
The distribution of sodium ions in aluminosilicate glasses: a high-field Na-23 MAS and 3Q MAS NMR study Lee, Sung Keun; Stebbins, Jonathan F. Geochimica et Cosmochimica Acta, Vol. 67, Issue 9 https://doi.org/10.1016/S0016-7037(03)00026-7	journal	May 2003
²⁹ Si and ²⁷ Al MAS-NMR spectroscopy of β-eucryptite (LiAlSiO ₄ ): The enthalpy of Si,Al ordering Phillips, Brian L.; Xu, Hongwu; Heaney, Peter J. American Mineralogist, Vol. 85, Issue 1 https://doi.org/10.2138/am-2000-0117	journal	January 2000
Al–O–Al and Si–O–Si sites in framework aluminosilicate glasses with Si/Al=1: quantification of framework disorder Lee, Sung Keun; Stebbins, Jonathan F. Journal of Non-Crystalline Solids, Vol. 270, Issue 1-3 https://doi.org/10.1016/S0022-3093(00)00089-2	journal	May 2000
Defects and short-range order in nepheline group minerals: a silicon-29 nuclear magnetic resonance study Stebbins, J. F.; Murdoch, J. B.; Carmichael, I. S. E. Physics and Chemistry of Minerals, Vol. 13, Issue 6 https://doi.org/10.1007/BF00309182	journal	November 1986
Understanding the structural origin of crystalline phase transformations in nepheline (NaAlSiO ₄ )‐based glass‐ceramics Deshkar, Ambar; Marcial, José; Southern, Scott A. Journal of the American Ceramic Society, Vol. 100, Issue 7 https://doi.org/10.1111/jace.14845	journal	April 2017

Similar Records

Ionic conductivity in solid electrolytes based on lithium aluminosilicate glass and glass-ceramic. [LiAlSiO/sub 4/;. beta. -eucryptite glass-ceramic;. beta. -spodumene]

Journal Article · Sat May 01 00:00:00 EDT 1976 · J. Electrochem. Soc.; (United States) · OSTI ID:1419091

Johnson, Jr, R T; Biefeld, R M; Knotek, M L; +1 more

Effect of B on Crystallization of Li and Na aluminosilicates - 16323

Conference · Fri Jul 01 00:00:00 EDT 2016 · OSTI ID:1419091

Marcial, Jose; Kabel, Joey; Saleh, Muad; +3 more

Understanding the structural origin of crystalline phase transformations in nepheline (NaAlSiO ₄ )‐based glass‐ceramics

Journal Article · Sun Apr 09 00:00:00 EDT 2017 · Journal of the American Ceramic Society · OSTI ID:1419091

Deshkar, Ambar; Marcial, José; Southern, Scott A.; +4 more

Title: Structural dependence of crystallization in glasses along the nepheline (NaAlSiO 4 ) ‐ eucryptite (LiAlSiO 4 ) join

Citation Formats

References (70)

Similar Records

Related Subjects

Title: Structural dependence of crystallization in glasses along the nepheline (NaAlSiO ₄ ) ‐ eucryptite (LiAlSiO ₄ ) join