Phosphate and phytate adsorption and precipitation on ferrihydrite surfaces

Wang, Xiaoming; Hu, Yongfeng; Tang, Yadong; Yang, Peng; Feng, Xionghan; Xu, Wenqian; Zhu, Mengqiang

doi:10.1039/c7en00705a

Title: Phosphate and phytate adsorption and precipitation on ferrihydrite surfaces

Journal Article · Tue Sep 26 00:00:00 EDT 2017 · Environmental Science: Nano

DOI:https://doi.org/10.1039/c7en00705a· OSTI ID:1416015

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Univ. of Wyoming, Laramie, WY (United States). Department of Ecosystem Science and Management
University of Saskatchewan, Saskatoon (Canada). Canadian Light Source
Huazhong Agricultural University, Wuhan (China). Key Laboratory of Arable Land Conservation (Middle and Lower Reaches of Yangtze River), Ministry of Agriculture, College of Resources and Environment
Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division, Advanced Photon Source

Phosphorous (P) sorption on mineral surfaces largely controls P mobility and bioavailability, hence its pollution potential, but the sorption speciation and mechanism remain poorly understood. In this study, we have identified and quantified the speciation of both phosphate and phytate sorbed on ferrihydrite with various P loadings at pH 3–8 using differential atomic pair distribution function (d-PDF) analysis, synchrotron-based X-ray diffraction (XRD), and P and Fe K-edge X-ray absorption near edge structure (XANES) and attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy. With increasing P sorption loading for both phosphate and phytate, the sorption mechanism transits from bidentate-binuclear surface complexation to unidentified ternary complexation and to precipitation of amorphous FePO₄ and amorphous Fe-phytate. At a given P sorption loading, phosphate precipitates more readily than phytate. Both phosphate and phytate promote ferrihydrite dissolution with phytate more intensively, but the dissolved FeIII concentration in the bulk solution is low because the majority of the released Fe^III precipitate with the anions. Results also show that amorphous FePO₄ and amorphous Fe-phytate have similar PO₄ local coordination environment. In conclusion, these new insights into the P surface complexation and precipitation, and the ligand-promoted dissolution behavior improve our understanding of P fate in soils, aquatic environment and water treatment systems as mediated by mineral-water interfacial reactions.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; Canadian Light Source, Inc.; University of Wyoming; National Science Foundation of China

Grant/Contract Number:: AC02-06CH11357; AC02-76SF00515

OSTI ID:: 1416015

Journal Information:: Environmental Science: Nano, Vol. 4, Issue 11; ISSN 2051-8153

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 66 works

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