Tuning Singlet Fission in π-Bridge-π Chromophores

Kumarasamy, Elango; Sanders, Samuel N.; Tayebjee, Murad J.  Y.; Asadpoordarvish, Amir; Hele, Timothy J.  H.; Fuemmeler, Eric G.; Pun, Andrew B.; Yablon, Lauren M.; Low, Jonathan Z.; Paley, Daniel W.; Dean, Jacob C.; Choi, Bonnie; Scholes, Gregory D.; Steigerwald, Michael L.; Ananth, Nandini; McCamey, Dane R.; Sfeir, Matthew Y.; Campos, Luis M.

doi:10.1021/jacs.7b05204

Title: Tuning Singlet Fission in π-Bridge-π Chromophores

Journal Article · Fri Aug 11 00:00:00 EDT 2017 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.7b05204· OSTI ID:1413948

^[1];

^[1]; Tayebjee, Murad J. Y. ^[2]; Asadpoordarvish, Amir ^[3]; Hele, Timothy J. H. ^[4]; Fuemmeler, Eric G. ^[5]; Pun, Andrew B. ^[1]; Yablon, Lauren M. ^[1]; Low, Jonathan Z. ^[1]; Paley, Daniel W. ^[1]; Dean, Jacob C. ^[6]; Choi, Bonnie ^[1];

^[6]; Steigerwald, Michael L. ^[1]; Ananth, Nandini ^[5]; McCamey, Dane R. ^[3];

^[7];

^[1]

Columbia Univ., New York, NY (United States). Department of Chemistry
University of New South Wales, Sydney (Australia). School of Photovoltaic and Renewable Energy Engineering; University of Cambridge (United Kingdom). Cavendish Laboratory
University of New South Wales, Sydney (Australia). ARC Centre of Excellence in Exciton Science, School of Physics
Cornell Univ., Ithaca, NY (United States). Department of Chemistry and Chemical Biology; Cambridge University (United Kingdom). Jesus College
Cornell Univ., Ithaca, NY (United States). Department of Chemistry and Chemical Biology
Princeton Univ., NJ (United States). Department of Chemistry
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials

For this study, we have designed a series of pentacene dimers separated by homoconjugated or nonconjugated bridges that exhibit fast and efficient intramolecular singlet exciton fission (iSF). These materials are distinctive among reported iSF compounds because they exist in the unexplored regime of close spatial proximity but weak electronic coupling between the singlet exciton and triplet pair states. Using transient absorption spectroscopy to investigate photophysics in these molecules, we find that homoconjugated dimers display desirable excited-state dynamics, with significantly reduced recombination rates as compared to conjugated dimers with similar singlet fission rates. In addition, unlike conjugated dimers, the time constants for singlet fission are relatively insensitive to the interplanar angle between chromophores, since rotation about σ bonds negligibly affects the orbital overlap within the π-bonding network. In the nonconjugated dimer, where the iSF occurs with a time constant >10 ns, comparable to the fluorescence lifetime, we used electron spin resonance spectroscopy to unequivocally establish the formation of triplet–triplet multiexcitons and uncoupled triplet excitons through singlet fission. Together, these studies enable us to articulate the role of the conjugation motif in iSF.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; SC0015429

OSTI ID:: 1413948

Report Number(s):: BNL-114743-2017-JA; KC0403020; TRN: US1800601

Journal Information:: Journal of the American Chemical Society, Vol. 139, Issue 36; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 120 works

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References (49)

