High-Voltage Aqueous Magnesium Ion Batteries

Wang, Fei; Fan, Xiulin; Gao, Tao; Sun, Wei; Ma, Zhaohui; Yang, Chongyin; Han, Fudong; Xu, Kang; Wang, Chunsheng

doi:10.1021/acscentsci.7b00361

Title: High-Voltage Aqueous Magnesium Ion Batteries

Journal Article · Thu Sep 07 00:00:00 EDT 2017 · ACS Central Science

DOI:https://doi.org/10.1021/acscentsci.7b00361· OSTI ID:1396421

Wang, Fei ^[1]; Fan, Xiulin ^[2]; Gao, Tao ^[2]; Sun, Wei ^[2]; Ma, Zhaohui ^[2];

^[2]; Han, Fudong ^[2]; Xu, Kang ^[3];

^[2]

Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, Maryland 20742, United States, Electrochemistry Branch, Sensor and Electron Devices Directorate, Power and Energy Division, U.S. Army Research Laboratory, Adelphi, Maryland 20783, United States
Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, Maryland 20742, United States
Electrochemistry Branch, Sensor and Electron Devices Directorate, Power and Energy Division, U.S. Army Research Laboratory, Adelphi, Maryland 20783, United States

Nonaqueous rechargeable magnesium (Mg) batteries suffer from the complicated and moisture-sensitive electrolyte chemistry. Besides electrolytes, the practicality of a Mg battery is also confined by the absence of high-performance electrode materials due to the intrinsically slow Mg2+ diffusion in the solids. In this work, we demonstrated a rechargeable aqueous magnesium ion battery (AMIB) concept of high energy density, fast kinetics, and reversibility. Using a superconcentration approach we expanded the electrochemical stability window of the aqueous electrolyte to 2.0 V. More importantly, two new Mg ion host materials, Li superconcentration approach we expanded the electrochemical stability window of the aqueous electrolyte to 2.0 V. More importantly, two new Mg ion host materials, Li3V2(PO4)3 and poly pyromellitic dianhydride, were developed and employed as cathode and anode electrodes, respectively. Based on comparisons of the aqueous and nonaqueous systems, the role of water is identified to be critical in the Mg ion mobility in the intercalation host but remaining little detrimental to its non-diffusion controlled process. Compared with the previously reported Mg ion cell delivers an unprecedented high power density of 6400 W kg ion cell delivers an unprecedented high power density of 6400 W kg while retaining 92% of the initial capacity after 6000 cycles, pushing the Mg ion cell to a brand new stage.

View Journal Article

Cite

Export

Save

Research Organization:: Univ. of Maryland, College Park, MD (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E); National Science Foundation (NSF)

Grant/Contract Number:: AR0000389

OSTI ID:: 1396421

Alternate ID(s):: OSTI ID: 1415275; OSTI ID: 1507705

Journal Information:: ACS Central Science, Journal Name: ACS Central Science Vol. 3 Journal Issue: 10; ISSN 2374-7943

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 219 works

Citation information provided by
Web of Science

References (59)

