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Title: Mineralogy, provenance, and diagenesis of a potassic basaltic sandstone on Mars: CheMin X-ray diffraction of the Windjana sample (Kimberley area, Gale Crater)

Journal Article · · Journal of Geophysical Research. Planets
DOI:https://doi.org/10.1002/2015JE004932· OSTI ID:1412866
 [1];  [2];  [3];  [4];  [5];  [6];  [6];  [5];  [7];  [8];  [6];  [7];  [9];  [10];  [11];  [12];  [13];  [14]; ORCiD logo [15];  [16] more »;  [2];  [17];  [18];  [7];  [8];  [19];  [20];  [8];  [21];  [12];  [8];  [22];  [20];  [20] « less
  1. Lunar and Planetary Inst., Houston, TX (United States)
  2. Indiana Univ., Bloomington, IN (United States). Dept. of Geological Sciences
  3. Planetary Science Inst., Tucson, AZ (United States)
  4. Chesapeake Energy Corporation, Oklahoma City, OK (United States)
  5. NASA Ames Research Center (ARC), Moffett Field, Mountain View, CA (United States)
  6. NASA Johnson Space Center, Houston, TX (United States). Astromaterials Research and Exploration Science Division
  7. Univ. of Arizona, Tucson, AZ (United States). Dept. of Geosciences
  8. California Inst. of Technology (CalTech), Pasadena, CA (United States). Division of Geologic and Planetary Sciences
  9. Southern Illinois Univ., Carbondale, IL (United States). Dept. of Geology
  10. Univ. of North Carolina, Chapel Hill, NC (United States). Dept. of Geological Sciences
  11. Univ. of Guelf, Guelf, ON (Canada). Dept. of Physics
  12. Univ. of New Brunswick, Fredericton NB (Canada). Dept. of Earth Sciences
  13. Brock Univ., St. Catharines, ON (Canada). Dept. of Earth Sciences
  14. Unvi. de Nantes, Nantes (France). Laboratoire Planetologie et Geodynamique de Nantes (LPGN/CNRS)
  15. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  16. NASA Goddard Space Flight Center (GSFC), Greenbelt, MD (United States)
  17. Malin Space Science Systems, Inc., San Diego, CA (United States)
  18. Arizona State Univ., Tempe, AZ (United States). School of Earth and Space Exploration
  19. Imperial College, London (United Kingdom). Dept. of Earth Science and Engineering
  20. California Inst. of Technology (CalTech), Pasadena, CA (United States). Jet Propulsion Lab.
  21. Western Washington Univ., Bellingham, WA (United States). Dept. of Earth Sciences
  22. Univ. of California, Davis, CA (United States). Dept. of of Earth and Planetary Sciences

The Windjana drill sample, a sandstone of the Dillinger member (Kimberley formation, Gale Crater, Mars), was analyzed by CheMin X-ray diffraction (XRD) in the MSL Curiosity rover. From Rietveld refinements of its XRD pattern, Windjana contains the following: sanidine (21% weight, ~Or95); augite (20%); magnetite (12%); pigeonite; olivine; plagioclase; amorphous and smectitic material (~25%); and percent levels of others including ilmenite, fluorapatite, and bassanite. From mass balance on the Alpha Proton X-ray Spectrometer (APXS) chemical analysis, the amorphous material is Fe rich with nearly no other cations—like ferrihydrite. The Windjana sample shows little alteration and was likely cemented by its magnetite and ferrihydrite. From ChemCam Laser-Induced Breakdown Spectrometer (LIBS) chemical analyses, Windjana is representative of the Dillinger and Mount Remarkable members of the Kimberley formation. LIBS data suggest that the Kimberley sediments include at least three chemical components. The most K-rich targets have 5.6% K2O, ~1.8 times that of Windjana, implying a sediment component with >40% sanidine, e.g., a trachyte. A second component is rich in mafic minerals, with little feldspar (like a shergottite). A third component is richer in plagioclase and in Na2O, and is likely to be basaltic. The K-rich sediment component is consistent with APXS and ChemCam observations of K-rich rocks elsewhere in Gale Crater. The source of this sediment component was likely volcanic. Finally, the presence of sediment from many igneous sources, in concert with Curiosity's identifications of other igneous materials (e.g., mugearite), implies that the northern rim of Gale Crater exposes a diverse igneous complex, at least as diverse as that found in similar-age terranes on Earth.

Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
National Aeronautics and Space Administration (NASA); USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
AC52-06NA25396
OSTI ID:
1412866
Report Number(s):
LA-UR-17-27709; TRN: US1800381
Journal Information:
Journal of Geophysical Research. Planets, Vol. 121, Issue 1; ISSN 2169-9097
Publisher:
American Geophysical UnionCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 144 works
Citation information provided by
Web of Science

References (140)

Sulfur-bearing phases detected by evolved gas analysis of the Rocknest aeolian deposit, Gale Crater, Mars: ROCKNEST SULFUR PHASES DETECTED BY SAM journal February 2014
Magmatic salt melt and vapor: Extreme fluids forming porphyry gold deposits in shallow subvolcanic settings journal June 2014
The Influence of Aluminum on Iron Oxides: XIV. Al-Substituted Magnetite Synthesized at Ambient Temperatures journal January 1990
Contributions of gamma-ray spectrometry to terrestrial impact crater studies: The example of Serra da Cangalha, northeastern Brazil: GAMMA-RAY SPECTROMETRY OF IMPACT CRATER journal February 2012
FULLPAT : a full-pattern quantitative analysis program for X-ray powder diffraction using measured and calculated patterns journal November 2002
Hydrothermal processes associated with meteorite impact structures: evidence from three Australian examples and implications for economic resources journal September 2005
The Sample Analysis at Mars Investigation and Instrument Suite journal April 2012
Late Archaean felsic alkaline igneous rocks in the Eastern Goldfields, Yilgarn Craton, Western Australia: a result of lower crustal delamination? journal May 1999
Chemistry and texture of the rocks at Rocknest, Gale Crater: Evidence for sedimentary origin and diagenetic alteration: ROCKNEST CHEMISTRY AND TEXTURE journal September 2014
Igneous mineralogy at Bradbury Rise: The first ChemCam campaign at Gale crater: IGNEOUS MINERALOGY AT BRADBURY RISE journal January 2014
Mineralogy of a Mudstone at Yellowknife Bay, Gale Crater, Mars journal December 2013
A Habitable Fluvio-Lacustrine Environment at Yellowknife Bay, Gale Crater, Mars journal December 2013
The importance of fractional crystallization and magma mixing in controlling chemical differentiation at Süphan stratovolcano, eastern Anatolia, Turkey journal February 2011
In Situ Radiometric and Exposure Age Dating of the Martian Surface journal December 2013
K 2 O-rich trapped melt in olivine in the Nakhla meteorite: Implications for petrogenesis of nakhlites and evolution of the Martian mantle journal December 2013
Characterization and petrologic interpretation of olivine-rich basalts at Gusev Crater, Mars: OLIVINE-RICH BASALTS AT GUSEV CRATER, MARS journal January 2006
MINCRYST: A crystallographic database for minerals, local and network (WWW) versions journal September 2001
A-type granites and related rocks: Evolution of a concept, problems and prospects journal August 2007
Sequence of infilling events in Gale Crater, Mars: Results from morphology, stratigraphy, and mineralogy: SEDIMENTARY INFILLING IN GALE CRATER journal December 2013
Chlorine Occupancy Dependence of Crystal Structure of Pure β-Phase of Iron-Oxyhydroxide journal January 2010
Elemental Geochemistry of Sedimentary Rocks at Yellowknife Bay, Gale Crater, Mars journal December 2013
Origin and age of the earliest Martian crust from meteorite NWA 7533 journal November 2013
Origin of Exceptionally Abundant Phonolites on Ua Pou Island (Marquesas, French Polynesia): Partial Melting of Basanites Followed by Crustal Contamination journal May 2005
Alteration minerals in impact-generated hydrothermal systems – Exploring host rock variability journal September 2013
High pressure single-crystal micro X-ray diffraction analysis with GSE_ADA/RSV software journal August 2013
Determination of nanoparticulate magnetite stoichiometry by Mossbauer spectroscopy, acidic dissolution, and powder X-ray diffraction: A critical review journal June 2010
The Hadean Crust: Evidence from >4 Ga Zircons journal May 2009
The origin and evolution of the Peace Vallis fan system that drains to the Curiosity landing area, Gale Crater, Mars : Origin and evolution of Peace Vallis fan journal April 2014
