Impact of Mn(II)-Manganese Oxide Reactions on Ni and Zn Speciation

Hinkle, Margaret G.; Dye, Katherine G.; Catalano, Jeffrey G.

doi:10.1021/acs.est.6b04347

Impact of Mn(II)-Manganese Oxide Reactions on Ni and Zn Speciation

Journal Article · Wed Mar 01 00:00:00 EST 2017 · Environmental Science and Technology

DOI:https://doi.org/10.1021/acs.est.6b04347· OSTI ID:1418550

^[1]; Dye, Katherine G. ^[2]; ^[3]

Washington Univ., Saint Louis, MO (United States); DOE OSTI
Washington Univ., Saint Louis, MO (United States)
Washington Univ., St. Louis, MO (United States)

Layered Mn oxide minerals (phyllomanganates) often control trace metal fate in natural systems. The strong uptake of metals such as Ni and Zn by phyllomanganates results from adsorption on or incorporation into vacancy sites. Mn(II) also binds to vacancies and subsequent comproportionation with structural Mn(IV) may alter sheet structures by forming larger and distorted Mn(III)O₆ octahedra. Such Mn(II)-phyllomanganate reactions may thus alter metal uptake by blocking key reactive sites. Here we investigate the effect of Mn(II) on Ni and Zn binding to phyllomanganates of varying initial vacancy content (δ-MnO₂, hexagonal birnessite, and triclinic birnessite) at pH 4 and 7 under anaerobic conditions. Dissolved Mn(II) decreases macroscopic Ni and Zn uptake at pH 4 but not pH 7. Extended X-ray absorption fine structure spectroscopy demonstrates that decreased uptake at pH 4 corresponds with altered Ni and Zn adsorption mechanisms. These metals transition from binding in the interlayer to sheet edges, with Zn increasing its tetrahedrally coordinated fraction. These effects on metal uptake and binding correlate with Mn(II)-induced structural changes, which are more substantial at pH 4 than 7. Finally, through these structural effects and the pH-dependence of Mn(II)-metal competitive adsorption, system pH largely controls metal binding to phyllomanganates in the presence of dissolved Mn(II).

View Accepted Manuscript (DOE)

Research Organization:: Washington Univ., Saint Louis, MO (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357; AC02-76SF00515

OSTI ID:: 1418550

Journal Information:: Environmental Science and Technology, Journal Name: Environmental Science and Technology Journal Issue: 6 Vol. 51; ISSN 0013-936X

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (72)

