Regenerable Cu-intercalated MnO2 layered cathode for highly cyclable energy dense batteries

Yadav, Gautam G.; Gallaway, Joshua W.; Turney, Damon E.; Nyce, Michael; Huang, Jinchao; Wei, Xia; Banerjee, Sanjoy

doi:10.1038/ncomms14424

Title: Regenerable Cu-intercalated MnO2 layered cathode for highly cyclable energy dense batteries

Journal Article · Mon Mar 06 00:00:00 EST 2017 · Nature Communications

DOI:https://doi.org/10.1038/ncomms14424· OSTI ID:1409595

Yadav, Gautam G.; Gallaway, Joshua W.; Turney, Damon E.; Nyce, Michael;

; Wei, Xia; Banerjee, Sanjoy

Manganese dioxide cathodes are inexpensive and have high theoretical capacity (based on two electrons) of 617 mAh g-1, making them attractive for low-cost, energy-dense batteries. They are used in non-rechargeable batteries with anodes like zinc. Only ~10% of the theoretical capacity is currently accessible in rechargeable alkaline systems. Attempts to access the full capacity using additives have been unsuccessful. We report a class of Bi-birnessite (a layered manganese oxide polymorph mixed with bismuth oxide (Bi2O3)) cathodes intercalated with Cu2+ that deliver near-full two-electron capacity reversibly for >6,000 cycles. The key to rechargeability lies in exploiting the redox potentials of Cu to reversibly intercalate into the Bi-birnessite-layered structure during its dissolution and precipitation process for stabilizing and enhancing its charge transfer characteristics. This process holds promise for other applications like catalysis and intercalation of metal ions into layered structures. A large prismatic rechargeable Zn-birnessite cell delivering ~140 Wh l-1 is shown.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0012704

OSTI ID:: 1409595

Report Number(s):: BNL-114647-2017-JA¿¿¿

Journal Information:: Nature Communications, Vol. 8; ISSN 2041-1723

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

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