Mars Science Laboratory Mission and Science Investigation journal July 2012
Low heat flow inferred from >4 Gyr zircons suggests Hadean plate boundary interactions journal November 2008
Calcium sulfate veins characterized by ChemCam/Curiosity at Gale crater, Mars: CALCIUM SULFATE VEINS AT GALE CRATER journal September 2014
From Fe(III) Ions to Ferrihydrite and then to Hematite journal January 1999
Mantle Fluid Compositions Buffered by Carbonates in Peridotite-$$CO_{2}-H_{2}O$$ journal March 1977
β-FeOOH · Cln (akaganéite) and Fe1-xO (wüstite) in hot brine from the Atlantis II Deep (Red Sea) and the uptake of amino acids by synthetic β-FeOOH · Cln journal August 1983
Magnetic hysteresis properties, Mössbauer spectra and structural data of spherical 250nm particles of solid solutions –- journal February 2006
Geochemical diversity of shergottite basalts: Mixing and fractionation, and their relation to Mars surface basalts journal October 2014
Oxide melt solution calorimetry of Fe2+-bearing oxides and application to the magnetite-maghemite (Fe3O4-Fe8/3O4) system journal January 2012
Detection of copiapite in the northern Mawrth Vallis region of Mars: Evidence of acid sulfate alteration journal October 2014
Sedimentary rocks at Meridiani Planum: Origin, diagenesis, and implications for life on Mars journal November 2005
Unique Meteorite from Early Amazonian Mars: Water-Rich Basaltic Breccia Northwest Africa 7034 journal January 2013
Collecting Samples in Gale Crater, Mars; an Overview of the Mars Science Laboratory Sample Acquisition, Sample Processing and Handling System journal June 2012
Unraveling the effects of potassium metasomatism in sedimentary rocks and paleosols, with implications for paleoweathering conditions and provenance journal January 1995
The Mars Science Laboratory scooping campaign at Rocknest journal August 2015
Curiosity at Gale Crater, Mars: Characterization and Analysis of the Rocknest Sand Shadow journal September 2013
Curiosity's Mission of Exploration at Gale Crater, Mars journal February 2015
An occurrence of a fully-oxidized natural titanomaghemite in basalt journal June 1989
Calculation of T -site occupancies in alkali feldspar from refined lattice constants journal December 1977
Crystal chemistry of the magnetite-ulvospinel series journal January 2009
Diagenesis in first-cycle desert alluvium of Cenozoic age, southwestern United States and northwestern Mexico journal January 1978
Ancient plutonic processes on Mars inferred from the detection of possible anorthositic terrains journal November 2013
Prolonged magmatic activity on Mars inferred from the detection of felsic rocks journal November 2013
Episodic potassic diagenesis of Ordovician tuffs in the Mississippi Valley area journal January 1988
Petrology of igneous clasts in Northwest Africa 7034: Implications for the petrologic diversity of the martian crust journal May 2015
Syngenetic Sanidine Beds from Middle Ordovician Saint Peter Sandstone, Wisconsin journal May 1972
The Petrochemistry of Jake_M: A Martian Mugearite journal September 2013
Water and the composition of Martian magmas journal July 2013
Synthesis and Anion Exchange of Tunnel Structure Akaganeite journal December 2001
An integrated view of the chemistry and mineralogy of martian soils journal July 2005
The Role of Pressure in Producing Compositional Diversity in Intraplate Basaltic Magmas journal November 2006
Ferrian saponite from the Santa Monica Mountains (California, U.S.A., Earth): Characterization as an analog for clay minerals on Mars with application to Yellowknife Bay in Gale Crater journal November 2014
X-ray Diffraction Results from Mars Science Laboratory: Mineralogy of Rocknest at Gale Crater journal September 2013
Core formation in the Earth and Shergottite Parent Body (SPB): Chemical evidence from basalts journal June 1986
Miocene potassium metasomatism, Whipple Mountains, southeastern California: A datable tracer of extension-related fluid transport journal January 1999
The composition of near-solidus melts of peridotite in the presence of CO2 and H2O between 40 and 60 kbar journal November 2009
Alkalic parental magmas for chassignites? journal June 2007