Grain size and geochemical partitioning of heavy metals in sediments of the Damodar River - a tributary of the lower Ganga, India Singh, A. K.; Hasnain, S. I.; Banerjee, D. K. Environmental Geology, Vol. 39, Issue 1 https://doi.org/10.1007/s002540050439	journal	November 1999
Remobilization of transition metals in surficial pelagic sediments from the eastern Pacific Graybeal, Amy L.; Heath, G. Ross Geochimica et Cosmochimica Acta, Vol. 48, Issue 5 https://doi.org/10.1016/0016-7037(84)90188-1	journal	May 1984
Structure of heavy metal sorbed birnessite. Part III: Results from powder and polarized extended X-ray absorption fine structure spectroscopy Manceau, Alain; Lanson, Bruno; Drits, Victor A. Geochimica et Cosmochimica Acta, Vol. 66, Issue 15 https://doi.org/10.1016/S0016-7037(02)00869-4	journal	August 2002
Characterization of the manganese oxide produced by pseudomonas putida strain MnB1 Villalobos, Mario; Toner, Brandy; Bargar, John Geochimica et Cosmochimica Acta, Vol. 67, Issue 14 https://doi.org/10.1016/S0016-7037(03)00217-5	journal	July 2003
Solid phases in the cycling of manganese in eutrophic lakes: New insights from EXAFS spectroscopy Friedl, Gabriela; Wehrli, Bernhard; Manceau, Alain Geochimica et Cosmochimica Acta, Vol. 61, Issue 2 https://doi.org/10.1016/S0016-7037(96)00316-X	journal	January 1997
A new synthetic route to todorokite-type manganese oxides Ching, Stanton; Krukowska, Katarzyna S.; Suib, Steven L. Inorganica Chimica Acta, Vol. 294, Issue 2 https://doi.org/10.1016/S0020-1693(99)00208-X	journal	November 1999
Chemical Forms of Pb, Zn and Cu in the Sediment Profiles of the Pearl River Estuary Li, Xiangdong; Shen, Zhenguo; Wai, Onyx W. H. Marine Pollution Bulletin, Vol. 42, Issue 3 https://doi.org/10.1016/S0025-326X(00)00145-4	journal	March 2001
Dissolved metals and associated constituents in abandoned coal-mine discharges, Pennsylvania, USA. Part 1: Constituent quantities and correlations Cravotta, Charles A. Applied Geochemistry, Vol. 23, Issue 2 https://doi.org/10.1016/j.apgeochem.2007.10.011	journal	February 2008
Characterization of manganese oxide precipitates from Appalachian coal mine drainage treatment systems Tan, Hui; Zhang, Gengxin; Heaney, Peter J. Applied Geochemistry, Vol. 25, Issue 3 https://doi.org/10.1016/j.apgeochem.2009.12.006	journal	March 2010
Defining manganese(II) removal processes in passive coal mine drainage treatment systems through laboratory incubation experiments Luan, Fubo; Santelli, Cara M.; Hansel, Colleen M. Applied Geochemistry, Vol. 27, Issue 8 https://doi.org/10.1016/j.apgeochem.2012.03.010	journal	August 2012
Sorption of Ni by birnessite: Equilibrium controls on Ni in seawater Peacock, Caroline L.; Sherman, David M. Chemical Geology, Vol. 238, Issue 1-2 https://doi.org/10.1016/j.chemgeo.2006.10.019	journal	March 2007
Copper sorption by the edge surfaces of synthetic birnessite nanoparticles Peña, Jasquelin; Bargar, John R.; Sposito, Garrison Chemical Geology, Vol. 396 https://doi.org/10.1016/j.chemgeo.2014.12.021	journal	March 2015
Biogenic precipitation of manganese oxides and enrichment of heavy metals at acidic soil pH Mayanna, Sathish; Peacock, Caroline L.; Schäffner, Franziska Chemical Geology, Vol. 402 https://doi.org/10.1016/j.chemgeo.2015.02.029	journal	May 2015
Transformations from triclinic to hexagonal birnessite at circumneutral pH induced through pH control by common biological buffers Ling, Florence T.; Heaney, Peter J.; Post, Jeffrey E. Chemical Geology, Vol. 416 https://doi.org/10.1016/j.chemgeo.2015.10.007	journal	November 2015
Mn, Fe, Zn and As speciation in a fast-growing ferromanganese marine nodule Marcus, Matthew A.; Manceau, Alain; Kersten, Michael Geochimica et Cosmochimica Acta, Vol. 68, Issue 14 https://doi.org/10.1016/j.gca.2004.01.015	journal	July 2004