Recent Advances in Singlet Fission Smith, Millicent B.; Michl, Josef Annual Review of Physical Chemistry, Vol. 64, Issue 1 https://doi.org/10.1146/annurev-physchem-040412-110130	journal	April 2013
Singlet Fission Smith, Millicent B.; Michl, Josef Chemical Reviews, Vol. 110, Issue 11 https://doi.org/10.1021/cr1002613	journal	November 2010
Solar conversion efficiency of photovoltaic and photoelectrolysis cells with carrier multiplication absorbers Hanna, M. C.; Nozik, A. J. Journal of Applied Physics, Vol. 100, Issue 7 https://doi.org/10.1063/1.2356795	journal	October 2006
Thermodynamic Limit of Exciton Fission Solar Cell Efficiency Tayebjee, Murad J. Y.; Gray-Weale, Angus A.; Schmidt, Timothy W. The Journal of Physical Chemistry Letters, Vol. 3, Issue 19 https://doi.org/10.1021/jz301069u	journal	September 2012
Semi-Empirical Limiting Efficiency of Singlet-Fission-Capable Polyacene/Inorganic Hybrid Solar Cells Tayebjee, M. J. Y.; Mahboubi Soufiani, A.; Conibeer, G. J. The Journal of Physical Chemistry C, Vol. 118, Issue 5 https://doi.org/10.1021/jp4101637	journal	January 2014
Beyond Shockley–Queisser: Molecular Approaches to High-Efficiency Photovoltaics Tayebjee, Murad J. Y.; McCamey, Dane R.; Schmidt, Timothy W. The Journal of Physical Chemistry Letters, Vol. 6, Issue 12 https://doi.org/10.1021/acs.jpclett.5b00716	journal	June 2015
Correlating Structure and Function in Organic Electronics: From Single Molecule Transport to Singlet Fission Low, Jonathan Z.; Sanders, Samuel N.; Campos, Luis M. Chemistry of Materials, Vol. 27, Issue 16 https://doi.org/10.1021/cm502366x	journal	August 2015
Singlet fission in pentacene dimers Zirzlmeier, Johannes; Lehnherr, Dan; Coto, Pedro B. Proceedings of the National Academy of Sciences, Vol. 112, Issue 17 https://doi.org/10.1073/pnas.1422436112	journal	April 2015
Intramolecular Singlet Fission in Oligoacene Heterodimers Sanders, Samuel N.; Kumarasamy, Elango; Pun, Andrew B. Angewandte Chemie International Edition, Vol. 55, Issue 10 https://doi.org/10.1002/anie.201510632	journal	February 2016
Quantitative Intramolecular Singlet Fission in Bipentacenes Sanders, Samuel N.; Kumarasamy, Elango; Pun, Andrew B. Journal of the American Chemical Society, Vol. 137, Issue 28 https://doi.org/10.1021/jacs.5b04986	journal	July 2015
Tuneable Singlet Exciton Fission and Triplet-Triplet Annihilation in an Orthogonal Pentacene Dimer Lukman, Steven; Musser, Andrew J.; Chen, Kai Advanced Functional Materials, Vol. 25, Issue 34 https://doi.org/10.1002/adfm.201501537	journal	August 2015
Singlet Fission in a Covalently Linked Cofacial Alkynyltetracene Dimer Korovina, Nadezhda V.; Das, Saptaparna; Nett, Zachary Journal of the American Chemical Society, Vol. 138, Issue 2 https://doi.org/10.1021/jacs.5b10550	journal	January 2016
Long-Lived Triplet Excited States of Bent-Shaped Pentacene Dimers by Intramolecular Singlet Fission Sakuma, Takao; Sakai, Hayato; Araki, Yasuyuki The Journal of Physical Chemistry A, Vol. 120, Issue 11 https://doi.org/10.1021/acs.jpca.6b00988	journal	March 2016
Fast Singlet Exciton Decay in Push–Pull Molecules Containing Oxidized Thiophenes Busby, Erik; Xia, Jianlong; Low, Jonathan Z. The Journal of Physical Chemistry B, Vol. 119, Issue 24 https://doi.org/10.1021/jp511704r	journal	December 2014
A design strategy for intramolecular singlet fission mediated by charge-transfer states in donor–acceptor organic materials Busby, Erik; Xia, Jianlong; Wu, Qin Nature Materials, Vol. 14, Issue 4 https://doi.org/10.1038/nmat4175	journal	January 2015
High Yield Ultrafast Intramolecular Singlet Exciton Fission in a Quinoidal Bithiophene Varnavski, Oleg; Abeyasinghe, Neranga; Aragó, Juan The Journal of Physical Chemistry Letters, Vol. 6, Issue 8 https://doi.org/10.1021/acs.jpclett.5b00198	journal	April 2015
Ultrafast Singlet Fission in a Push–Pull Low-Bandgap Polymer Film Kasai, Yukitomo; Tamai, Yasunari; Ohkita, Hideo Journal of the American Chemical Society, Vol. 137, Issue 51 https://doi.org/10.1021/jacs.5b09361	journal	December 2015
Singlet Fission: Progress and Prospects in Solar Cells Xia, Jianlong; Sanders, Samuel N.; Cheng, Wei Advanced Materials, Vol. 29, Issue 20 https://doi.org/10.1002/adma.201601652	journal	December 2016
Exploring Non-Condon Effects in a Covalent Tetracene Dimer: How Important Are Vibrations in Determining the Electronic Coupling for Singlet Fission? Alguire, Ethan C.; Subotnik, Joseph E.; Damrauer, Niels H. The Journal of Physical Chemistry A, Vol. 119, Issue 2 https://doi.org/10.1021/jp510777c	journal	December 2014
Solution-Phase Singlet Fission in a Structurally Well-Defined Norbornyl-Bridged Tetracene Dimer Cook, Jasper D.; Carey, Thomas J.; Damrauer, Niels H. The Journal of Physical Chemistry A, Vol. 120, Issue 26 https://doi.org/10.1021/acs.jpca.6b04367	journal	June 2016
Tunable Electronic Coupling and Driving Force in Structurally Well-Defined Tetracene Dimers for Molecular Singlet Fission: A Computational Exploration Using Density Functional Theory Vallett, Paul J.; Snyder, Jamie L.; Damrauer, Niels H. The Journal of Physical Chemistry A, Vol. 117, Issue 42 https://doi.org/10.1021/jp407426q	journal	September 2013
Synthesis of Geometrically Well-Defined Covalent Acene Dimers for Mechanistic Exploration of Singlet Fission Carey, Thomas J.; Snyder, Jamie L.; Miller, Ethan G. The Journal of Organic Chemistry, Vol. 82, Issue 9 https://doi.org/10.1021/acs.joc.7b00602	journal	April 2017
Unified model for singlet fission within a non-conjugated covalent pentacene dimer Basel, Bettina S.; Zirzlmeier, Johannes; Hetzer, Constantin Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15171	journal	May 2017
A transferable model for singlet-fission kinetics Yost, Shane R.; Lee, Jiye; Wilson, Mark W. B. Nature Chemistry, Vol. 6, Issue 6 https://doi.org/10.1038/nchem.1945	journal	May 2014