Nickel Hexacyanoferrate Nanoparticle Electrodes For Aqueous Sodium and Potassium Ion Batteries Wessells, Colin D.; Peddada, Sandeep V.; Huggins, Robert A. Nano Letters, Vol. 11, Issue 12, p. 5421-5425 https://doi.org/10.1021/nl203193q	journal	December 2011
Controllable synthesis of spherical Li3V2(PO4)3/C cathode material and its electrochemical performance Zhang, Lu-Lu; Peng, Gang; Liang, Gan Electrochimica Acta, Vol. 90 https://doi.org/10.1016/j.electacta.2012.11.126	journal	February 2013
Cation-Deficient Spinel ZnMn ₂ O ₄ Cathode in Zn(CF ₃ SO ₃ ) ₂ Electrolyte for Rechargeable Aqueous Zn-Ion Battery Zhang, Ning; Cheng, Fangyi; Liu, Yongchang Journal of the American Chemical Society, Vol. 138, Issue 39 https://doi.org/10.1021/jacs.6b05958	journal	September 2016
Odyssey of Multivalent Cathode Materials: Open Questions and Future Challenges Canepa, Pieremanuele; Sai Gautam, Gopalakrishnan; Hannah, Daniel C. Chemical Reviews, Vol. 117, Issue 5 https://doi.org/10.1021/acs.chemrev.6b00614	journal	February 2017
A high capacity thiospinel cathode for Mg batteries Sun, Xiaoqi; Bonnick, Patrick; Duffort, Victor Energy & Environmental Science, Vol. 9, Issue 7 https://doi.org/10.1039/C6EE00724D	journal	January 2016
Highly Reversible Open Framework Nanoscale Electrodes for Divalent Ion Batteries Wang, Richard Y.; Wessells, Colin D.; Huggins, Robert A. Nano Letters, Vol. 13, Issue 11 https://doi.org/10.1021/nl403669a	journal	October 2013
Electrochemical Property: Structure Relationships in Monoclinic Li ₃ _- _y V ₂ (PO ₄ ) ₃ Yin, S. -C.; Grondey, H.; Strobel, P. Journal of the American Chemical Society, Vol. 125, Issue 34 https://doi.org/10.1021/ja034565h	journal	August 2003
Preparation of M1/3Ni1/3Mn2/3O2 (M=Mg or Zn) and its performance as the cathode material of aqueous divalent cations battery Zhang, Ying; Cheng, Kui; Ye, Ke Electrochimica Acta, Vol. 182 https://doi.org/10.1016/j.electacta.2015.10.008	journal	November 2015
Energetic Zinc Ion Chemistry: The Rechargeable Zinc Ion Battery Xu, Chengjun; Li, Baohua; Du, Hongda Angewandte Chemie International Edition, Vol. 51, Issue 4 https://doi.org/10.1002/anie.201106307	journal	December 2011
On the Way to Rechargeable Mg Batteries: The Challenge of New Cathode Materials ^† Levi, E.; Gofer, Y.; Aurbach, D. Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm9016497	journal	February 2010
Highly Reversible Mg Insertion in Nanostructured Bi for Mg Ion Batteries Shao, Yuyan; Gu, Meng; Li, Xiaolin Nano Letters, Vol. 14, Issue 1 https://doi.org/10.1021/nl403874y	journal	December 2013
Self-Discharge in Electrochemical Capacitors: A Perspective Article Andreas, Heather A. Journal of The Electrochemical Society, Vol. 162, Issue 5 https://doi.org/10.1149/2.0081505jes	journal	January 2015
TiS2 nanotubes as the cathode materials of Mg-ion batteries Tao, Zhan-Liang; Xu, Li-Na; Gou, Xing-Long Chemical Communications, Issue 18 https://doi.org/10.1039/b403855j	journal	January 2004
Progress in Rechargeable Magnesium Battery Technology Aurbach, D.; Suresh, G. S.; Levi, E. Advanced Materials, Vol. 19, Issue 23 https://doi.org/10.1002/adma.200701495	journal	December 2007
Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide Lukatskaya, M. R.; Mashtalir, O.; Ren, C. E. Science, Vol. 341, Issue 6153 https://doi.org/10.1126/science.1241488	journal	September 2013
Nanostructured Composites: A High Capacity, Fast Rate Li3V2(PO4)3/Carbon Cathode for Rechargeable Lithium Batteries Huang, H.; Yin, S. -C.; Kerr, T. Advanced Materials, Vol. 14, Issue 21 https://doi.org/10.1002/1521-4095(20021104)14:21<1525::AID-ADMA1525>3.0.CO;2-3	journal	November 2002
