3D Printed Silicones with Shape Memory

Wu, Amanda S.; Small IV, Ward; Bryson, Taylor M.; Cheng, Emily; Metz, Thomas R.; Schulze, Stephanie E.; Duoss, Eric B.; Wilson, Thomas S.

doi:10.1038/s41598-017-04663-z

3D Printed Silicones with Shape Memory

Journal Article · Wed Jul 05 00:00:00 EDT 2017 · Scientific Reports

DOI:https://doi.org/10.1038/s41598-017-04663-z· OSTI ID:1395481

Wu, Amanda S. ^[1]; Small IV, Ward ^[2]; Bryson, Taylor M. ^[1]; Cheng, Emily ^[1]; Metz, Thomas R. ^[1]; Schulze, Stephanie E. ^[3]; Duoss, Eric B. ^[1]; Wilson, Thomas S. ^[2]

Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Materials Engineering Division
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Materials Science Division
Honeywell, Materials Engineering, Kansas City, MO (United States). Department of Energys National Security Campus

Direct ink writing enables the layer-by-layer manufacture of ordered, porous structures whose mechanical behavior is driven by architecture and material properties. Here, we incorporate two different gas filled microsphere pore formers to evaluate the effect of shell stiffness and T_g on compressive behavior and compression set in siloxane matrix printed structures. The lower T_g microsphere structures exhibit substantial compression set when heated near and above T_g, with full structural recovery upon reheating without constraint. By contrast, the higher T_g microsphere structures exhibit reduced compression set with no recovery upon reheating. Aside from their role in tuning the mechanical behavior of direct ink write structures, polymer microspheres are good candidates for shape memory elastomers requiring structural complexity, with potential applications toward tandem shape memory polymers.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 1395481

Alternate ID(s):: OSTI ID: 1417275

Report Number(s):: LLNL-JRNL--716517; PII: 4663

Journal Information:: Scientific Reports, Journal Name: Scientific Reports Journal Issue: 1 Vol. 7; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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