Singlet Fission via an Excimer-Like Intermediate in 3,6-Bis(thiophen-2-yl)diketopyrrolopyrrole Derivatives Mauck, Catherine M.; Hartnett, Patrick E.; Margulies, Eric A. Journal of the American Chemical Society, Vol. 138, Issue 36 https://doi.org/10.1021/jacs.6b05627	journal	August 2016
Singlet Exciton Fission in Thin Films of tert -Butyl-Substituted Terrylenes Eaton, Samuel W.; Miller, Stephen A.; Margulies, Eric A. The Journal of Physical Chemistry A, Vol. 119, Issue 18 https://doi.org/10.1021/acs.jpca.5b02719	journal	April 2015
Two Thin Film Polymorphs of the Singlet Fission Compound 1,3-Diphenylisobenzofuran Ryerson, Joseph L.; Schrauben, Joel N.; Ferguson, Andrew J. The Journal of Physical Chemistry C, Vol. 118, Issue 23 https://doi.org/10.1021/jp502122d	journal	May 2014
Different Rates of Singlet Fission in Monoclinic versus Orthorhombic Crystal Forms of Diphenylhexatriene Dillon, Robert J.; Piland, Geoffrey B.; Bardeen, Christopher J. Journal of the American Chemical Society, Vol. 135, Issue 46 https://doi.org/10.1021/ja409266s	journal	November 2013
Molecular Packing Determines Singlet Exciton Fission in Organic Semiconductors Kolata, Kolja; Breuer, Tobias; Witte, Gregor ACS Nano, Vol. 8, Issue 7 https://doi.org/10.1021/nn502544d	journal	June 2014
Maximizing Singlet Fission by Intermolecular Packing Wang, Linjun; Olivier, Yoann; Prezhdo, Oleg V. The Journal of Physical Chemistry Letters, Vol. 5, Issue 19 https://doi.org/10.1021/jz5015955	journal	September 2014
Aqueous Colloidal Acene Nanoparticles: A New Platform for Studying Singlet Fission Mastron, Joseph N.; Roberts, Sean T.; McAnally, R. Eric The Journal of Physical Chemistry B, Vol. 117, Issue 49 https://doi.org/10.1021/jp4057972	journal	July 2013
Efficient Singlet Fission Discovered in a Disordered Acene Film Roberts, Sean T.; McAnally, R. Eric; Mastron, Joseph N. Journal of the American Chemical Society, Vol. 134, Issue 14 https://doi.org/10.1021/ja300504t	journal	March 2012
Tuning the role of charge-transfer states in intramolecular singlet exciton fission through side-group engineering Lukman, Steven; Chen, Kai; Hodgkiss, Justin M. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13622	journal	December 2016
A Covalently Linked Tetracene Trimer: Synthesis and Singlet Exciton Fission Property Liu, Heyuan; Wang, Rui; Shen, Li Organic Letters, Vol. 19, Issue 3 https://doi.org/10.1021/acs.orglett.6b03739	journal	January 2017
A Direct Mechanism of Ultrafast Intramolecular Singlet Fission in Pentacene Dimers Fuemmeler, Eric G.; Sanders, Samuel N.; Pun, Andrew B. ACS Central Science, Vol. 2, Issue 5 https://doi.org/10.1021/acscentsci.6b00063	journal	May 2016
Tuning Conductance in π–σ–π Single-Molecule Wires Su, Timothy A.; Li, Haixing; Klausen, Rebekka S. Journal of the American Chemical Society, Vol. 138, Issue 24 https://doi.org/10.1021/jacs.6b04394	journal	June 2016
Electronic Absorption Spectra of Neutral Pentacene (C ₂₂ H ₁₄ ) and Its Positive and Negative Ions in Ne, Ar, and Kr Matrices Halasinski, Thomas M.; Hudgins, Douglas M.; Salama, Farid The Journal of Physical Chemistry A, Vol. 104, Issue 32 https://doi.org/10.1021/jp0011544	journal	August 2000
Microscopic theory of singlet exciton fission. II. Application to pentacene dimers and the role of superexchange Berkelbach, Timothy C.; Hybertsen, Mark S.; Reichman, David R. The Journal of Chemical Physics, Vol. 138, Issue 11 https://doi.org/10.1063/1.4794427	journal	March 2013
Quintet multiexciton dynamics in singlet fission Tayebjee, Murad J. Y.; Sanders, Samuel N.; Kumarasamy, Elango Nature Physics, Vol. 13, Issue 2 https://doi.org/10.1038/nphys3909	journal	October 2016
Exciton Correlations in Intramolecular Singlet Fission Sanders, Samuel N.; Kumarasamy, Elango; Pun, Andrew B. Journal of the American Chemical Society, Vol. 138, Issue 23 https://doi.org/10.1021/jacs.6b00657	journal	June 2016
Singlet Fission in Polypentacene Sanders, Samuel N.; Kumarasamy, Elango; Pun, Andrew B. Chem, Vol. 1, Issue 3 https://doi.org/10.1016/j.chempr.2016.08.016	journal	September 2016
Direct Observation of a Charge-Transfer State Preceding High-Yield Singlet Fission in Terrylenediimide Thin Films Margulies, Eric A.; Logsdon, Jenna L.; Miller, Claire E. Journal of the American Chemical Society, Vol. 139, Issue 2 https://doi.org/10.1021/jacs.6b07721	journal	December 2016
Distinct properties of the triplet pair state from singlet fission Trinh, M. Tuan; Pinkard, Andrew; Pun, Andrew B. Science Advances, Vol. 3, Issue 7 https://doi.org/10.1126/sciadv.1700241	journal	July 2017
Properties of Poly- and Oligopentacenes Synthesized from Modular Building Blocks Kumarasamy, Elango; Sanders, Samuel N.; Pun, Andrew B. Macromolecules, Vol. 49, Issue 4 https://doi.org/10.1021/acs.macromol.5b02711	journal	February 2016
Localization length scales of triplet excitons in singlet fission materials Bayliss, Sam L.; Thorley, Karl J.; Anthony, John E. Physical Review B, Vol. 92, Issue 11 https://doi.org/10.1103/PhysRevB.92.115432	journal	September 2015
An EPR study of the triplet state of pentacene by electron spin-echo techniques and laser flash excitation Van Strien, A. J.; Schmidt, J. Chemical Physics Letters, Vol. 70, Issue 3 https://doi.org/10.1016/0009-2614(80)80115-1	journal	March 1980
Comments on exciton fission and electron spin resonance in tetracene single crystals Swenberg, C. E.; van Metter, R.; Ratner, M. Chemical Physics Letters, Vol. 16, Issue 3 https://doi.org/10.1016/0009-2614(72)80405-6	journal	October 1972
Strongly exchange-coupled triplet pairs in an organic semiconductor Weiss, Leah R.; Bayliss, Sam L.; Kraffert, Felix Nature Physics, Vol. 13, Issue 2 https://doi.org/10.1038/nphys3908	journal	October 2016
Singlet exciton fission in solution Walker, Brian J.; Musser, Andrew J.; Beljonne, David Nature Chemistry, Vol. 5, Issue 12 https://doi.org/10.1038/nchem.1801	journal	November 2013

