Spin-reorientation transitions in the Cairo pentagonal magnet Bi4Fe5O13F

Tsirlin, Alexander A.; Rousochatzakis, Ioannis; Filimonov, Dmitry; Batuk, Dmitry; Frontzek, Matthias; Abakumov, Artem M.

doi:10.1103/PhysRevB.96.094420

Title: Spin-reorientation transitions in the Cairo pentagonal magnet ${Bi}_{4} {Fe}_{5} O_{13} F$

Journal Article · Tue Sep 19 00:00:00 EDT 2017 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.96.094420· OSTI ID:1410907

Tsirlin, Alexander A. ^[1]; Rousochatzakis, Ioannis ^[2]; Filimonov, Dmitry ^[3]; Batuk, Dmitry ^[4];

^[5]; Abakumov, Artem M. ^[6]

Univ. of Augsburg (Germany). Experimental Physics VI, Center for Electronic Correlations and Magnetism
Univ. of Minnesota, Minneapolis, MN (United States). School of Physics and Astronomy
Lomonosov Moscow State Univ., Moscow (Russia). Dept. of Chemistry
Univ. of Antwerp, Antwerp (Belgium). Electron microscopy for materials science (EMAT)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division
Lomonosov Moscow State Univ., Moscow (Russia). Dept. of Chemistry; Skolkovo Inst. of Science and Technology, Moscow (Russia)

Here, we show that interlayer spins play a dual role in the Cairo pentagonal magnet Bi₄Fe₅O₁₃F, on one hand mediating the three-dimensional magnetic order, and on the other driving spin-reorientation transitions both within and between the planes. The corresponding sequence of magnetic orders unraveled by neutron diffraction and Mössbauer spectroscopy features two orthogonal magnetic structures described by opposite local vector chiralities, and an intermediate, partly disordered phase with nearly collinear spins. A similar collinear phase has been predicted theoretically to be stabilized by quantum fluctuations, but Bi₄Fe₅O₁₃F is very far from the relevant parameter regime. While the observed in-plane reorientation cannot be explained by any standard frustration mechanism, our ab initio band-structure calculations reveal strong single-ion anisotropy of the interlayer Fe³⁺ spins that turns out to be instrumental in controlling the local vector chirality and the associated interlayer order.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; Russian Science Foundation

Grant/Contract Number:: AC05-00OR22725; 14-13-00680

OSTI ID:: 1410907

Journal Information:: Physical Review B, Vol. 96, Issue 9; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 11 works

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Title: Spin-reorientation transitions in the Cairo pentagonal magnet ${Bi}_{4} {Fe}_{5} O_{13} F$