High power rechargeable magnesium/iodine battery chemistry Tian, Huajun; Gao, Tao; Li, Xiaogang Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14083	journal	January 2017
High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance Augustyn, Veronica; Come, Jérémy; Lowe, Michael A. Nature Materials, Vol. 12, Issue 6 https://doi.org/10.1038/nmat3601	journal	April 2013
Prototype systems for rechargeable magnesium batteries Aurbach, D.; Lu, Z.; Schechter, A. Nature, Vol. 407, Issue 6805, p. 724-727 https://doi.org/10.1038/35037553	journal	October 2000
Recent Advances in Rechargeable Magnesium Battery Technology: A Review of the Field’s Current Status and Prospects Park, Min-Sik; Kim, Jae-Geun; Kim, Young-Jun Israel Journal of Chemistry, Vol. 55, Issue 5 https://doi.org/10.1002/ijch.201400174	journal	March 2015
MoS ₂ Nanostructures: Synthesis and Electrochemical Mg ²⁺ Intercalation Li, Xiao-Lin; Li, Ya-Dong The Journal of Physical Chemistry B, Vol. 108, Issue 37 https://doi.org/10.1021/jp0367575	journal	September 2004
Aqueous Mg-Ion Battery Based on Polyimide Anode and Prussian Blue Cathode Chen, L.; Bao, J. L.; Dong, X. ACS Energy Letters, Vol. 2, Issue 5 https://doi.org/10.1021/acsenergylett.7b00040	journal	April 2017
"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries Suo, L.; Borodin, O.; Gao, T. Science, Vol. 350, Issue 6263 https://doi.org/10.1126/science.aab1595	journal	November 2015
Manganese dioxides as rechargeable magnesium battery cathode; synthetic approach to understand magnesiation process Zhang, Ruigang; Arthur, Timothy S.; Ling, Chen Journal of Power Sources, Vol. 282 https://doi.org/10.1016/j.jpowsour.2015.02.067	journal	May 2015
Towards High-Voltage Aqueous Metal-Ion Batteries Beyond 1.5 V: The Zinc/Zinc Hexacyanoferrate System Zhang, Leyuan; Chen, Liang; Zhou, Xufeng Advanced Energy Materials, Vol. 5, Issue 2 https://doi.org/10.1002/aenm.201400930	journal	September 2014
Cathode materials for magnesium and magnesium-ion based batteries Huie, Matthew M.; Bock, David C.; Takeuchi, Esther S. Coordination Chemistry Reviews, Vol. 287 https://doi.org/10.1016/j.ccr.2014.11.005	journal	March 2015
Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage Pasta, Mauro; Wessells, Colin D.; Huggins, Robert A. Nature Communications, Vol. 3, Issue 1, Article No. 1149 https://doi.org/10.1038/ncomms2139	journal	January 2012
Mg rechargeable batteries: an on-going challenge Yoo, Hyun Deog; Shterenberg, Ivgeni; Gofer, Yosef Energy & Environmental Science, Vol. 6, Issue 8, p. 2265-2279 https://doi.org/10.1039/c3ee40871j	journal	January 2013
The challenge of developing rechargeable magnesium batteries Shterenberg, Ivgeni; Salama, Michael; Gofer, Yossi MRS Bulletin, Vol. 39, Issue 5 https://doi.org/10.1557/mrs.2014.61	journal	May 2014
Copper hexacyanoferrate battery electrodes with long cycle life and high power Wessells, Colin D.; Huggins, Robert A.; Cui, Yi Nature Communications, Vol. 2, Article No. 550 https://doi.org/10.1038/ncomms1563	journal	November 2011
The High Performance of Crystal Water Containing Manganese Birnessite Cathodes for Magnesium Batteries Nam, Kwan Woo; Kim, Sangryun; Lee, Soyeon Nano Letters, Vol. 15, Issue 6 https://doi.org/10.1021/acs.nanolett.5b01109	journal	May 2015
A new class of cathode materials for rechargeable magnesium batteries: Organosulfur compounds based on sulfur–sulfur bonds NuLi, Yanna; Guo, Zaiping; Liu, Huakun Electrochemistry Communications, Vol. 9, Issue 8, p. 1913-1917 https://doi.org/10.1016/j.elecom.2007.05.009	journal	August 2007
