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Group IV nanocrystals with ion-exchangeable surface ligands and methods of making the same

Patent ·
OSTI ID:1416730
Methods are described that include reacting a starting nanocrystal that includes a starting nanocrystal core and a covalently bound surface species to create an ion-exchangeable (IE) nanocrystal that includes a surface charge and a first ion-exchangeable (IE) surface ligand ionically bound to the surface charge, where the starting nanocrystal core includes a group IV element.
Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC36-08GO28308
Assignee:
Alliance for Sustainable Energy, LLC (Golden, CO)
Patent Number(s):
9,862,841
Application Number:
15/388,415
OSTI ID:
1416730
Country of Publication:
United States
Language:
English

References (16)

Two-photon absorption of matrix-free Ge nanocrystals journal September 2006
Thiol-Capped Germanium Nanocrystals: Preparation and Evidence for Quantum Size Effects journal March 2014
Near-Infrared Photoluminescence Enhancement in Ge/CdS and Ge/ZnS Core/Shell Nanocrystals: Utilizing IV/II–VI Semiconductor Epitaxy journal July 2014
Silicon Nanocrystals and Silicon-Polymer Hybrids: Synthesis, Surface Engineering, and Applications journal November 2015
Ligand Exchange and the Stoichiometry of Metal Chalcogenide Nanocrystals: Spectroscopic Observation of Facile Metal-Carboxylate Displacement and Binding
  • Anderson, Nicholas C.; Hendricks, Mark P.; Choi, Joshua J.
  • Journal of the American Chemical Society, Vol. 135, Issue 49, p. 18536-18548 https://doi.org/10.1021/ja4086758
journal November 2013
Plasma-Assisted Synthesis of Silicon Nanocrystal Inks journal September 2007
Silyl Radical Abstraction in the Functionalization of Plasma-Synthesized Silicon Nanocrystals journal September 2015
Illuminating Silicon Surface Hydrosilylation: An Unexpected Plurality of Mechanisms journal September 2013
Hypervalent surface interactions for colloidal stability and doping of silicon nanocrystals journal July 2013
The synthesis of silicon and germanium quantum dots for biomedical applications conference March 2006
Colloidal Synthesis of Infrared-Emitting Germanium Nanocrystals journal March 2009
Toward a Mechanistic Understanding of Exciton-Mediated Hydrosilylation on Nanocrystalline Silicon journal December 2011
Surface Chemistry Exchange of Alloyed Germanium Nanocrystals: A Pathway Toward Conductive Group IV Nanocrystal Films journal January 2013
Size Controlled Synthesis of Germanium Nanocrystals by Hydride Reducing Agents and Their Biological Applications journal January 2010
Synthesis and Characterization of Germanium/Si−Alkyl and Germanium/Silica Core−Shell Quantum Dots journal December 1999
Size and Bandgap Control in the Solution-Phase Synthesis of Near-Infrared-Emitting Germanium Nanocrystals journal November 2010

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