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Title: Texture development and coercivity enhancement in cast alnico 9 magnets

Journal Article · · AIP Advances
DOI:https://doi.org/10.1063/1.5007171· OSTI ID:1556932

The effect of Y addition and magnetic field on texture and magnetic properties of arc-melted alnico 9 magnets has been investigated. Small additions of Y (1.5 wt.%) develop a (200) texture for the arc-melted alnico 9 magnet. Such a texture is hard to form in cast samples. To achieve this goal, we set up a high-field annealing system with a maximum operation temperature of 1250 °C. This system enabled annealing in a field of 45 kOe with subsequent draw annealing for the solutionized buttons; we have been able to substantially increase remanence ratio and coercivity, from 0.70 and 1200 Oe for the Y-free alnico 9 to 0.90 and 1400 Oe for the Y-doped alnico 9, respectively. A high energy product of 7.3 MGOe has been achieved for the fully heat-treated Y-doped alnico 9. The enhancement of coercivity is believed to arise from the introduction of magnetocrystalline anisotropy from 80 nm Y2Co17-type grains, which are exchange-coupled to the main-phase alnico rods.

Research Organization:
Ames Lab., Ames, IA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
under Award ECCS: 1542182; AC02-07CH11358
OSTI ID:
1556932
Alternate ID(s):
OSTI ID: 1414985
Report Number(s):
IS-J-9633
Journal Information:
AIP Advances, Vol. 8, Issue 5; ISSN 2158-3226
Publisher:
American Institute of Physics (AIP)Copyright Statement
Country of Publication:
United States
Language:
English

References (12)

Development of controlled solid-state alignment for alnico permanent magnets in near-final shape journal May 2017
Novel pre-alloyed powder processing of modified alnico 8: Correlation of microstructure and magnetic properties journal May 2015
Atomic-scale Chemical Imaging and Quantification of Metallic Alloy Structures by Energy-Dispersive X-ray Spectroscopy journal February 2014
Architecture and magnetism of alnico journal August 2014
Coercivity and nanostructure of melt-spun Ti-Fe-Co-B-based alloys journal May 2016
Compression Molding and Novel Sintering Treatments for Alnico Type-8 Permanent Magnets in Near-Final Shape with Preferred Orientation journal July 2017
Software Design for Simulation and Analysis of Electron Diffraction Patterns journal July 2012
Landyne - a Software Suite for Electron Diffraction Simulation and Analysis journal July 2016
Structure and magnetic properties of Y2Co17−xSix compounds journal October 1999
Crystal structure and magnetic properties of the Y2Co17−xGax phases journal September 2007
Effect of interstitial hydrogen and nitrogen on magnetic and structural properties of R2T17 (R ≡ Y, Ce and Sm; T ≡ Fe, Co and Ni) journal March 1995
Magnetic properties of Pr2Co17−xAlx and Y2Co17−xAlx journal August 1997

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