Photodegradable polymers: Synthesis, characterization and photochemistry of vinyl polymers with Fe-Fe bonds incorporated into the backbone
Conference
·
OSTI ID:141025
- Univ. of Oregon, Eugene, OR (United States)
In the present work the synthesis of vinyl polymers with Fe-Fe bonds along the backbone is described. The synthesis and polymerization of two polymers via ring-opening metathesis polymerization (ROMP) (polymer 1) and via acyclic diene metathesis polymerization (ADMET) and radical chain polymerization (polymer 2) is discussed. Because the Fe-Fe bond is photochemically reactive, the polymers are photodegradable. The mechanism of the photodegradation is also be discussed.
- OSTI ID:
- 141025
- Report Number(s):
- CONF-930304--
- Country of Publication:
- United States
- Language:
- English
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