Volatiles on Earth and Mars: A comparison journal August 1987
In situ evidence for continental crust on early Mars journal July 2015
A cool early Earth journal January 2002
Geochemical diversity in first rocks examined by the Curiosity Rover in Gale Crater: Evidence for and significance of an alkali and volatile-rich igneous source: FIRST ROCKS EXAMINED BY THE CURIOSITY ROVER IN GALE CRATER journal January 2014
Oxidative dissolution of 4C- and NC-pyrrhotite: Intrinsic reactivity differences, pH dependence, and the effect of anisotropy journal February 2013
Fe2+–Mg partitioning between olivine and basaltic melts: Applications to genesis of olivine-phyric shergottites and conditions of melting in the Martian interior journal April 2011
The bulk composition of Mars journal December 2013
The Mountain pass Rare-Earth Carbonatite and Associated Ultrapotassic Rocks, California journal August 2008
ChemCam results from the Shaler outcrop in Gale crater, Mars journal March 2015
Alkaline magmatism and enriched mantle reservoirs: Mechanisms, time, and depth of formation journal January 2006
Geology and Age of the Late Archean Keivy Alkaline Province, Northeastern Baltic Shield journal September 2005
The Petrology and Geochemistry of Lavas from the Western Azores Islands of Flores and Corvo journal June 2012
Mineralogy at Gusev Crater from the Mossbauer Spectrometer on the Spirit Rover journal August 2004
Geochemical properties of rocks and soils in Gusev Crater, Mars: Results of the Alpha Particle X-Ray Spectrometer from Cumberland Ridge to Home Plate journal January 2008
Direct observation of spinodal decomposition in the magnetite-hercynite system by susceptibility measurements and transmission electron microscopy journal August 2005
Inventory of H 2 O in the ancient Martian regolith from Northwest Africa 7034: The important role of Fe oxides journal December 2014
Petrography and composition of Martian regolith breccia meteorite Northwest Africa 7475 journal February 2015
Akaganeite and schwertmannite: Spectral properties and geochemical implications of their possible presence on Mars journal April 2015
ChemCam: Chemostratigraphy by the First Mars Microprobe journal February 2015
Interpretation of neovolcanic versus palaeovolcanic sand grains: an example from Miocene deep-marine sandstone of the Topanga Group (Southern California) journal October 1995
Characterization and Calibration of the CheMin Mineralogical Instrument on Mars Science Laboratory journal June 2012
Partial melt compositions of carbonated peridotite at 3 GPa and role of CO 2 in alkali-basalt magma generation journal November 1997
Formation age and metamorphic history of the Nuvvuagittuq Greenstone Belt journal November 2012
Constraints on the origin and evolution of the layered mound in Gale Crater, Mars using Mars Reconnaissance Orbiter data journal August 2011
Mantle derivation of Archean amphibole-bearing granitoid and associated mafic rocks: evidence from the southern Superior Province, Canada journal August 1990
Kalsilite-bearing plutonic rocks: The deep-seated Archean Awsard massif of the Reguibat Rise, South Morocco, West African Craton journal November 2014
Neodymium-142 Evidence for Hadean Mafic Crust journal September 2008
Partial Melting Experiments of Peridotite + CO2 at 3 GPa and Genesis of Alkalic Ocean Island Basalts journal October 2007
Martian meteorites and Martian magnetic anomalies: A new perspective from NWA 7034: Martian meteorites & magnetic anomalies journal July 2014
Stratigraphy, structure, and potassic alteration of Miocene volcanic rocks in the Sleeping Beauty area, central Mojave Desert, California journal March 1988
The petrological expression of early Mars volcanism: EARLY MARS VOLCANISM journal January 2013
The Origin and Evolution of Silica-saturated Alkalic Suites: an Experimental Study journal April 2004
High-temperature chlorine-rich fluid in the martian crust: A precursor to habitability journal September 2014
Vein-plus-wall-rock melting mechanisms in the lithosphere and the origin of potassic alkaline magmas journal November 1992
Crystallization experiments on a Gusev Adirondack basalt composition journal July 2008
Deposition, exhumation, and paleoclimate of an ancient lake deposit, Gale crater, Mars journal October 2015
