Near-zero thermal expansion in magnetically ordered state in dysprosium at high pressures and low temperatures
Abstract
The atomic volume of rare earth metal Dysprosium (Dy) has been measured up to high pressures of 35 GPa and low temperatures between 200 K and 7 K in a diamond anvil cell using angle dispersive x-ray diffraction at a synchrotron source. The hexagonal close-packed (hcp), alpha-Samarium (α-Sm), and double hexagonal close packed (dhcp) phases are observed to be stable in Dy under high-pressure and low-temperature conditions achieved in our experiments. Dy is known to undergo magnetic ordering below 176 K at ambient pressure with magnetic ordering Néel temperature (T N) that changes rapidly with increasing pressure. Our experimental measurement shows that Dy has near-zero thermal expansion in the magnetically ordered state and normal thermal expansion in the paramagnetic state for all the three known high pressure phases (hcp, α-Sm, and dhcp) to 35 GPa. This near-zero thermal expansion behavior in Dy is observed below the magnetic ordering temperature T N at all pressures up to 35 GPa.
- Authors:
-
- Univ. of Montevallo, Montevallo, AL (United States). Dept. of Biology, Chemistry and Mathematics
- Univ. of Alabama, Birmingham, AL (United States). Dept. of Physics
- Publication Date:
- Research Org.:
- Univ. of Alabama, Birmingham, AL (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF)
- OSTI Identifier:
- 1412680
- Grant/Contract Number:
- NA0002928; NA0001974; FG02-99ER45775; AC02-06CH11357
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Cogent Physics
- Additional Journal Information:
- Journal Volume: 4; Journal Issue: 1; Journal ID: ISSN 2331-1940
- Publisher:
- Cogent OA
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Rare Earth Metals; High Pressures; Low Temperatures; Magnetic Ordering; Thermal Expansion
Citation Formats
Hope, Kevin M., Samudrala, Gopi K., and Vohra, Yogesh K. Near-zero thermal expansion in magnetically ordered state in dysprosium at high pressures and low temperatures. United States: N. p., 2017.
Web. doi:10.1080/23311940.2017.1412107.
Hope, Kevin M., Samudrala, Gopi K., & Vohra, Yogesh K. Near-zero thermal expansion in magnetically ordered state in dysprosium at high pressures and low temperatures. United States. https://doi.org/10.1080/23311940.2017.1412107
Hope, Kevin M., Samudrala, Gopi K., and Vohra, Yogesh K. Sun .
"Near-zero thermal expansion in magnetically ordered state in dysprosium at high pressures and low temperatures". United States. https://doi.org/10.1080/23311940.2017.1412107. https://www.osti.gov/servlets/purl/1412680.
@article{osti_1412680,
title = {Near-zero thermal expansion in magnetically ordered state in dysprosium at high pressures and low temperatures},
author = {Hope, Kevin M. and Samudrala, Gopi K. and Vohra, Yogesh K.},
abstractNote = {The atomic volume of rare earth metal Dysprosium (Dy) has been measured up to high pressures of 35 GPa and low temperatures between 200 K and 7 K in a diamond anvil cell using angle dispersive x-ray diffraction at a synchrotron source. The hexagonal close-packed (hcp), alpha-Samarium (α-Sm), and double hexagonal close packed (dhcp) phases are observed to be stable in Dy under high-pressure and low-temperature conditions achieved in our experiments. Dy is known to undergo magnetic ordering below 176 K at ambient pressure with magnetic ordering Néel temperature (TN) that changes rapidly with increasing pressure. Our experimental measurement shows that Dy has near-zero thermal expansion in the magnetically ordered state and normal thermal expansion in the paramagnetic state for all the three known high pressure phases (hcp, α-Sm, and dhcp) to 35 GPa. This near-zero thermal expansion behavior in Dy is observed below the magnetic ordering temperature TN at all pressures up to 35 GPa.},
doi = {10.1080/23311940.2017.1412107},
url = {https://www.osti.gov/biblio/1412680},
journal = {Cogent Physics},
issn = {2331-1940},
number = 1,
volume = 4,
place = {United States},
year = {2017},
month = {1}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Crystal Structure of Dysprosium at Low Temperatures
journal, April 1963
- Darnell, F. J.; Moore, E. P.
- Journal of Applied Physics, Vol. 34, Issue 4
Temperature dependence of the ruby luminescence method for measuring high pressures
journal, December 1992
- Yen, J.; Nicol, M.
- Journal of Applied Physics, Vol. 72, Issue 12
Anomalous Thermal Expansion and Magnetostriction of Single-Crystal Dysprosium
journal, April 1965
- Clark, A. E.; DeSavage, B. F.; Bozorth, R.
- Physical Review, Vol. 138, Issue 1A
Some Magnetic and Electrical Properties of Gadolinium, Dysprosium, and Erbium Metals
journal, January 1953
- Legvold, S.; Spedding, F. H.; Barson, F.
- Reviews of Modern Physics, Vol. 25, Issue 1
Neutron diffraction and electrical transport studies on magnetic ordering in terbium at high pressures and low temperatures
journal, August 2013
- Thomas, Sarah A.; Montgomery, Jeffrey M.; Tsoi, Georgiy M.
- High Pressure Research, Vol. 33, Issue 3
Correlation between -Band Occupancy and Crystal Structure in the Rare Earths
journal, March 1977
- Duthie, J. C.; Pettifor, D. G.
- Physical Review Letters, Vol. 38, Issue 10
Generalized phase diagram for the rare-earth elements: Calculations and correlations of bulk properties
journal, April 1975
- Johansson, Börje; Rosengren, Anders
- Physical Review B, Vol. 11, Issue 8
Neutron Diffraction Investigation of Magnetic Ordering in Dysprosium
journal, March 1961
- Wilkinson, M. K.; Koehler, W. C.; Wollan, E. O.
- Journal of Applied Physics, Vol. 32, Issue 3
EXPGUI , a graphical user interface for GSAS
journal, April 2001
- Toby, Brian H.
- Journal of Applied Crystallography, Vol. 34, Issue 2
Magnetic ordering temperatures in rare earth metal dysprosium under ultrahigh pressures
journal, April 2014
- Samudrala, Gopi K.; Tsoi, Georgiy M.; Weir, Samuel T.
- High Pressure Research, Vol. 34, Issue 2