Collapsed tetragonal phase transition in
Journal Article
·
· Physical Review B
- Ames Lab. and Iowa State Univ., Ames, IA (United States)
Here, the structural properties of LaRu2P2 under external pressure have been studied up to 14 GPa, employing high-energy x-ray diffraction in a diamond-anvil pressure cell. At ambient conditions, LaRu2P2 (I4/mmm) has a tetragonal structure with a bulk modulus of B = 105(2) GPa and exhibits superconductivity at Tc = 4.1 K. With the application of pressure, LaRu2P2 undergoes a phase transition to a collapsed tetragonal (cT) state with a bulk modulus of B = 175(5) GPa. At the transition, the c-lattice parameter exhibits a sharp decrease with a concurrent increase of the a-lattice parameter. The cT phase transition in LaRu2P2 is consistent with a second-order transition, and was found to be temperature dependent, increasing from P = 3.9(3) GPa at 160 K to P = 4.6(3) GPa at 300 K. In total, our data are consistent with the cT transition being near, but slightly above 2 GPa at 5 K where superconductivity is suppressed. Finally, we compare the effect of physical and chemical pressure in the RRu2P2 (R = Y, La–Er, Yb) isostructural series of compounds and find them to be analogous.
- Research Organization:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Organization:
- USDOE
- Grant/Contract Number:
- AC02-06CH11357; FG02-94ER14466; NA0001974
- OSTI ID:
- 1410346
- Alternate ID(s):
- OSTI ID: 1408263
OSTI ID: 1413318
- Report Number(s):
- IS-J--9507
- Journal Information:
- Physical Review B, Journal Name: Physical Review B Journal Issue: 18 Vol. 96; ISSN 2469-9950; ISSN PRBMDO
- Publisher:
- American Physical Society (APS)Copyright Statement
- Country of Publication:
- United States
- Language:
- English
New materials physics
|
journal | November 2019 |
Superconducting and magnetic phase diagram of RbEuFe 4 As 4 and CsEuFe 4 As 4 at high pressure
|
journal | July 2018 |
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