Constraints on abundance, composition, and nature of X-ray amorphous components of soils and rocks at Gale crater, Mars: X-ray amorphous components at Gale journal December 2014
A-type granites of crustal origin ultimately result from open-system fenitization-type reactions in an extensional environment journal October 2006
Calibration of the Mars Science Laboratory Alpha Particle X-ray Spectrometer journal April 2012
Metasomatized Lithosphere and the Origin of Alkaline Lavas journal May 2008
Akaganéite (β-FeOOH) precipitation in inland acid sulfate soils of south-western New South Wales (NSW), Australia journal November 2011
Fenites Associated with Carbonatites journal August 2008
A Structural Model for Natural Siliceous Ferrihydrite journal January 1992
Petrogenetic linkages among Martian basalts: Implications based on trace element chemistry of olivine journal July 2008
A Study of Potash Fenitization around the Brent Crater, Ontario,—A Paleozoic Alkaline Complex journal May 1971
Effects of Metasomatism on Mineral Systems and Their Host Rocks: Alkali Metasomatism, Skarns, Greisens, Tourmalinites, Rodingites, Black-Wall Alteration and Listvenites book April 2012
Can crystallization of olivine tholeiite give rise to potassic rhyolites?—an experimental investigation journal June 2007
Thermal history of the Earth and its petrological expression journal March 2010
K-Ca-Ar systematics of authigenic sanidine from Waukau, Wisconsin, and the diffusivity of argon journal January 1986
Orbital detection and implications of akaganéite on Mars journal June 2015
Chronology, chemistry, and origin of trachytes from Hualalai Volcano, Hawaii: HUALALAI VOLCANO TRACHYTES journal September 2003
The occurrence of magnesioferrite-rich spinels in a trachyandesite from NE China journal October 2008
Allophane detection on Mars with Thermal Emission Spectrometer data and implications for regional-scale chemical weathering processes journal September 2012
Synthesis and structural state of K-feldspars in the system K[AlSi3O8]K[FeSi3O8] [Synthesis and structural state of K-feldspars in the system K[AlSi3O8]K[FeSi3O8]] journal August 2008
The origin and implications of clay minerals from Yellowknife Bay, Gale crater, Mars journal April 2015
Experimental melting of phlogopite-bearing mantle at 1 GPa: Implications for potassic magmatism journal July 2014
Iron-rich alkaline magmatism in the Archean Wawa greenstone belts (Ontario, Canada) journal October 2014
A thermodynamic model of Fe–Cr spinels journal June 2005
Experimental stability of magnesium sulfate hydrates that may be present on Mars journal January 2007
Metamorphism in the Martian crust journal July 2014
The ChemCam Instrument Suite on the Mars Science Laboratory (MSL) Rover: Body Unit and Combined System Tests journal June 2012
Melting of the primitive martian mantle at 0.5–2.2 GPa and the origin of basalts and alkaline rocks on Mars journal October 2015
Gale Crater: Formation and post-impact hydrous environments journal September 2012
Detrital-zircon geochronology and sedimentary provenance journal August 2011
The Range of Spinel Compositions in Terrestrial Mafic and Ultramafic Rocks journal December 2001
The Petrology and Geochemistry of St. Helena Alkali Basalts: Evaluation of the Oceanic Crust-recycling Model for HIMU OIB journal March 2011
Evidence for indigenous nitrogen in sedimentary and aeolian deposits from the Curiosity rover investigations at Gale crater, Mars journal March 2015
A crystallographic study of the system FeCr2O4Fe3O4 (Fe2+Fe3+xCr2−xO4) journal January 1972
Porphyry Copper Systems journal January 2010
Precambrian alkaline magmatism journal April 1996
Cation ordering in magnesioferrite, MgFe 2 O 4 , to 982 °C using in situ synchrotron X-ray powder diffraction journal January 2005
Silicate mineralogy of martian meteorites journal December 2009
ChemCam passive reflectance spectroscopy of surface materials at the Curiosity landing site, Mars journal March 2015
Chapter 10. Chlorites: Structures and Crystal Chemistry book January 1988
Chapter 3. Lattice Parameters, Composition and Al,Si Order in Alkali Feldspars book January 1983

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