Natural speciation of Mn, Ni, and Zn at the micrometer scale in a clayey paddy soil using X-ray fluorescence, absorption, and diffraction Manceau, Alain; Tommaseo, Caterina; Rihs, Sophie Geochimica et Cosmochimica Acta, Vol. 69, Issue 16 https://doi.org/10.1016/j.gca.2005.03.018	journal	August 2005
Zinc sorption to biogenic hexagonal-birnessite particles within a hydrated bacterial biofilm Toner, Brandy; Manceau, Alain; Webb, Samuel M. Geochimica et Cosmochimica Acta, Vol. 70, Issue 1 https://doi.org/10.1016/j.gca.2005.08.029	journal	January 2006
Natural speciation of Ni, Zn, Ba, and As in ferromanganese coatings on quartz using X-ray fluorescence, absorption, and diffraction Manceau, Alain; Lanson, Martine; Geoffroy, Nicolas Geochimica et Cosmochimica Acta, Vol. 71, Issue 1 https://doi.org/10.1016/j.gca.2006.08.036	journal	January 2007
Ba and Ni speciation in a nodule of binary Mn oxide phase composition from Lake Baikal Manceau, Alain; Kersten, Michael; Marcus, Matthew A. Geochimica et Cosmochimica Acta, Vol. 71, Issue 8 https://doi.org/10.1016/j.gca.2007.02.007	journal	April 2007
Formation of todorokite from vernadite in Ni-rich hemipelagic sediments Bodeï, Sabine; Manceau, Alain; Geoffroy, Nicolas Geochimica et Cosmochimica Acta, Vol. 71, Issue 23 https://doi.org/10.1016/j.gca.2007.07.020	journal	December 2007
Formation of Zn–Ca phyllomanganate nanoparticles in grass roots Lanson, Bruno; Marcus, Matthew A.; Fakra, Sirine Geochimica et Cosmochimica Acta, Vol. 72, Issue 10 https://doi.org/10.1016/j.gca.2008.02.022	journal	May 2008
Physiochemical controls on the crystal-chemistry of Ni in birnessite: Genetic implications for ferromanganese precipitates Peacock, Caroline L. Geochimica et Cosmochimica Acta, Vol. 73, Issue 12 https://doi.org/10.1016/j.gca.2009.03.020	journal	June 2009
Enzymatic microbial Mn(II) oxidation and Mn biooxide production in the Guaymas Basin deep-sea hydrothermal plume Dick, Gregory J.; Clement, Brian G.; Webb, Samuel M. Geochimica et Cosmochimica Acta, Vol. 73, Issue 21 https://doi.org/10.1016/j.gca.2009.07.039	journal	November 2009
Mechanisms of nickel sorption by a bacteriogenic birnessite Peña, Jasquelin; Kwon, Kideok D.; Refson, Keith Geochimica et Cosmochimica Acta, Vol. 74, Issue 11 https://doi.org/10.1016/j.gca.2010.02.035	journal	June 2010
Zn sorption modifies dynamically the layer and interlayer structure of vernadite Grangeon, Sylvain; Manceau, Alain; Guilhermet, Julien Geochimica et Cosmochimica Acta, Vol. 85 https://doi.org/10.1016/j.gca.2012.02.019	journal	May 2012
Distribution and speciation of trace elements in iron and manganese oxide cave deposits Frierdich, Andrew J.; Catalano, Jeffrey G. Geochimica et Cosmochimica Acta, Vol. 91 https://doi.org/10.1016/j.gca.2012.05.032	journal	August 2012
Characterization of Ni-rich hexagonal birnessite and its geochemical effects on aqueous Pb2+/Zn2+ and As(III) Yin, Hui; Tan, Wenfeng; Zheng, Lirong Geochimica et Cosmochimica Acta, Vol. 93 https://doi.org/10.1016/j.gca.2012.05.039	journal	September 2012
Understanding the trends in transition metal sorption by vacancy sites in birnessite Kwon, Kideok D.; Refson, Keith; Sposito, Garrison Geochimica et Cosmochimica Acta, Vol. 101 https://doi.org/10.1016/j.gca.2012.08.038	journal	January 2013
The influence of particle size and structure on the sorption and oxidation behavior of birnessite: I. Adsorption of As(V) and oxidation of As(III) Villalobos, Mario; Escobar-Quiroz, Ingrid N.; Salazar-Camacho, Carlos Geochimica et Cosmochimica Acta, Vol. 125 https://doi.org/10.1016/j.gca.2013.10.029	journal	January 2014
