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Title: Hot Isostatic Pressing of Engineered Forms of I-AgZ

Abstract

Hot isostatic pressing (HIP) is being considered for direct conversion of 129I-bearing materials to a radiological waste form. The removal of volatile radioactive 129I from the off-gas of a nuclear fuel reprocessing facility will be necessary to comply with regulatory requirements regarding reprocessing facilities sited within the United States, and any iodine-containing media or solid sorbents generated by offgas abatement will require disposal. Zeolite minerals such as silver-exchanged mordenite (AgZ) have been studied as potential iodine sorbents and will contain 129I as chemisorbed AgI. Oak Ridge National Laboratory (ORNL) has conducted several recent studies on the HIP of both iodine-loaded AgZ (I-AgZ) and other iodine-bearing zeolite minerals. The goal of these research efforts is to achieve a stable, highly leach resistant material that is reduced in volume as compared to bulk iodine-loaded I-AgZ. Through the use of HIP, it may be possible to achieve this with the addition of little or no additional materials (waste formers). Other goals for the process include that the waste form will be tolerant to high temperatures and pressures, not chemically hazardous, and that the process will result in minimal secondary waste generation. This document describes the preparation of 27 samples that are distinct frommore » previous efforts in that they are prepared exclusively with an engineered form of AgZ that is manufactured using a binder. Iodine was incorporated solely by chemisorption. This base material is expected to be more representative of an operational system than were samples prepared previously with pure minerals.« less

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Nuclear Energy (NE), Fuel Cycle Technologies (NE-5)
OSTI Identifier:
1415914
Report Number(s):
ORNL/TM-2017/707
NTRD-MRWFD-2017-000412
DOE Contract Number:  
AC05-00OR22725
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES

Citation Formats

Jubin, Robert Thomas, Watkins, Thomas R., Bruffey, Stephanie H., Jordan, Jacob A., and Parks, Mackenzie L.. Hot Isostatic Pressing of Engineered Forms of I-AgZ. United States: N. p., 2017. Web. doi:10.2172/1415914.
Jubin, Robert Thomas, Watkins, Thomas R., Bruffey, Stephanie H., Jordan, Jacob A., & Parks, Mackenzie L.. Hot Isostatic Pressing of Engineered Forms of I-AgZ. United States. doi:10.2172/1415914.
Jubin, Robert Thomas, Watkins, Thomas R., Bruffey, Stephanie H., Jordan, Jacob A., and Parks, Mackenzie L.. Wed . "Hot Isostatic Pressing of Engineered Forms of I-AgZ". United States. doi:10.2172/1415914. https://www.osti.gov/servlets/purl/1415914.
@article{osti_1415914,
title = {Hot Isostatic Pressing of Engineered Forms of I-AgZ},
author = {Jubin, Robert Thomas and Watkins, Thomas R. and Bruffey, Stephanie H. and Jordan, Jacob A. and Parks, Mackenzie L.},
abstractNote = {Hot isostatic pressing (HIP) is being considered for direct conversion of 129I-bearing materials to a radiological waste form. The removal of volatile radioactive 129I from the off-gas of a nuclear fuel reprocessing facility will be necessary to comply with regulatory requirements regarding reprocessing facilities sited within the United States, and any iodine-containing media or solid sorbents generated by offgas abatement will require disposal. Zeolite minerals such as silver-exchanged mordenite (AgZ) have been studied as potential iodine sorbents and will contain 129I as chemisorbed AgI. Oak Ridge National Laboratory (ORNL) has conducted several recent studies on the HIP of both iodine-loaded AgZ (I-AgZ) and other iodine-bearing zeolite minerals. The goal of these research efforts is to achieve a stable, highly leach resistant material that is reduced in volume as compared to bulk iodine-loaded I-AgZ. Through the use of HIP, it may be possible to achieve this with the addition of little or no additional materials (waste formers). Other goals for the process include that the waste form will be tolerant to high temperatures and pressures, not chemically hazardous, and that the process will result in minimal secondary waste generation. This document describes the preparation of 27 samples that are distinct from previous efforts in that they are prepared exclusively with an engineered form of AgZ that is manufactured using a binder. Iodine was incorporated solely by chemisorption. This base material is expected to be more representative of an operational system than were samples prepared previously with pure minerals.},
doi = {10.2172/1415914},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Nov 01 00:00:00 EDT 2017},
month = {Wed Nov 01 00:00:00 EDT 2017}
}

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