NH3-SCR on Cu, Fe and Cu + Fe exchanged beta and SSZ-13 catalysts: Hydrothermal aging and propylene poisoning effects

Wang, Aiyong; Wang, Yilin; Walter, Eric D.; Washton, Nancy M.; Guo, Yanglong; Lu, Guanzhong; Peden, Charles H. F.; Gao, Feng

doi:10.1016/J.CATTOD.2017.09.061

NH₃-SCR on Cu, Fe and Cu + Fe exchanged beta and SSZ-13 catalysts: Hydrothermal aging and propylene poisoning effects

Journal Article · Sat Oct 07 00:00:00 EDT 2017 · Catalysis Today

DOI:https://doi.org/10.1016/J.CATTOD.2017.09.061· OSTI ID:1413492

Wang, Aiyong ^[1]; Wang, Yilin ^[2]; Walter, Eric D. ^[2]; Washton, Nancy M. ^[2]; Guo, Yanglong ^[3]; Lu, Guanzhong ^[3]; Peden, Charles H. F. ^[2]; Gao, Feng ^[2]

East China Univ. of Science of Technology, Shanghai (China); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
East China Univ. of Science of Technology, Shanghai (China)

Cu, Fe and Cu + Fe ion exchanged Beta and SSZ-13 catalysts were prepared by solution ion exchange using commercial NH₄/Beta, and NH₄/SSZ-13 that was prepared in-house. To study hydrothermal aging effects, Beta supported catalysts were aged hydrothermally at 700 °C and SSZ-13 supported catalysts were aged at 750 °C. In order to reveal the effects of Fe addition in the co-exchanged catalysts, these catalysts were characterized by means of powder X-ray diffraction (XRD), N₂ adsorption-desorption, electron paramagnetic resonance (EPR), ²⁷Al-nuclear magnetic resonance (²⁷Al-NMR) and propylene coking followed with temperature programmed reaction (TPR), and further tested with standard NH₃-SCR with and without the presence of propylene. Collectively, the catalyst characterizations and reaction testing indicated minor beneficial effects of Fe addition in Cu,Fe/Beta, where NH₃-SCR activity, N₂ selectivity and hydrothermal stability were all slightly improved. In contrast, Fe addition did not show apparent beneficial effects in low-temperature SCR for the Cu,Fe/SSZ-13 case. In conclusion, at elevated reaction temperatures, however, the presence of Fe indeed considerably improved NO conversion and N₂ selectivity for the hydrothermally aged Cu,Fe/SSZ-13 catalyst in the presence of propylene.

View Accepted Manuscript (DOE)

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1413492

Alternate ID(s):: OSTI ID: 1701853
OSTI ID: 1582602

Report Number(s):: PNNL-SA--128427; PII: S0920586117306764

Journal Information:: Catalysis Today, Journal Name: Catalysis Today Vol. 320; ISSN 0920-5861

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Beta
Cu
Fe
NH3-SCR
SSZ-13