Probing the sorption reactivity of the edge surfaces in birnessite nanoparticles using nickel(II) Simanova, Anna A.; Kwon, Kideok D.; Bone, Sharon E. Geochimica et Cosmochimica Acta, Vol. 164 https://doi.org/10.1016/j.gca.2015.04.050	journal	September 2015
Structural response of phyllomanganates to wet aging and aqueous Mn(II) Hinkle, Margaret A. G.; Flynn, Elaine D.; Catalano, Jeffrey G. Geochimica et Cosmochimica Acta, Vol. 192 https://doi.org/10.1016/j.gca.2016.07.035	journal	November 2016
Zn sorption mechanisms onto sheathed Leptothrix discophora and the impact of the nanoparticulate biogenic Mn oxide coating Boonfueng, Thipnakarin; Axe, Lisa; Yee, Nathan Journal of Colloid and Interface Science, Vol. 333, Issue 2 https://doi.org/10.1016/j.jcis.2009.02.033	journal	May 2009
Geomicrobiology of manganese(II) oxidation Tebo, Bradley M.; Johnson, Hope A.; McCarthy, James K. Trends in Microbiology, Vol. 13, Issue 9 https://doi.org/10.1016/j.tim.2005.07.009	journal	September 2005
A Mn-54 Radiotracer Study of Mn Isotope Solid–Liquid Exchange during Reductive Transformation of Vernadite (δ-MnO ₂ ) by Aqueous Mn(II) Elzinga, Evert J.; Kustka, Adam B. Environmental Science & Technology, Vol. 49, Issue 7 https://doi.org/10.1021/acs.est.5b00022	journal	March 2015
Time-Resolved Investigation of Cobalt Oxidation by Mn(III)-Rich δ-MnO ₂ Using Quick X-ray Absorption Spectroscopy Simanova, Anna A.; Peña, Jasquelin Environmental Science & Technology, Vol. 49, Issue 18 https://doi.org/10.1021/acs.est.5b01088	journal	July 2015
Redox Reactions between Mn(II) and Hexagonal Birnessite Change Its Layer Symmetry Zhao, Huaiyan; Zhu, Mengqiang; Li, Wei Environmental Science & Technology, Vol. 50, Issue 4 https://doi.org/10.1021/acs.est.5b04436	journal	January 2016
Reaction Rates and Products of Manganese Oxidation at the Sediment-Water Interface Wehrli, Bernhard; Friedl, Gabriela; Manceau, Alain Advances in Chemistry https://doi.org/10.1021/ba-1995-0244.ch005	book	May 1995
Preparative Parameters and Framework Dopant Effects in the Synthesis of Layer-Structure Birnessite by Air Oxidation Cai, Jun; Liu, Jia; Suib, Steven L. Chemistry of Materials, Vol. 14, Issue 5 https://doi.org/10.1021/cm010771h	journal	May 2002
Processes of Nickel and Cobalt Uptake by a Manganese Oxide Forming Sediment in Pinal Creek, Globe Mining District, Arizona Kay, John T.; Conklin, Martha H.; Fuller, Christopher C. Environmental Science & Technology, Vol. 35, Issue 24 https://doi.org/10.1021/es010514d	journal	December 2001
Molecular-Scale Speciation of Zn and Ni in Soil Ferromanganese Nodules from Loess Soils of the Mississippi Basin Manceau, Alain; Tamura, Nobumichi; Celestre, Richard S. Environmental Science & Technology, Vol. 37, Issue 1 https://doi.org/10.1021/es025748r	journal	January 2003
Cation Effects on the Layer Structure of Biogenic Mn-Oxides Zhu, Mengqiang; Ginder-Vogel, Matthew; Parikh, Sanjai J. Environmental Science & Technology, Vol. 44, Issue 12 https://doi.org/10.1021/es1009955	journal	June 2010
Reductive Transformation of Birnessite by Aqueous Mn(II) Elzinga, Evert J. Environmental Science & Technology, Vol. 45, Issue 15 https://doi.org/10.1021/es2013038	journal	August 2011
Influence of pH on the Reductive Transformation of Birnessite by Aqueous Mn(II) Lefkowitz, Joshua P.; Rouff, Ashaki A.; Elzinga, Evert J. Environmental Science & Technology, Vol. 47, Issue 18 https://doi.org/10.1021/es402108d	journal	September 2013
Processes of Zinc Attenuation by Biogenic Manganese Oxides Forming in the Hyporheic Zone of Pinal Creek, Arizona Fuller, Christopher C.; Bargar, John R. Environmental Science & Technology, Vol. 48, Issue 4 https://doi.org/10.1021/es402576f	journal	February 2014
Impacts of Aqueous Mn(II) on the Sorption of Zn(II) by Hexagonal Birnessite Lefkowitz, Joshua P.; Elzinga, Evert J. Environmental Science & Technology, Vol. 49, Issue 8 https://doi.org/10.1021/es506019j	journal	April 2015
