A new strategy to engineer polymer bulk heterojunction solar cells with thick active layers via self-assembly of the tertiary columnar phase

Li, Hongfei; Yang, Zhenhua; Pan, Cheng; Jiang, Naisheng; Satija, Sushil K.; Xu, Di; Gersappe, Dilip; Nam, Chang-Yong; Rafailovich, Miriam H.

doi:10.1039/C7NR03789A

A new strategy to engineer polymer bulk heterojunction solar cells with thick active layers via self-assembly of the tertiary columnar phase

Journal Article · Sun Jan 01 04:00:00 EST 2017 · Nanoscale

DOI:https://doi.org/10.1039/C7NR03789A· OSTI ID:1409518

Li, Hongfei ^[1]; Yang, Zhenhua ^[1]; Pan, Cheng ^[1]; Jiang, Naisheng ^[1]; Satija, Sushil K. ^[2]; Xu, Di ^[1]; Gersappe, Dilip ^[1]; ^[3]; Rafailovich, Miriam H. ^[1]

Department of Materials Science and Engineering; Stony Brook University; Stony Brook; USA
Center for Neutron Research; National Institute of Standards and Technology; Gaithersburg; USA
Center for Functional Nanomaterials; Brookhaven National Laboratory; Upton; USA

A self-assembled ternary blend bulk heterojunction increases the optimal blend thickness, making it suitable for practical roll-to-roll organic solar cell fabrication.

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

DOE Contract Number:: SC0012704

OSTI ID:: 1409518

Report Number(s):: BNL--114570-2017-JA¿¿¿

Journal Information:: Nanoscale, Journal Name: Nanoscale Journal Issue: 32 Vol. 9; ISSN NANOHL; ISSN 2040-3364

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (70)

