Synthesis and physical characterization of layered organometallic intercalates of MX{sub 2}(M = Sn, Zr; X = S, Se)
Conference
·
OSTI ID:141051
- Univ. of Oxford (United Kingdom)
Large, plate-like crystals of the metal chalcogenides have been intercalated with a variety of organometallic sandwich compounds. They have been characterized by X-ray diffraction, neutron diffraction, solid state deuterium NMR, SQUID magnetometry and electrical conductivity. The intercalated materials all show enhanced conductivity relative to the host materials, and SnSe{sub 2}(Co({eta}-C{sub 5}H{sub 5}){sub 2}){sub 0.3}, in particular, is a relatively isotropic Type II superconductor with a T{sub c} of 8.3K. Synthetic routes to the above intercalates and their physical properties will be discussed, with a view towards design of new molecular intercalates with enhanced electrical and magnetic characteristics.
- OSTI ID:
- 141051
- Report Number(s):
- CONF-930304--
- Country of Publication:
- United States
- Language:
- English
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