Ni(II) Sorption on Biogenic Mn-Oxides with Varying Mn Octahedral Layer Structure Zhu, Mengqiang; Ginder-Vogel, Matthew; Sparks, Donald L. Environmental Science & Technology, Vol. 44, Issue 12 https://doi.org/10.1021/es9037066	journal	June 2010
Effects of Inorganic Cation Templates on Octahedral Molecular Sieves of Manganese Oxide Shen, Yan-Fei; Suib, Steven L.; O'Young, Chi-Lin Journal of the American Chemical Society, Vol. 116, Issue 24 https://doi.org/10.1021/ja00103a018	journal	November 1994
Sorption selectivity of birnessite particle edges: a d-PDF analysis of Cd( ii ) and Pb( ii ) sorption by δ-MnO ₂ and ferrihydrite van Genuchten, Case M.; Peña, Jasquelin Environmental Science: Processes & Impacts, Vol. 18, Issue 8 https://doi.org/10.1039/C6EM00136J	journal	January 2016
Parameter-free calculations of X-ray spectra with FEFF9 Rehr, John J.; Kas, Joshua J.; Vila, Fernando D. Physical Chemistry Chemical Physics, Vol. 12, Issue 21 https://doi.org/10.1039/b926434e	journal	January 2010
Manganese oxide minerals: Crystal structures and economic and environmental significance Post, J. E. Proceedings of the National Academy of Sciences, Vol. 96, Issue 7 https://doi.org/10.1073/pnas.96.7.3447	journal	March 1999
Sorption of Trace Elements on Mineral Surfaces: Modern Perspectives from Spectroscopic Studies, and Comments on Sorption in the Marine Environment Brown, Gordon E.; Parks, George A. International Geology Review, Vol. 43, Issue 11 https://doi.org/10.1080/00206810109465060	journal	November 2001
Zinc Sorption During Bio-oxidation and Precipitation of Manganese Modifies the Layer Stacking of Biogenic Birnessite Yu, Qianqian; Sasaki, Keiko; Tanaka, Kazuya Geomicrobiology Journal, Vol. 30, Issue 9 https://doi.org/10.1080/01490451.2013.774075	journal	October 2013
Marine Geochemistry 1. Chemical Scavengers of the Sea Goldberg, Edward D. The Journal of Geology, Vol. 62, Issue 3 https://doi.org/10.1086/626161	journal	May 1954
Short-range and long-range order of phyllomanganate nanoparticles determined using high-energy X-ray scattering Manceau, Alain; Marcus, Matthew A.; Grangeon, S. Journal of Applied Crystallography, Vol. 46, Issue 1 https://doi.org/10.1107/S0021889812047917	journal	January 2013
IFEFFIT : interactive XAFS analysis and FEFF fitting Newville, Matthew Journal of Synchrotron Radiation, Vol. 8, Issue 2 https://doi.org/10.1107/S0909049500016964	journal	March 2001
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Crystalline Todorokite Associated with Biogenic Debris in Manganese Nodules Siegel, M. D.; Turner, S. Science, Vol. 219, Issue 4581 https://doi.org/10.1126/science.219.4581.172	journal	January 1983
BIOGENIC MANGANESE OXIDES: Properties and Mechanisms of Formation Tebo, Bradley M.; Bargar, John R.; Clement, Brian G. Annual Review of Earth and Planetary Sciences, Vol. 32, Issue 1 https://doi.org/10.1146/annurev.earth.32.101802.120213	journal	May 2004
Cation exchange in synthetic manganates: I. Alkylammonium exchange in a synthetic phyllomanganate Paterson, E.; Bunch, J. L.; Clark, D. R. Clay Minerals, Vol. 21, Issue 5 https://doi.org/10.1180/claymin.1986.021.5.08	journal	December 1986
SIXPack a Graphical User Interface for XAS Analysis Using IFEFFIT Webb, S. M. Physica Scripta https://doi.org/10.1238/Physica.Topical.115a01011	journal	January 2005
Microbial manganese oxide formation and interaction with toxic metal ions Miyata, Naoyuki; Tani, Yukinori; Sakata, Masahiro Journal of Bioscience and Bioengineering, Vol. 104, Issue 1 https://doi.org/10.1263/jbb.104.1	journal	July 2007
Structural mechanism of Co (super 2+) oxidation by the phyllomanganate buserite Manceau, Alain; Drits, Victor A.; Silvester, Ewen American Mineralogist, Vol. 82, Issue 11-12 https://doi.org/10.2138/am-1997-11-1213	journal	December 1997
