Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Oxidative Corrosion of the UO 2 (001) Surface by Nonclassical Diffusion

Journal Article · · Langmuir
Abstract not provided
Research Organization:
Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)
Sponsoring Organization:
USDOE Office of Science (SC), Biological and Environmental Research (BER) (SC-23); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI ID:
1416568
Journal Information:
Langmuir, Journal Name: Langmuir Journal Issue: 46 Vol. 33; ISSN 0743-7463
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
ENGLISH

References (43)

Computer simulation of defect clusters in UO2 and their dependence on composition journal January 2015
Characterization of single crystal uranium-oxide thin films grown via reactive-gas magnetron sputtering on yttria-stabilized zirconia and sapphire journal June 2012
Cooperativity among defect sites in A O 2 + x and A 4 O 9 ( A = U , Np , Pu ) : Density functional calculations journal January 2009
Point defects and clustering in uranium dioxide by LSDA + U calculations journal March 2008
Characterisation of crystalline UO2 oxidised in 1 Torr of oxygen at 25, 225 and 300 °C. Part 2.—X-ray diffraction and scanning electron microscopy
  • Allen, Geoffrey C.; Tempest, Paul A.; Tyler, Jonathan W.
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 84, Issue 11 https://doi.org/10.1039/f19888404061
journal January 1988
Crystal truncation rods and surface roughness journal March 1986
Water corrosion of spent nuclear fuel: radiolysis driven dissolution at the UO 2 /water interface journal January 2015
X-ray Reflectivity as a Probe of Mineral-Fluid Interfaces: A User Guide journal January 2002
Oxygen transport in off-stoichiometric uranium dioxide mediated by defect clustering dynamics journal March 2015
Local Structure and Charge Distribution in the UO 2 −U 4 O 9 System journal November 2004
Stability mechanism of cuboctahedral clusters in U O 2 + x : First-principles calculations journal May 2008
Average structure and local configuration of excess oxygen in UO2+x journal March 2014
XPS determination of uranium oxidation states: XPS determination of uranium oxidation states journal October 2011
Linear ordering of oxygen clusters in hyperstoicheiometric uranium dioxide journal January 1982
A review of the oxidation of uranium dioxide at temperatures below 400°C journal April 1998
Ab initio investigation on oxygen defect clusters in UO2+x journal November 2008
Positions of the Oxygen Atoms in UO2.13 journal February 1963
Cluster method for analysing surface X-ray diffraction data sets using area detectors journal January 2014
Biogenic Uraninite Nanoparticles and Their Importance for Uranium Remediation journal December 2008
Diffuse multiple scattering journal January 2015
Surface defect configurations on the (100) dipolar surface of UO 2 journal July 2005
Role of di-interstitial clusters in oxygen transport in UO 2 + x from first principles journal August 2009
GenX : an extensible X-ray reflectivity refinement program utilizing differential evolution journal November 2007
Fitting with differential evolution: an introduction and evaluation journal November 2011
Stability and migration of large oxygen clusters in UO 2+ x : Density functional theory calculations journal June 2012
Structures of UO2 and PuO2 surfaces with hydroxide coverage journal September 2005
Quantum mechanical vs. empirical potential modeling of uranium dioxide (UO2) surfaces: (111), (110), and (100) journal November 2006
An STM study of the UO2(001) surface journal April 1999
DFT + U investigation of charged point defects and clusters in UO 2 journal July 2014
Diffusion of oxygen interstitials in UO2+ using kinetic Monte Carlo simulations: Role of O/M ratio and sensitivity analysis journal April 2016
Hydroxylation-induced surface stability of AnO2 (An=U, Np, Pu) from first-principles journal February 2013
Refinement of the structure of β-U 4 O 9 journal June 2004
Migration mechanisms of oxygen interstitial clusters in UO 2 journal November 2012
Fuel corrosion processes under waste disposal conditions journal November 2000
Coordination model for the defect structure of hyperstoichiometric UO2+x and U4O9 journal January 1982
The formation of U 3 O 8 on crystalline UO 2 journal August 1986
UO 2 Oxidative Corrosion by Nonclassical Diffusion journal June 2015
A neutron diffraction study of anion clusters in nonstoichiometric uranium dioxide journal January 1990
Charge distribution and oxygen diffusion in hyperstoichiometric uranium dioxide UO2+x (x⩽0.25) journal March 2013
Effects of stoichiometry on the defect clustering in uranium dioxide journal October 2015
Advances in first-principles modelling of point defects in UO 2 : f electron correlations and the issue of local energy minima journal July 2013
He+ ion-scattering spectroscopy studies of UO2(hkl) surfaces journal January 1980
Distorted surface oxygen structure on UO2(100) journal May 1981

Cited By (2)

Nanoscale oxygen defect gradients in UO 2+ x surfaces journal August 2019
Direct observation of pure pentavalent uranium in U2O5 thin films by high resolution photoemission spectroscopy journal May 2018

Similar Records

Oxidative Corrosion of the UO2 (001) Surface by Nonclassical Diffusion
Journal Article · Wed Nov 01 00:00:00 EDT 2017 · Langmuir · OSTI ID:1821751

Oxidative Corrosion of the UO 2 (001) Surface by Nonclassical Diffusion
Journal Article · Mon Nov 06 23:00:00 EST 2017 · Langmuir · OSTI ID:1411913

Oxidative Corrosion of the UO 2 (001) Surface by Nonclassical Diffusion
Journal Article · Sun Oct 29 20:00:00 EDT 2017 · Langmuir · OSTI ID:1508051

Related Subjects