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Title: Bond breakage under pressure in a metal organic framework

Journal Article · · Chemical Science
DOI:https://doi.org/10.1039/C7SC03786D· OSTI ID:1413306
 [1];  [2]; ORCiD logo [3]; ORCiD logo [3]; ORCiD logo [2]
  1. Department of Chemistry; University of Illinois at Urbana-Champaign; Urbana; USA; School of Chemistry and Materials Science
  2. Department of Chemistry; University of Illinois at Urbana-Champaign; Urbana; USA
  3. Davidson School of Chemical Engineering; Purdue University; West Lafayette; USA

The internal free volume of porous materials diminishes upon mechanical compression, and such volume collapse can have chemical consequences.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
U.S. OFFICE OF NAVAL RESEARCHOTHER
OSTI ID:
1413306
Journal Information:
Chemical Science, Vol. 8, Issue 12; ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
ENGLISH

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  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953
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