Elastic Properties across the y→α Volume Collapse in Cerium versus Pressure and Temperature

Lipp, M. J.; Jenei, Zs.; Cynn, H.; Kono, Y.; Park, C.; Kenney-Benson, C.; Evans, W. J.

doi:10.1038/s41467-017-01411-9

Title: Elastic Properties across the y→α Volume Collapse in Cerium versus Pressure and Temperature

Journal Article · Tue Oct 31 00:00:00 EDT 2017 · Nature Communications

DOI:https://doi.org/10.1038/s41467-017-01411-9· OSTI ID:1410020

Lipp, M. J. ^[1]; Jenei, Zs. ^[1]; Cynn, H. ^[1]; Kono, Y. ^[2]; Park, C. ^[2]; Kenney-Benson, C. ^[2]; Evans, W. J. ^[1]

Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Carnegie Institute of Washington, Argonne, IL (United States)

Here, the longitudinal and transverse sound speeds, c_L and c_T, of polycrystalline cerium were measured isothermally vs pressure up to the critical temperature across the iso-structural γ-α volume collapse (VC) phase transition. We deduce values for the adiabatic bulk modulus BS, the shear modulus G = ρc_T², the Poisson’s ratio ν and the Debye temperature, θ_D(p). We find that the elastic constant C₁₂ is solely responsible for the decrease of B_S with pressure towards the VC at RT. With increasing temperature, the lattice contribution ΔS_vib(γ→α) to the total entropy change across the VC decreases more rapidly to zero than the total entropy itself suggesting that another mechanism, possibly disorder, assists in stabilizing the γ-phase entropically against the α-phase. Also, with increasing temperature, the Poisson’s ratio becomes negative near the VC transition, meaning that cerium metal takes on auxetic characteristics over a small pressure range. At the critical point the Poisson’s ratio ought to be -1, since the isothermal bulk modulus vanishes and the shear modulus remains nonzero.

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Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 1410020

Report Number(s):: LLNL-JRNL-677515

Journal Information:: Nature Communications, Vol. 8; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 14 works

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