High concentration magnesium borohydride/tetraglyme electrolyte for rechargeable magnesium batteries Tuerxun, Feilure; Abulizi, Yasen; NuLi, Yanna Journal of Power Sources, Vol. 276 https://doi.org/10.1016/j.jpowsour.2014.11.113	journal	February 2015
V2O5 aerogel as a versatile host for metal ions Tang, Paul E.; Sakamoto, Jeff S.; Baudrin, Emmanuel Journal of Non-Crystalline Solids, Vol. 350 https://doi.org/10.1016/j.jnoncrysol.2004.07.072	journal	December 2004
An ultrafast chargeable polymer electrode based on the combination of nitroxide radical and aqueous electrolyte Koshika, Kenichiroh; Sano, Naoki; Oyaizu, Kenichi Chem. Commun., Issue 7 https://doi.org/10.1039/B818087C	journal	January 2009
Structure and compatibility of a magnesium electrolyte with a sulphur cathode Kim, Hee Soo; Arthur, Timothy S.; Allred, Gary D. Nature Communications, Vol. 2, Article No. 427 https://doi.org/10.1038/ncomms1435	journal	August 2011
Polyimides: Promising Energy-Storage Materials Song, Zhiping; Zhan, Hui; Zhou, Yunhong Angewandte Chemie International Edition, Vol. 49, Issue 45 https://doi.org/10.1002/anie.201002439	journal	September 2010
Magnesium insertion electrodes for rechargeable nonaqueous batteries — a competitive alternative to lithium? Novák, Petr; Imhof, Roman; Haas, Otto Electrochimica Acta, Vol. 45, Issue 1-2, p. 351-367 https://doi.org/10.1016/S0013-4686(99)00216-9	journal	September 1999
New Insight on the Unusually High Ionic Mobility in Chevrel Phases Levi, E.; Gershinsky, G.; Aurbach, D. Chemistry of Materials, Vol. 21, Issue 7 https://doi.org/10.1021/cm900033v	journal	April 2009
An organic cathode material based on a polyimide/CNT nanocomposite for lithium ion batteries Wu, Haiping; Wang, Kai; Meng, Yuena Journal of Materials Chemistry A, Vol. 1, Issue 21 https://doi.org/10.1039/c3ta10473g	journal	January 2013
Electrolyte Solutions with a Wide Electrochemical Window for Rechargeable Magnesium Batteries Mizrahi, Oren; Amir, Nir; Pollak, Elad Journal of The Electrochemical Society, Vol. 155, Issue 2, p. A103-A109 https://doi.org/10.1149/1.2806175	journal	January 2008
Enhancing the Reversibility of Mg/S Battery Chemistry through Li ⁺ Mediation Gao, Tao; Noked, Malachi; Pearse, Alex J. Journal of the American Chemical Society, Vol. 137, Issue 38 https://doi.org/10.1021/jacs.5b07820	journal	September 2015
The Interplay of Al and Mg Speciation in Advanced Mg Battery Electrolyte Solutions See, Kimberly A.; Chapman, Karena W.; Zhu, Lingyang Journal of the American Chemical Society, Vol. 138, Issue 1 https://doi.org/10.1021/jacs.5b10987	journal	December 2015
Investigation of the Mechanism of Mg Insertion in Birnessite in Nonaqueous and Aqueous Rechargeable Mg-Ion Batteries Sun, Xiaoqi; Duffort, Victor; Mehdi, B. Layla Chemistry of Materials, Vol. 28, Issue 2 https://doi.org/10.1021/acs.chemmater.5b03983	journal	January 2016
Achieving High Aqueous Energy Storage via Hydrogen-Generation Passivation Wang, Yuhang; Cui, Xiaoqi; Zhang, Yueyu Advanced Materials, Vol. 28, Issue 35 https://doi.org/10.1002/adma.201602583	journal	July 2016
Defect-Tolerant Diffusion Channels for Mg ²⁺ Ions in Ribbon-Type Borates: Structural Insights into Potential Battery Cathodes MgVBO ₄ and Mg _x Fe _{2– x} B ₂ O ₅ Bo, Shou-Hang; Grey, Clare P.; Khalifah, Peter G. Chemistry of Materials, Vol. 27, Issue 13 https://doi.org/10.1021/acs.chemmater.5b01040	journal	June 2015
Polyanthraquinone-Based Organic Cathode for High-Performance Rechargeable Magnesium-Ion Batteries Pan, Baofei; Huang, Jinhua; Feng, Zhenxing Advanced Energy Materials, Vol. 6, Issue 14 https://doi.org/10.1002/aenm.201600140	journal	May 2016
