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Title: Synthesis and Reactivity of New Aminophenolate Complexes of Nickel

Journal Article · · Molecules
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New well-defined, paramagnetic nickel complexes have been prepared and characterized by X-ray crystallography. The complexes were found to be active for the cross-coupling of alkyl electrophiles (especially ethyl 2-bromobutyrate) with alkyl Grignard reagents. The ligand architecture in these new complexes could potentially be rendered chiral, opening up future possibilities for performing asymmetric cross-coupling reactions.

Research Organization:
Univ. of Hawaii, Honolulu, HI (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
Grant/Contract Number:
FG02-07ER15885
OSTI ID:
1418702
Alternate ID(s):
OSTI ID: 1628476
Journal Information:
Molecules, Journal Name: Molecules Vol. 19 Journal Issue: 12; ISSN 1420-3049
Publisher:
MDPI AGCopyright Statement
Country of Publication:
Switzerland
Language:
English
Citation Metrics:
Cited by: 1 work
Citation information provided by
Web of Science

References (18)

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Catalytic Enantioselective Cross-Couplings of Secondary Alkyl Electrophiles with Secondary Alkylmetal Nucleophiles: Negishi Reactions of Racemic Benzylic Bromides with Achiral Alkylzinc Reagents journal October 2012

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59 BASIC BIOLOGICAL SCIENCES
Biochemistry & Molecular Biology
Chemistry
nickel
cross-coupling
coordination chemistry
paramagnetic complexes