skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Synchrotron X-ray studies of model SOFC cathodes, part II: Porous powder cathodes

Abstract

Infiltrated La 0.6Sr 0.4Co 0.2Fe 0.8O 3-δ (LSCF) sintered porous powder cathodes for solid oxide fuel cells have been investigated by synchrotron ultra-small angle x-ray scattering (USAXS). Here, we demonstrated that atomic layer deposition (ALD) is the method for a uniform coating and liquid-phase infiltration for growing nanoscale particles on the porous LSCF surfaces. The MnO infiltrate, grown by ALD, forms a conformal layer with a uniform thickness throughout the pores evidenced by USAXS thickness fringes. The La 0.6Sr 0.4CoO 3 (LSC) and La 2Zr 2O 7 (LZO) infiltrates, grown by liquid-phase infiltration, were found to form nanoscale particles on the surfaces of LSCF particles resulting in increased surface areas. In conclusion, impedance measurements suggest that the catalytic property of LSC infiltrate, not the increased surface area of LZO, is important for increasing oxygen reduction activities.

Authors:
 [1]; ORCiD logo [2];  [3];  [4];  [1];  [1]
  1. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  3. Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division
  4. National Energy Technology Lab. (NETL), Morgantown, WV (United States); AECOM, Morgantown, WV (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
OSTI Identifier:
1411042
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Solid State Ionics
Additional Journal Information:
Journal Volume: 311; Journal Issue: C; Journal ID: ISSN 0167-2738
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Chang, Kee-Chul, Ingram, Brian, Ilavsky, Jan, Lee, Shiwoo, Fuoss, Paul, and You, Hoydoo. Synchrotron X-ray studies of model SOFC cathodes, part II: Porous powder cathodes. United States: N. p., 2017. Web. doi:10.1016/j.ssi.2017.10.001.
Chang, Kee-Chul, Ingram, Brian, Ilavsky, Jan, Lee, Shiwoo, Fuoss, Paul, & You, Hoydoo. Synchrotron X-ray studies of model SOFC cathodes, part II: Porous powder cathodes. United States. doi:10.1016/j.ssi.2017.10.001.
Chang, Kee-Chul, Ingram, Brian, Ilavsky, Jan, Lee, Shiwoo, Fuoss, Paul, and You, Hoydoo. Sat . "Synchrotron X-ray studies of model SOFC cathodes, part II: Porous powder cathodes". United States. doi:10.1016/j.ssi.2017.10.001. https://www.osti.gov/servlets/purl/1411042.
@article{osti_1411042,
title = {Synchrotron X-ray studies of model SOFC cathodes, part II: Porous powder cathodes},
author = {Chang, Kee-Chul and Ingram, Brian and Ilavsky, Jan and Lee, Shiwoo and Fuoss, Paul and You, Hoydoo},
abstractNote = {Infiltrated La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) sintered porous powder cathodes for solid oxide fuel cells have been investigated by synchrotron ultra-small angle x-ray scattering (USAXS). Here, we demonstrated that atomic layer deposition (ALD) is the method for a uniform coating and liquid-phase infiltration for growing nanoscale particles on the porous LSCF surfaces. The MnO infiltrate, grown by ALD, forms a conformal layer with a uniform thickness throughout the pores evidenced by USAXS thickness fringes. The La0.6Sr0.4CoO3 (LSC) and La2Zr2O7 (LZO) infiltrates, grown by liquid-phase infiltration, were found to form nanoscale particles on the surfaces of LSCF particles resulting in increased surface areas. In conclusion, impedance measurements suggest that the catalytic property of LSC infiltrate, not the increased surface area of LZO, is important for increasing oxygen reduction activities.},
doi = {10.1016/j.ssi.2017.10.001},
journal = {Solid State Ionics},
number = C,
volume = 311,
place = {United States},
year = {Sat Oct 28 00:00:00 EDT 2017},
month = {Sat Oct 28 00:00:00 EDT 2017}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Save / Share: