Aqueous Bismuth Titanium–Oxo Sulfate Cluster Speciation and Crystallization

Molina, Pedro I.; Kozma, Karoly; Santala, Melissa; Falaise, Clément; Nyman, May

doi:10.1002/anie.201709539

Title: Aqueous Bismuth Titanium–Oxo Sulfate Cluster Speciation and Crystallization

Journal Article · Fri Nov 24 00:00:00 EST 2017 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201709539· OSTI ID:1410362

Molina, Pedro I. ^[1]; Kozma, Karoly ^[2]; Santala, Melissa ^[3]; Falaise, Clément ^[4];

^[2]

Department of Chemistry Oregon State University 107 Gilbert Hall Corvallis OR 97331-4003 USA, Current address: Valliscor Advanced Technology &, Manufacturing Institute 1110 NE Circle Blvd Corvallis USA
Department of Chemistry Oregon State University 107 Gilbert Hall Corvallis OR 97331-4003 USA
Department of Mechanical, Industrial and Manufacturing Engineering Oregon State University USA
Department of Chemistry Oregon State University 107 Gilbert Hall Corvallis OR 97331-4003 USA, Current address: Institut Lavoisier de Versailles, UMR 8180, UVSQ Université Paris-Saclay 78035 Versailles France

Abstract Inorganic aqueous metal–oxo clusters are both functional “molecular metal oxides” and intermediates to understand metal oxide growth from water. There has been a recent surge in discovery of aqueous Ti‐oxo clusters but without extensive solution characterization. We use small‐angle and total X‐ray scattering, dynamic light scattering, transmission electron microscopy, and a single‐crystal X‐ray structure to show that heterometals such as bismuth stabilize labile Ti–oxo sulfate clusters in aqueous solution.[Ti ₂₂ Bi ₇ O ₄₁ (OH)(OH ₂ ) ₃₀ (SO ₄ ) ₁₂ ] ²⁺ features edge‐sharing between the Ti and Bi polyhedra, in contrast to the dominant corner‐linking of Ti‐oxo clusters. Bi stabilizes the Ti‐polyhedra, which are synergistically stabilized by the bidentate sulfates. Gained stability and potential functionality from heterometals is an incentive to develop more broadly the landscape of heterometallic Ti–oxo clusters.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 1410362

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Vol. 56 Journal Issue: 51; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

Citation Metrics:

Cited by: 27 works

Citation information provided by
Web of Science

References (47)

Controlling the Self-Assembly of a Mixed-Metal Mo/V-Selenite Family of Polyoxometalates Corella-Ochoa, M. Nieves; Miras, Haralampos N.; Long, De-Liang Chemistry - A European Journal, Vol. 18, Issue 43 https://doi.org/10.1002/chem.201200912	journal	September 2012
Al13–[X–Mo/WOn] (X=Al, Co, V, P) composites as catalysts in clean oxidation of aromatic sulfides Muñoz, Mercedes; Romanelli, Gustavo; Botto, Irma L. Applied Catalysis B: Environmental, Vol. 100, Issue 1-2 https://doi.org/10.1016/j.apcatb.2010.08.001	journal	October 2010
Heteropolymetalate Clusters of the Subvalent Main Group Elements Bi ^III and Sb ^III ^‖ Loose, Ina; Droste, Elisabeth; Bösing, Michael Inorganic Chemistry, Vol. 38, Issue 11 https://doi.org/10.1021/ic981313m	journal	May 1999
The crystal structure of zirconyl chloride octahydrate and zirconyl bromide octahydrate Clearfield, A.; Vaughan, P. A. Acta Crystallographica, Vol. 9, Issue 7 https://doi.org/10.1107/S0365110X56001558	journal	July 1956
Polyoxometalate-functionalized nanocarbon materials for energy conversion, energy storage and sensor systems Ji, Yuanchun; Huang, Lujiang; Hu, Jun Energy & Environmental Science, Vol. 8, Issue 3 https://doi.org/10.1039/C4EE03749A	journal	January 2015
Dissolution of insulating oxide materials at the molecular scale Ohlin, C. André; Villa, Eric M.; Rustad, James R. Nature Materials, Vol. 9, Issue 1 https://doi.org/10.1038/nmat2585	journal	November 2009
Large Aqueous Aluminum Hydroxide Molecules Casey, William H. Chemical Reviews, Vol. 106, Issue 1 https://doi.org/10.1021/cr040095d	journal	January 2006
Crystallography and Properties of Polyoxotitanate Nanoclusters Coppens, Philip; Chen, Yang; Trzop, Elżbieta Chemical Reviews, Vol. 114, Issue 19 https://doi.org/10.1021/cr400724e	journal	May 2014
Controlling transformations in the assembly of polyoxometalate clusters: {Mo11V7}, {Mo17V8} and {Mo72V30} Miras, Haralampos N.; Ochoa, M. Nieves Corella; Long, De-Liang Chemical Communications, Vol. 46, Issue 43 https://doi.org/10.1039/c0cc02849e	journal	January 2009
Amphoteric Aqueous Hafnium Cluster Chemistry Goberna-Ferrón, Sara; Park, Deok-Hie; Amador, Jenn M. Angewandte Chemie International Edition, Vol. 55, Issue 21 https://doi.org/10.1002/anie.201601134	journal	April 2016
Structure of [Ti8O12(H2O)24]Cl8.HCl.7H2O Reichmann, M. G.; Hollander, F. J.; Bell, A. T. Acta Crystallographica Section C Crystal Structure Communications, Vol. 43, Issue 9 https://doi.org/10.1107/S0108270187090577	journal	September 1987
The crystal structure of Hf ₁₈ O ₁₀ (OH) ₂₆ (SO ₄ ) ₁₃ (H ₂ O) ₃₃ Mark, W.; Hansson, M. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 31, Issue 4 https://doi.org/10.1107/S0567740875004591	journal	April 1975
Recent Advances in Polyoxometalate-Catalyzed Reactions Wang, Sa-Sa; Yang, Guo-Yu Chemical Reviews, Vol. 115, Issue 11 https://doi.org/10.1021/cr500390v	journal	May 2015
Selective Precipitation of Prions by Polyoxometalate Complexes Lee, In Su; Long, Jeffrey R.; Prusiner, Stanley B. Journal of the American Chemical Society, Vol. 127, Issue 40 https://doi.org/10.1021/ja055219y	journal	October 2005
Heteropolymolybdates of AsIII, SbIII, BiIII, SeIV, and TeIV Functionalized by Amino Acids Kortz, Ulrich; Savelieff, Masha G.; Ghali, Fida Y. Abou Angewandte Chemie International Edition, Vol. 41, Issue 21 https://doi.org/10.1002/1521-3773(20021104)41:21<4070::AID-ANIE4070>3.0.CO;2-3	journal	November 2002
Refinement of the crystal structure of zirconyl chloride octahydrate Mak, Thomas C. W. Canadian Journal of Chemistry, Vol. 46, Issue 22 https://doi.org/10.1139/v68-579	journal	November 1968
Chemical Stabilization and Electrochemical Destabilization of the Iron Keggin Ion in Water Sadeghi, Omid; Falaise, Clément; Molina, Pedro I. Inorganic Chemistry, Vol. 55, Issue 21 https://doi.org/10.1021/acs.inorgchem.6b01694	journal	October 2016
Assembly of Molecular “Layered” Heteropolyoxometalate Architectures Gao, Jing; Yan, Jun; Beeg, Sebastian Angewandte Chemie International Edition, Vol. 51, Issue 14 https://doi.org/10.1002/anie.201108428	journal	February 2012
Aqueous formation and manipulation of the iron-oxo Keggin ion Sadeghi, O.; Zakharov, L. N.; Nyman, M. Science, Vol. 347, Issue 6228 https://doi.org/10.1126/science.aaa4620	journal	February 2015
Manganese‐Substituted Polyoxometalate as an Effective Shuttle Redox Mediator in Z‐Scheme Water Splitting under Visible Light Tsuji, Kohei; Tomita, Osamu; Higashi, Masanobu ChemSusChem, Vol. 9, Issue 16 https://doi.org/10.1002/cssc.201600563	journal	July 2016
Aqueous Hafnium Sulfate Chemistry: Structures of Crystalline Precipitates Kalaji, Ali; Soderholm, L. Inorganic Chemistry, Vol. 53, Issue 20 https://doi.org/10.1021/ic501841e	journal	September 2014
Crystal structure of a complex basic zirconium sulfate Squattrito, Philip J.; Rudolf, Philip R.; Clearfield, Abraham Inorganic Chemistry, Vol. 26, Issue 25 https://doi.org/10.1021/ic00272a020	journal	December 1987
A novel nonanuclear hafnium oxide–hydroxide–sulphate cluster crystallised from aqueous solution Kalaji, A.; Soderholm, L. Chem. Commun., Vol. 50, Issue 8 https://doi.org/10.1039/C3CC48167K	journal	January 2014
Chemical and Structural Investigation of High-Resolution Patterning with HafSOx Oleksak, Richard P.; Ruther, Rose E.; Luo, Feixiang ACS Applied Materials & Interfaces, Vol. 6, Issue 4 https://doi.org/10.1021/am405463u	journal	February 2014
Small Titanium Oxo Clusters: Primary Structures of Titanium(IV) in Water Zhang, Guanyun; Hou, Jie; Tung, Chen-Ho Inorganic Chemistry, Vol. 55, Issue 7 https://doi.org/10.1021/acs.inorgchem.6b00129	journal	March 2016
Actinyl Peroxide Nanospheres Burns, Peter C.; Kubatko, Karrie-Ann; Sigmon, Ginger Angewandte Chemie, Vol. 117, Issue 14 https://doi.org/10.1002/ange.200462445	journal	March 2005
Benchmarking Uranyl Peroxide Capsule Chemistry in Organic Media: Benchmarking Uranyl Peroxide Capsule Chemistry in Organic Media Neal, Harrison A.; Szymanowski, Jennifer; Fein, Jeremy B. European Journal of Inorganic Chemistry, Vol. 2017, Issue 1 https://doi.org/10.1002/ejic.201601219	journal	November 2016
Counteranion-Stabilized Titanium(IV) Isopolyoxocationic Clusters Isolated from Water Zhang, Guanyun; Hou, Jie; Li, Mingzhong Inorganic Chemistry, Vol. 55, Issue 10 https://doi.org/10.1021/acs.inorgchem.5b01901	journal	April 2016
Edelmetalle in Polyoxometallaten Izarova, Natalya V.; Pope, Michael T.; Kortz, Ulrich Angewandte Chemie, Vol. 124, Issue 38 https://doi.org/10.1002/ange.201202750	journal	August 2012
Self-Assembly of a Heteropolyoxopalladate Nanocube: [Pd ^II ₁₃ As ^V ₈ O ₃₄ (OH) ₆ ] ⁸⁻ Chubarova, Elena V.; Dickman, Michael H.; Keita, Bineta Angewandte Chemie International Edition, Vol. 47, Issue 49 https://doi.org/10.1002/anie.200803527	journal	November 2008
Structure of the Molecule of 12-Phosphotungstic Acid Keggin, J. F. Nature, Vol. 131, Issue 3321 https://doi.org/10.1038/131908b0	journal	June 1933
Mit Aminosäuren funktionalisierte Heteropolymolybdate von AsIII, SbIII, BiIII, SeIV und TeIV Kortz, Ulrich; Savelieff, Masha G.; Ghali, Fida Y. Abou Angewandte Chemie, Vol. 114, Issue 21 https://doi.org/10.1002/1521-3757(20021104)114:21<4246::AID-ANGE4246>3.0.CO;2-E	journal	November 2002
Chemical and Photochemical Functionality of the First Molecular Bismuth Vanadium Oxide Tucher, Johannes; Nye, Leanne C.; Ivanovic-Burmazovic, Ivana Chemistry - A European Journal, Vol. 18, Issue 35 https://doi.org/10.1002/chem.201200404	journal	July 2012
Oligomeric group 13 hydroxide compounds—a rare but varied class of molecules Mensinger, Zachary L.; Wang, Wei; Keszler, Douglas A. Chem. Soc. Rev., Vol. 41, Issue 3 https://doi.org/10.1039/C1CS15216E	journal	January 2012
“Electron/Ion Sponge”-Like V-Based Polyoxometalate: Toward High-Performance Cathode for Rechargeable Sodium Ion Batteries Liu, Jilei; Chen, Zhen; Chen, Shi ACS Nano, Vol. 11, Issue 7 https://doi.org/10.1021/acsnano.7b02062	journal	May 2017
Di-μ-hydroxo-bis[aquasulfatobismuth(III)] Graunar, M.; Lazarini, F. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 38, Issue 11 https://doi.org/10.1107/S0567740882010188	journal	November 1982
Structure of the hydrated, hydrolysed and solvated zirconium( iv ) and hafnium( iv ) ions in water and aprotic oxygen donor solvents. A crystallographic, EXAFS spectroscopic and large angle X-ray scattering study Hagfeldt, Camelia; Kessler, Vadim; Persson, Ingmar Dalton Trans., Issue 14 https://doi.org/10.1039/B402804J	journal	January 2004
Amphoteric Aqueous Hafnium Cluster Chemistry Goberna-Ferrón, Sara; Park, Deok-Hie; Amador, Jenn M. Angewandte Chemie, Vol. 128, Issue 21 https://doi.org/10.1002/ange.201601134	journal	April 2016
Effects of Dawson-Type Tungstophosphate on Photoelectrochemical Responses of Cadmium Sulfide Composite Film Sun, Zhixia; Li, Fengyan; Xu, Lin The Journal of Physical Chemistry C, Vol. 116, Issue 10 https://doi.org/10.1021/jp2119982	journal	March 2012
Assembly of Molecular “Layered” Heteropolyoxometalate Architectures Gao, Jing; Yan, Jun; Beeg, Sebastian Angewandte Chemie, Vol. 124, Issue 14 https://doi.org/10.1002/ange.201108428	journal	February 2012
Water-Soluble Pentagonal-Prismatic Titanium-Oxo Clusters Zhang, Guanyun; Liu, Caiyun; Long, De-Liang Journal of the American Chemical Society, Vol. 138, Issue 35 https://doi.org/10.1021/jacs.6b06290	journal	August 2016
Assembly of titanium embedded polyoxometalates with unprecedented structural features McGlone, Thomas; Vilà-Nadal, Laia; Miras, Haralampos N. Dalton Transactions, Vol. 39, Issue 48 https://doi.org/10.1039/c0dt01327g	journal	January 2010
Enhanced Water Purification: A Single Atom Makes a Difference ^∥ Stewart, Tom A.; Trudell, Daniel E.; Alam, Todd M. Environmental Science & Technology, Vol. 43, Issue 14 https://doi.org/10.1021/es803683t	journal	July 2009
Actinyl Peroxide Nanospheres Burns, Peter C.; Kubatko, Karrie-Ann; Sigmon, Ginger Angewandte Chemie International Edition, Vol. 44, Issue 14 https://doi.org/10.1002/anie.200462445	journal	March 2005
Selbstorganisation eines Heteropolyoxopalladat-Nanowürfels, [Pd ^II ₁₃ As ^V ₈ O ₃₄ (OH) ₆ ] ⁸⁻ Chubarova, Elena V.; Dickman, Michael H.; Keita, Bineta Angewandte Chemie, Vol. 120, Issue 49 https://doi.org/10.1002/ange.200803527	journal	November 2008
Noble Metals in Polyoxometalates Izarova, Natalya V.; Pope, Michael T.; Kortz, Ulrich Angewandte Chemie International Edition, Vol. 51, Issue 38 https://doi.org/10.1002/anie.201202750	journal	August 2012
The linkage between ribosomal crystallography, metal ions, heteropolytungstates and functional flexibility Bashan, Anat; Yonath, Ada Journal of Molecular Structure, Vol. 890, Issue 1-3 https://doi.org/10.1016/j.molstruc.2008.03.043	journal	November 2008

Similar Records

Aqueous Bismuth Titanium–Oxo Sulfate Cluster Speciation and Crystallization

Journal Article · Fri Nov 24 00:00:00 EST 2017 · Angewandte Chemie · OSTI ID:1410362

Molina, Pedro I.; Kozma, Karoly; Santala, Melissa; +2 more

The role of titanium-oxo clusters in the sulfate process for TiO₂ production

Journal Article · Thu Jun 20 00:00:00 EDT 2019 · Dalton Transactions · OSTI ID:1410362

Kozma, Karoly; Wang, Maoyu; Molina, Pedro I.; +3 more

The Role of Bi ³⁺ in Promoting and Stabilizing Iron Oxo Clusters in Strong Acid

Journal Article · Wed Apr 25 00:00:00 EDT 2018 · Angewandte Chemie · OSTI ID:1410362

Sadeghi, Omid; Amiri, Mehran; Reinheimer, Eric W.; +1 more

Title: Aqueous Bismuth Titanium–Oxo Sulfate Cluster Speciation and Crystallization

Citation Formats

References (47)

Similar Records

Related Subjects