Effect of electron-transport polymer addition to polymer/fullerene blend solar cells Kim, Y.; Cook, S.; Choulis, S. A. Synthetic Metals, Vol. 152, Issue 1-3 https://doi.org/10.1016/j.synthmet.2005.07.189	journal	September 2005
P3HT/PCBM Bulk Heterojunction Solar Cells: Impact of Blend Composition and 3D Morphology on Device Performance van Bavel, Svetlana S.; Bärenklau, Maik; de With, Gijsbertus Advanced Functional Materials, Vol. 20, Issue 9 https://doi.org/10.1002/adfm.200902247	journal	April 2010
Phase Diagram of P3HT/PCBM Blends and Its Implication for the Stability of Morphology Zhao, Jun; Swinnen, Ann; Van Assche, Guy The Journal of Physical Chemistry B, Vol. 113, Issue 6, p. 1587-1591 https://doi.org/10.1021/jp804151a	journal	February 2009
Real-Time Investigation of Crystallization and Phase-Segregation Dynamics in P3HT:PCBM Solar Cells During Thermal Annealing Agostinelli, Tiziano; Lilliu, Samuele; Labram, John G. Advanced Functional Materials, Vol. 21, Issue 9 https://doi.org/10.1002/adfm.201002076	journal	March 2011
Investigation of annealing effects and film thickness dependence of polymer solar cells based on poly(3-hexylthiophene) Li, Gang; Shrotriya, Vishal; Yao, Yan Journal of Applied Physics, Vol. 98, Issue 4 https://doi.org/10.1063/1.2008386	journal	August 2005
A Study on the Correlation Between Structure and Hole Transport in Semi-Crystalline Regioregular P3HT Shen, Xiaobo; Duzhko, Volodimyr V.; Russell, Thomas P. Advanced Energy Materials, Vol. 3, Issue 2 https://doi.org/10.1002/aenm.201200509	journal	September 2012
Enhanced Power Conversion Efficiency of Low Band-Gap Polymer Solar Cells by Insertion of Optimized Binary Processing Additives Wang, Dong Hwan; Kyaw, Aung Ko Ko; Pouliot, Jean-Rémi Advanced Energy Materials, Vol. 4, Issue 4 https://doi.org/10.1002/aenm.201300835	journal	October 2013
Pathways for the degradation of organic photovoltaic P3HT:PCBM based devices Reese, Matthew O.; Morfa, Anthony J.; White, Matthew S. Solar Energy Materials and Solar Cells, Vol. 92, Issue 7 https://doi.org/10.1016/j.solmat.2008.01.020	journal	July 2008
Ultra Fast and Parsimonious Materials Screening for Polymer Solar Cells Using Differentially Pumped Slot-Die Coating Alstrup, Jan; Jørgensen, Mikkel; Medford, Andrew J. ACS Applied Materials & Interfaces, Vol. 2, Issue 10 https://doi.org/10.1021/am100505e	journal	September 2010
Enhanced charge collection in confined bulk heterojunction organic solar cells Allen, Jonathan E.; Yager, Kevin G.; Hlaing, Htay Applied Physics Letters, Vol. 99, Issue 16 https://doi.org/10.1063/1.3651509	journal	October 2011
Correlating the scattered intensities of P3HT and PCBM to the current densities of polymer solar cells Gomez, Enrique D.; Barteau, Katherine P.; Wang, He Chem. Commun., Vol. 47, Issue 1 https://doi.org/10.1039/C0CC02927K	journal	January 2011
Fabrication and processing of polymer solar cells: A review of printing and coating techniques Krebs, Frederik C. Solar Energy Materials and Solar Cells, Vol. 93, Issue 4, p. 394-412 https://doi.org/10.1016/j.solmat.2008.10.004	journal	April 2009
High-Performance Air-Processed Polymerâ€“Fullerene Bulk Heterojunction Solar Cells Nam, Chang-Yong; Su, Dong; Black, Charles T. Advanced Functional Materials, Vol. 19, Issue 22 https://doi.org/10.1002/adfm.200900311	journal	November 2009
Enhanced Hole Mobility in Regioregular Polythiophene Infiltrated in Straight Nanopores Coakley, K. M.; Srinivasan, B. S.; Ziebarth, J. M. Advanced Functional Materials, Vol. 15, Issue 12 https://doi.org/10.1002/adfm.200500364	journal	December 2005
Formation of Nanopatterned Polymer Blends in Photovoltaic Devices He, Ximin; Gao, Feng; Tu, Guoli Nano Letters, Vol. 10, Issue 4 https://doi.org/10.1021/nl904098m	journal	April 2010
Record High Hole Mobility in Polymer Semiconductors via Side-Chain Engineering Kang, Il; Yun, Hui-Jun; Chung, Dae Sung Journal of the American Chemical Society, Vol. 135, Issue 40 https://doi.org/10.1021/ja405112s	journal	September 2013
Transport in polycrystalline polymer thin-film transistors Street, R. A.; Northrup, J. E.; Salleo, A. Physical Review B, Vol. 71, Issue 16 https://doi.org/10.1103/PhysRevB.71.165202	journal	April 2005