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Singlet Fission
Homoconjugated Dimers
Non-Conjugated
Organic Electronics
Pentacene Dimers
Electron Spin Resonance
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CCDC 1579912: Experimental Crystal Structure Determination: ECIWUL : {bicyclo[2.2.2]octane-1,4-diylbis[(pentacene-2,6,13-triyl)bis(ethyne-2,1-diyl)]}tetrakis[tris(propan-2-yl)silane] Kumarasamy, Elango; Sanders, Samuel N.; Tayebjee, Murad J. Y. https://doi.org/10.5517/ccdc.csd.cc1q10xp The current record is supplemented by this dataset	dataset	October 2017
CCDC 1579913: Experimental Crystal Structure Determination: ECIXAS : {(1,1,1,3,3,3-hexafluoropropane-2,2-diyl)bis[(pentacene-2,6,13-triyl)bis(ethyne-2,1-diyl)]}tetrakis[tris(propan-2-yl)silane] Space Group: C 2/c (15), Cell: a 26.5637(5)Å b 7.89746(9)Å c 41.3109(9)Å, α 90° β 106.605(2)° γ 90° Kumarasamy, Elango; Sanders, Samuel N.; Tayebjee, Murad J. Y. https://doi.org/10.5517/ccdc.csd.cc1q10yq The current record is supplemented by this dataset	dataset	October 2017