A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode Kundu, Dipan; Adams, Brian D.; Duffort, Victor Nature Energy, Vol. 1, Issue 10 https://doi.org/10.1038/nenergy.2016.119	journal	August 2016
Aqueous Lithium-Ion Batteries Using O ₂ Self-Elimination Polyimides Electrodes Chen, Long; Li, Wangyu; Guo, Zhaowei Journal of The Electrochemical Society, Vol. 162, Issue 10 https://doi.org/10.1149/2.0101510jes	journal	January 2015
Stabilizing high voltage LiCoO ₂ cathode in aqueous electrolyte with interphase-forming additive Wang, Fei; Lin, Yuxiao; Suo, Liumin Energy & Environmental Science, Vol. 9, Issue 12 https://doi.org/10.1039/C6EE02604D	journal	January 2016
Promise and reality of post-lithium-ion batteries with high energy densities Choi, Jang Wook; Aurbach, Doron Nature Reviews Materials, Vol. 1, Issue 4 https://doi.org/10.1038/natrevmats.2016.13	journal	March 2016
Polymer–Graphene Nanocomposites as Ultrafast-Charge and -Discharge Cathodes for Rechargeable Lithium Batteries Song, Zhiping; Xu, Terrence; Gordin, Mikhail L. Nano Letters, Vol. 12, Issue 5 https://doi.org/10.1021/nl2039666	journal	April 2012
Rechargeable Mg-Ion Batteries Based on WSe ₂ Nanowire Cathodes Liu, Bin; Luo, Tao; Mu, Guangyuan ACS Nano, Vol. 7, Issue 9 https://doi.org/10.1021/nn4032454	journal	August 2013
High energy density rechargeable magnesium battery using earth-abundant and non-toxic elements Orikasa, Yuki; Masese, Titus; Koyama, Yukinori Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep05622	journal	July 2014
Electrochemical Mg2+ intercalation into a bimetallic CuFe Prussian blue analog in aqueous electrolytes Mizuno, Yoshifumi; Okubo, Masashi; Hosono, Eiji Journal of Materials Chemistry A, Vol. 1, Issue 42 https://doi.org/10.1039/c3ta13205f	journal	January 2013
Electrolyte roadblocks to a magnesium rechargeable battery Muldoon, John; Bucur, Claudiu B.; Oliver, Allen G. Energy & Environmental Science, Vol. 5, Issue 3, p. 5941-5950 https://doi.org/10.1039/c2ee03029b	journal	January 2012
Raising the cycling stability of aqueous lithium-ion batteries by eliminating oxygen in the electrolyte Luo, Jia-Yan; Cui, Wang-Jun; He, Ping Nature Chemistry, Vol. 2, Issue 9 https://doi.org/10.1038/nchem.763	journal	August 2010
Synthesis and electrochemical study of Mg1.5MnO3: A defect spinel cathode for rechargeable magnesium battery Saha, Partha; Jampani, Prashanth H.; Hong, DaeHo Materials Science and Engineering: B, Vol. 202 https://doi.org/10.1016/j.mseb.2015.08.008	journal	December 2015

Similar Records

Unique aqueous Li-ion/sulfur chemistry with high energy density and reversibility

Journal Article · Wed May 31 00:00:00 EDT 2017 · Proceedings of the National Academy of Sciences of the United States of America · OSTI ID:1396421

Yang, Chongyin; Suo, Liumin; Borodin, Oleg; +9 more

Quantifying and Suppressing Proton Intercalation to Enable High-Voltage Zn-Ion Batteries

Journal Article · Mon Oct 04 00:00:00 EDT 2021 · Advanced Energy Materials · OSTI ID:1396421

Wang, Fei; Blanc, Lauren E.; Li, Qin; +9 more

Novel Nonflammable Electrolytes for Secondary Magnesium Batteries and High Voltage Electrolytes for Electrochemcial Supercapacitors

Technical Report · Tue Dec 30 00:00:00 EST 2008 · OSTI ID:1396421

Dixon, Brian

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
25 ENERGY STORAGE

Title: High-Voltage Aqueous Magnesium Ion Batteries

Citation Formats

References (59)

Similar Records

Related Subjects