Molecular dynamics simulation for polymers in the presence of a heat bath Grest, Gary S.; Kremer, Kurt Physical Review A, Vol. 33, Issue 5 https://doi.org/10.1103/PhysRevA.33.3628	journal	May 1986
High-Molecular-Weight Insulating Polymers Can Improve the Performance of Molecular Solar Cells Huang, Ye; Wen, Wen; Mukherjee, Subhrangsu Advanced Materials, Vol. 26, Issue 24 https://doi.org/10.1002/adma.201400497	journal	April 2014
Polymer Photovoltaic Cells: Enhanced Efficiencies via a Network of Internal Donor-Acceptor Heterojunctions Yu, G.; Gao, J.; Hummelen, J. C. Science, Vol. 270, Issue 5243, p. 1789-1791 https://doi.org/10.1126/science.270.5243.1789	journal	December 1995
A New Model for the Morphology of P3HT/PCBM Organic Photovoltaics from Small-Angle Neutron Scattering: Rivers and Streams Yin, Wen; Dadmun, Mark ACS Nano, Vol. 5, Issue 6, p. 4756-4768 https://doi.org/10.1021/nn200744q	journal	May 2011
Control of the nanoscale crystallinity and phase separation in polymer solar cells Chu, Chih-Wei; Yang, Hoichang; Hou, Wei-Jen Applied Physics Letters, Vol. 92, Issue 10 https://doi.org/10.1063/1.2891884	journal	March 2008
Nanostructured electrodes for organic bulk heterojunction solar cells: Model study using carbon nanotube dispersed polythiophene-fullerene blend devices Nam, Chang-Yong; Wu, Qin; Su, Dong Journal of Applied Physics, Vol. 110, Issue 6 https://doi.org/10.1063/1.3633236	journal	September 2011
Parallel-like Bulk Heterojunction Polymer Solar Cells Yang, Liqiang; Zhou, Huaxing; Price, Samuel C. Journal of the American Chemical Society, Vol. 134, Issue 12 https://doi.org/10.1021/ja211597w	journal	March 2012
Polymer bulk heterojunction solar cells employing Förster resonance energy transfer Huang, Jing-Shun; Goh, Tenghooi; Li, Xiaokai Nature Photonics, Vol. 7, Issue 6 https://doi.org/10.1038/nphoton.2013.82	journal	May 2013
Surface Studies of Solids by Total Reflection of X-Rays Parratt, L. G. Physical Review, Vol. 95, Issue 2 https://doi.org/10.1103/PhysRev.95.359	journal	July 1954
For the Bright Future-Bulk Heterojunction Polymer Solar Cells with Power Conversion Efficiency of 7.4% Liang, Yongye; Xu, Zheng; Xia, Jiangbin Advanced Materials, Vol. 22, Issue 20, p. E135-E138 https://doi.org/10.1002/adma.200903528	journal	May 2010
Modeling optical effects and thickness dependent current in polymer bulk-heterojunction solar cells Sievers, Douglas W.; Shrotriya, Vishal; Yang, Yang Journal of Applied Physics, Vol. 100, Issue 11 https://doi.org/10.1063/1.2388854	journal	January 2006
Competition between Fullerene Aggregation and Poly(3-hexylthiophene) Crystallization upon Annealing of Bulk Heterojunction Solar Cells Wu, Wei-Ru; Jeng, U-Ser; Su, Chun-Jen ACS Nano, Vol. 5, Issue 8 https://doi.org/10.1021/nn2010816	journal	July 2011
Solution-processed small-molecule solar cells: breaking the 10% power conversion efficiency Liu, Yongsheng; Chen, Chun-Chao; Hong, Ziruo Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep03356	journal	November 2013
Improved Power Conversion Efficiency in Bulk Heterojunction Organic Solar Cells with Radial Electron Contacts Allen, Jonathan E.; Black, Charles T. ACS Nano, Vol. 5, Issue 10 https://doi.org/10.1021/nn2031963	journal	September 2011
Nanoparticle concentration profile in polymer-based solar cells Kiel, Jonathan W.; Kirby, Brian J.; Majkrzak, Charles F. Soft Matter, Vol. 6, Issue 3, p. 641-646 https://doi.org/10.1039/B920979D	journal	January 2010
Enhancing the efficiency of low bandgap conducting polymer bulk heterojunction solar cells using P3HT as a morphology control agent Chang, Sheng-Yung; Liao, Hsueh-Chung; Shao, Yu-Tsun Journal of Materials Chemistry A, Vol. 1, Issue 7 https://doi.org/10.1039/c2ta00990k	journal	January 2013
Dependence of Regioregular Poly(3-hexylthiophene) Film Morphology and Field-Effect Mobility on Molecular Weight Kline, R. Joseph; McGehee, Michael D.; Kadnikova, Ekaterina N. Macromolecules, Vol. 38, Issue 8, p. 3312-3319 https://doi.org/10.1021/ma047415f	journal	April 2005
Roll-to-Roll Printed Large-Area All-Polymer Solar Cells with 5% Efficiency Based on a Low Crystallinity Conjugated Polymer Blend Gu, Xiaodan; Zhou, Yan; Gu, Kevin Advanced Energy Materials, Vol. 7, Issue 14 https://doi.org/10.1002/aenm.201602742	journal	March 2017
