Atomic-layered Au clusters on α-MoC as catalysts for the low-temperature water-gas shift reaction

Yao, Siyu; Zhang, Xiao; Zhou, Wu; Gao, Rui; Xu, Wenqian; Ye, Yifan; Lin, Lili; Wen, Xiaodong; Liu, Ping; Chen, Bingbing; Crumlin, Ethan; Guo, Jinghua; Zuo, Zhijun; Li, Weizhen; Xie, Jinglin; Lu, Li; Kiely, Christopher J.; Gu, Lin; Shi, Chuan; Rodriguez, Jose A.; Ma, Ding

doi:10.1126/science.aah4321

Atomic-layered Au clusters on α-MoC as catalysts for the low-temperature water-gas shift reaction

Journal Article · Thu Jun 22 00:00:00 EDT 2017 · Science

DOI:https://doi.org/10.1126/science.aah4321· OSTI ID:1411142

^[1]; ^[2]; ^[3]; Gao, Rui ^[4]; ^[5]; Ye, Yifan ^[6]; ^[1]; Wen, Xiaodong ^[4]; ^[5]; ^[2]; ^[6]; ^[6]; Zuo, Zhijun ^[7]; Li, Weizhen ^[1]; ^[1]; ^[8]; ^[8]; ^[9]; ^[2]; ^[5] more »

Peking Univ., Beijing (China)
Dalian Univ. of Technology, Dalian (China)
Univ. of Chinese Academy of Sciences, Beijing (China); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Chinese Academy of Sciences, Shanxi (China); Synfuels China, Beijing (China)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Taiyuan Univ. of Technology, Shanxi (China)
Lehigh Univ., Bethlehem, PA (United States)
Chinese Academy of Sciences (CAS), Beijing (China)

Here, the water-gas shift (WGS) reaction (where carbon monoxide plus water yields dihydrogen and carbon dioxide) is an essential process for hydrogen generation and carbon monoxide removal in various energy-related chemical operations. This equilibrium-limited reaction is favored at a low working temperature. Potential application in fuel cells also requires a WGS catalyst to be highly active, stable, and energy-efficient and to match the working temperature of on-site hydrogen generation and consumption units. We synthesized layered gold (Au) clusters on a molybdenum carbide (α-MoC) substrate to create an interfacial catalyst system for the ultralow-temperature WGS reaction. Water was activated over α-MoC at 303 kelvin, whereas carbon monoxide adsorbed on adjacent Au sites was apt to react with surface hydroxyl groups formed from water splitting, leading to a high WGS activity at low temperatures.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-05CH11231; SC0012704

OSTI ID:: 1411142

Alternate ID(s):: OSTI ID: 1418304

Report Number(s):: BNL--114190-2017-JA; KC0302010

Journal Information:: Science, Journal Name: Science Journal Issue: 6349 Vol. 357; ISSN 0036-8075

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

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Well dispersed MoC quantum dots in ultrathin carbon films as efficient co-catalysts for photocatalytic H ₂ evolution Gao, Fan; Zhao, Yan; Zhang, Lulu Journal of Materials Chemistry A, Vol. 6, Issue 39 https://doi.org/10.1039/c8ta06029k	journal	January 2018
Ordered platinum–bismuth intermetallic clusters with Pt-skin for a highly efficient electrochemical ethanol oxidation reaction Zhang, Bin-Wei; Lai, Wei-Hong; Sheng, Tian Journal of Materials Chemistry A, Vol. 7, Issue 10 https://doi.org/10.1039/c8ta09553a	journal	January 2019
Light-driven thermocatalytic CO ₂ reduction over surface-passivated β-Mo ₂ C nanowires: enhanced catalytic stability by light Bai, Yujie; Zhao, Jie; Feng, Shuaijun Chemical Communications, Vol. 55, Issue 32 https://doi.org/10.1039/c9cc01479a	journal	January 2019
The catalytic mechanism of the Au@TiO _2−x /ZnO catalyst towards a low-temperature water-gas shift reaction Liu, Ning; Yin, Pan; Xu, Ming Catalysis Science & Technology, Vol. 10, Issue 3 https://doi.org/10.1039/c9cy02077b	journal	January 2020
Molybdenum carbide catalyst for the reduction of CO ₂ to CO: surface science aspects by NAPPES and catalysis studies Reddy, Kasala Prabhakar; Dama, Srikanth; Mhamane, Nitin B. Dalton Transactions, Vol. 48, Issue 32 https://doi.org/10.1039/c9dt01774g	journal	January 2019
Insights into interface engineering in steam reforming reactions for hydrogen production Chen, Sai; Pei, Chunlei; Gong, Jinlong Energy & Environmental Science, Vol. 12, Issue 12 https://doi.org/10.1039/c9ee02808k	journal	January 2019
Carbon vacancy defect-activated Pt cluster for hydrogen generation Bao, Xiaobing; Gong, Yutong; Chen, Yuzhuo Journal of Materials Chemistry A, Vol. 7, Issue 25 https://doi.org/10.1039/c9ta04010b	journal	January 2019
Controlled synthesis of 2D Mo 2 C/graphene heterostructure on liquid Au substrates as enhanced electrocatalytic electrodes Sun, Wenyu; Wang, Xinqi; Feng, Jingqi Nanotechnology, Vol. 30, Issue 38 https://doi.org/10.1088/1361-6528/ab2c0d	journal	July 2019
Recent advances in the precise control of isolated single-site catalysts by chemical methods Li, Zhijun; Wang, Dehua; Wu, Yuen National Science Review, Vol. 5, Issue 5 https://doi.org/10.1093/nsr/nwy056	journal	June 2018
Effect of Nickel Oxide Doping to Ceria-Supported Gold Catalyst for CO Oxidation and Water-Gas Shift Reactions Shu, Miao; Wei, Shuai; Jia, Chun-Jiang Catalysts, Vol. 8, Issue 12 https://doi.org/10.3390/catal8120584	journal	November 2018
Recent Advances in the Gold-Catalysed Low-Temperature Water–Gas Shift Reaction Carter, James H.; Hutchings, Graham J. Catalysts, Vol. 8, Issue 12 https://doi.org/10.3390/catal8120627	journal	December 2018
The Multifaceted Reactivity of Single-Atom Heterogeneous Catalysts Mitchell, Sharon; Vorobyeva, Evgeniya; Pérez-Ramírez, Javier ETH Zurich https://doi.org/10.3929/ethz-b-000304150	text	January 2018

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