Structure of synthetic monoclinic Na-rich birnessite and hexagonal birnessite; I, Results from X-ray diffraction and selected-area electron diffraction Drits, Victor A.; Silvester, Ewen; Gorshkov, Anatoli I. American Mineralogist, Vol. 82, Issue 9-10 https://doi.org/10.2138/am-1997-9-1012	journal	October 1997
Structure of synthetic monoclinic Na-rich birnessite and hexagonal birnessite; II, Results from chemical studies and EXAFS spectroscopy Silvester, Ewen; Manceau, Alain; Drits, Victor A. American Mineralogist, Vol. 82, Issue 9-10 https://doi.org/10.2138/am-1997-9-1013	journal	October 1997
Structure of H-exchanged hexagonal birnessite and its mechanism of formation from Na-rich monoclinic buserite at low pH Lanson, Bruno; Drits, Victor A.; Silvester, Ewen American Mineralogist, Vol. 85, Issue 5-6 https://doi.org/10.2138/am-2000-5-625	journal	May 2000
Deciphering Ni sequestration in soil ferromanganese nodules by combining X-ray fluorescence, absorption, and diffraction at micrometer scales of resolution Manceau, Alain; Tamura, Nobumichi; Marcus, Matthew A. American Mineralogist, Vol. 87, Issue 10 https://doi.org/10.2138/am-2002-1028	journal	October 2002
Structure of heavy-metal sorbed birnessite: Part 1. Results from X-ray diffraction Lanson, Bruno; Drits, Victor A.; Gaillot, Anne-Claire American Mineralogist, Vol. 87, Issue 11-12 https://doi.org/10.2138/am-2002-11-1213	journal	November 2002
Mineralogy and crystal chemistry of Mn, Fe, Co, Ni, and Cu in a deep-sea Pacific polymetallic nodule Manceau, A.; Lanson, M.; Takahashi, Y. American Mineralogist, Vol. 99, Issue 10 https://doi.org/10.2138/am-2014-4742	journal	October 2014
Biotic and abiotic products of Mn(II) oxidation by spores of the marine Bacillus sp. strain SG-1 Bargar, John R.; Tebo, Bradley M.; Bergmann, Uwe American Mineralogist, Vol. 90, Issue 1 https://doi.org/10.2138/am.2005.1557	journal	January 2005
Birnessite polytype systematics and identification by powder X-ray diffraction Drits, V. A.; Lanson, B.; Gaillot, A. -C. American Mineralogist, Vol. 92, Issue 5-6 https://doi.org/10.2138/am.2007.2207	journal	May 2007
Time-resolved structural analysis of K- and Ba-exchange reactions with synthetic Na-birnessite using synchrotron X-ray diffraction Lopano, C. L.; Heaney, P. J.; Post, J. E. American Mineralogist, Vol. 92, Issue 2-3 https://doi.org/10.2138/am.2007.2242	journal	February 2007
Crystal-chemistry of Ni in marine ferromanganese crusts and nodules Peacock, C. L.; Sherman, D. M. American Mineralogist, Vol. 92, Issue 7 https://doi.org/10.2138/am.2007.2378	journal	July 2007

Cited By (1)

Characterization of manganese oxide amendments for in situ remediation of mercury-contaminated sediments Leven, Alexander; Vlassopoulos, Dimitri; Kanematsu, Masakazu Environmental Science: Processes & Impacts, Vol. 20, Issue 12 https://doi.org/10.1039/c7em00576h	journal	January 2018

Similar Records

Structural response of phyllomanganates to wet aging and aqueous Mn(II)

Journal Article · Fri Aug 05 20:00:00 EDT 2016 · Geochimica et Cosmochimica Acta · OSTI ID:1418531

Structural alteration of hexagonal birnessite by aqueous Mn(II): Impacts on Ni(II) sorption

Journal Article · Fri Sep 01 00:00:00 EDT 2017 · Chemical Geology · OSTI ID:1377919

Impacts of sulfonic acids on fungal manganese oxide production

Journal Article · Thu Dec 01 19:00:00 EST 2022 · Geochimica et Cosmochimica Acta · OSTI ID:2423470

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Adsorption
Defects in solids
Metals
Physiology
Vinyl

Impact of Mn(II)-Manganese Oxide Reactions on Ni and Zn Speciation

Citation Formats

References (72)

Cited By (1)

Similar Records

Related Subjects