Submicron-scale manipulation of phase separation in organic solar cells Chen, Fang-Chung; Lin, Yi-Kai; Ko, Chu-Jung Applied Physics Letters, Vol. 92, Issue 2 https://doi.org/10.1063/1.2835047	journal	January 2008
Interdiffusion of PCBM and P3HT Reveals Miscibility in a Photovoltaically Active Blend Treat, Neil D.; Brady, Michael A.; Smith, Gordon Advanced Energy Materials, Vol. 1, Issue 1, p. 82-89 https://doi.org/10.1002/aenm.201000023	journal	November 2010
High-performance ternary blend polymer solar cells involving both energy transfer and hole relay processes Lu, Luyao; Chen, Wei; Xu, Tao Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8327	journal	June 2015
Panchromatic polymer–polymer ternary solar cells enhanced by Förster resonance energy transfer and solvent vapor annealing Goh, Tenghooi; Huang, Jing-Shun; Bartolome, Benjamin Journal of Materials Chemistry A, Vol. 3, Issue 36 https://doi.org/10.1039/C5TA04905A	journal	January 2015
Crystallization-Induced 10-nm Structure Formation in P3HT/PCBM Blends Kohn, Peter; Rong, Zhuxia; Scherer, Kai H. Macromolecules, Vol. 46, Issue 10 https://doi.org/10.1021/ma400403c	journal	April 2013
Poly(3-hexylthiophene) Nanorods with Aligned Chain Orientation for Organic Photovoltaics Kim, Jong Soo; Park, Yunmin; Lee, Dong Yun Advanced Functional Materials, Vol. 20, Issue 4 https://doi.org/10.1002/adfm.200901760	journal	February 2010
A Facile Route to Polymer Solar Cells with Optimum Morphology Readily Applicable to a Roll-to-Roll Process without Sacrificing High Device Performances Park, Hui Joon; Kang, Myung-Gyu; Ahn, Se Hyun Advanced Materials, Vol. 22, Issue 35 https://doi.org/10.1002/adma.201000250	journal	June 2010
Bulk heterojunction solar cells with internal quantum efficiency approaching 100% Park, Sung Heum; Roy, Anshuman; Beaupré, Serge Nature Photonics, Vol. 3, Issue 5, p. 297-302 https://doi.org/10.1038/nphoton.2009.69	journal	April 2009
Polymer-Fullerene Bulk-Heterojunction Solar Cells Dennler, Gilles; Scharber, Markus C.; Brabec, Christoph J. Advanced Materials, Vol. 21, Issue 13, p. 1323-1338 https://doi.org/10.1002/adma.200801283	journal	April 2009
Effects of Thermal Annealing Upon the Morphology of Polymer-Fullerene Blends Verploegen, Eric; Mondal, Rajib; Bettinger, Christopher J. Advanced Functional Materials, Vol. 20, Issue 20 https://doi.org/10.1002/adfm.201000975	journal	August 2010
Depletion of PCBM at the Cathode Interface in P3HT/PCBM Thin Films as Quantified via Neutron Reflectivity Measurements Parnell, Andrew J.; Dunbar, Alan D. F.; Pearson, Andrew J. Advanced Materials, Vol. 22, Issue 22 https://doi.org/10.1002/adma.200903971	journal	June 2010
Simultaneous Use of Small‐ and Wide‐Angle X‐ray Techniques to Analyze Nanometerscale Phase Separation in Polymer Heterojunction Solar Cells Chiu, Mao‐Yuan; Jeng, U‐Ser; Su, Chiu‐Hun Advanced Materials, Vol. 20, Issue 13 https://doi.org/10.1002/adma.200703097	journal	July 2008
Nanoscale Phase Separation and High Photovoltaic Efficiency in Solution-Processed, Small-Molecule Bulk Heterojunction Solar Cells Walker, Bright; Tamayo, Arnold B.; Dang, Xuan-Dung Advanced Functional Materials, Vol. 19, Issue 19, p. 3063-3069 https://doi.org/10.1002/adfm.200900832	journal	October 2009
High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends Li, Gang; Shrotriya, Vishal; Huang, Jinsong Nature Materials, Vol. 4, Issue 11, p. 864-868 https://doi.org/10.1038/nmat1500	journal	October 2005
The Scope and Limitations of Ternary Blend Organic Photovoltaics Savoie, Brett M.; Dunaisky, Scott; Marks, Tobin J. Advanced Energy Materials, Vol. 5, Issue 3 https://doi.org/10.1002/aenm.201400891	journal	September 2014
Low bandgap polymers for photon harvesting in bulk heterojunction solar cells Winder, Christoph; Sariciftci, Niyazi Serdar Journal of Materials Chemistry, Vol. 14, Issue 7 https://doi.org/10.1039/b306630d	journal	January 2004
Thermally Stable, Efficient Polymer Solar Cells with Nanoscale Control of the Interpenetrating Network Morphology Ma, W.; Yang, C.; Gong, X. Advanced Functional Materials, Vol. 15, Issue 10, p. 1617-1622 https://doi.org/10.1002/adfm.200500211	journal	October 2005
Charge-Transport Anisotropy Due to Grain Boundaries in Directionally Crystallized Thin Films of Regioregular Poly(3-hexylthiophene) Jimison, Leslie H.; Toney, Michael F.; McCulloch, Iain Advanced Materials, Vol. 21, Issue 16 https://doi.org/10.1002/adma.200802722	journal	April 2009
Miscibility, Crystallinity, and Phase Development in P3HT/PCBM Solar Cells: Toward an Enlightened Understanding of Device Morphology and Stability Collins, Brian A.; Tumbleston, John R.; Ade, Harald The Journal of Physical Chemistry Letters, Vol. 2, Issue 24 https://doi.org/10.1021/jz2014902	journal	November 2011
Two-dimensional charge transport in self-organized, high-mobility conjugated polymers Sirringhaus, H.; Brown, P. J.; Friend, R. H. Nature, Vol. 401, Issue 6754, p. 685-688 https://doi.org/10.1038/44359	journal	October 1999
Ternary blend polymer solar cells with enhanced power conversion efficiency Lu, Luyao; Xu, Tao; Chen, Wei Nature Photonics, Vol. 8, Issue 9 https://doi.org/10.1038/nphoton.2014.172	journal	August 2014
10.2% Power Conversion Efficiency Polymer Tandem Solar Cells Consisting of Two Identical Sub-Cells You, Jingbi; Chen, Chun-Chao; Hong, Ziruo Advanced Materials, Vol. 25, Issue 29 https://doi.org/10.1002/adma.201300964	journal	May 2013
Dynamics of entangled linear polymer melts: A molecular‐dynamics simulation Kremer, Kurt; Grest, Gary S. The Journal of Chemical Physics, Vol. 92, Issue 8 https://doi.org/10.1063/1.458541	journal	April 1990
25th Anniversary Article: Bulk Heterojunction Solar Cells: Understanding the Mechanism of Operation Heeger, Alan J. Advanced Materials, Vol. 26, Issue 1 https://doi.org/10.1002/adma.201304373	journal	December 2013
Materials for the Active Layer of Organic Photovoltaics: Ternary Solar Cell Approach Chen, Yung-Chung; Hsu, Chih-Yu; Lin, Ryan Yeh-Yung ChemSusChem, Vol. 6, Issue 1 https://doi.org/10.1002/cssc.201200609	journal	January 2013
Optimization of thickness and morphology of active layer for high performance of bulk-heterojunction organic solar cells Min Nam, Young; Huh, June; Ho Jo, Won Solar Energy Materials and Solar Cells, Vol. 94, Issue 6 https://doi.org/10.1016/j.solmat.2010.02.041	journal	June 2010
Tandem polymer solar cells featuring a spectrally matched low-bandgap polymer Dou, Letian; You, Jingbi; Yang, Jun Nature Photonics, Vol. 6, Issue 3 https://doi.org/10.1038/nphoton.2011.356	journal	February 2012
Enhancing the Efficiency of Bulk Heterojunction Solar Cells via Templated Self-Assembly Pan, Cheng; Li, Hongfei; Akgun, Bulent Macromolecules, Vol. 46, Issue 5 https://doi.org/10.1021/ma302458d	journal	February 2013
Self‐assembly of a homopolymer mixture via phase separation Krausch, Georg; Kramer, Edward J.; Rafailovich, Miriam H. Applied Physics Letters, Vol. 64, Issue 20 https://doi.org/10.1063/1.111482	journal	May 1994
Molecular-Scale and Nanoscale Morphology of P3HT:PCBM Bulk Heterojunctions: Energy-Filtered TEM and Low-Dose HREM ^† Drummy, Lawrence F.; Davis, Robert J.; Moore, Diana L. Chemistry of Materials, Vol. 23, Issue 3 https://doi.org/10.1021/cm102463t	journal	February 2011
Charge Transport and Photocurrent Generation in Poly(3-hexylthiophene): Methanofullerene Bulk-Heterojunction Solar Cells Mihailetchi, V. D.; Xie, H. X.; de Boer, B. Advanced Functional Materials, Vol. 16, Issue 5 https://doi.org/10.1002/adfm.200500420	journal	March 2006
High-performance multiple-donor bulk heterojunction solar cells Yang, Yang (Michael); Chen, Wei; Dou, Letian Nature Photonics, Vol. 9, Issue 3 https://doi.org/10.1038/nphoton.2015.9	journal	February 2015
In situ measurement of power conversion efficiency and molecular ordering during thermal annealing in P3HT:PCBM bulk heterojunction solar cells Treat, Neil D.; Shuttle, Chris G.; Toney, Michael F. Journal of Materials Chemistry, Vol. 21, Issue 39 https://doi.org/10.1039/c1jm12677f	journal	January 2011
Recombination and loss analysis in polythiophene based bulk heterojunction photodetectors Schilinsky, Pavel; Waldauf, Christoph; Brabec, Christoph J. Applied Physics Letters, Vol. 81, Issue 20 https://doi.org/10.1063/1.1521244	journal	November 2002
P3HT/PCBM Bulk Heterojunction Organic Photovoltaics: Correlating Efficiency and Morphology Chen, Dian; Nakahara, Atsuhiro; Wei, Dongguang Nano Letters, Vol. 11, Issue 2, p. 561-567 https://doi.org/10.1021/nl103482n	journal	February 2011

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