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Title: Amidoxime Polymers for Uranium Adsorption: Influence of Comonomers and Temperature

Journal Article · · Materials
DOI:https://doi.org/10.3390/ma10111268· OSTI ID:1422243
; ; ; ;

Recovering uranium from seawater has been the subject of many studies for decades, and has recently seen significant progress in materials development since the U.S. Department of Energy (DOE) has become involved. With DOE direction, the uranium uptake for amidoxime-based polymer adsorbents has more than tripled in capacity. In an effort to better understand how these new adsorbent materials behave under different environmental stimuli, several experimental and modeling based studies have been employed to investigate impacts of competing ions, salinity, pH, and other factors on uranium uptake. For this study, the effect of temperature and type of comonomer on uranium adsorption by three different amidoxime adsorbents (AF1, 38H, AI8) was examined. Experimental measurements of uranium uptake were taken in 1–L batch reactors from 10 to 40 °C. A chemisorption model was developed and applied in order to estimate unknown system parameters through optimization. Experimental results demonstrated that the overall uranium chemisorption process for all three materials is endothermic, which was also mirrored in the model results. Model simulations show very good agreement with the data and were able to predict the temperature effect on uranium adsorption as experimental conditions changed. Here, this model may be used for predicting uranium uptake by other amidoxime materials.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE; USDOE Office of Nuclear Energy (NE), Fuel Cycle Technologies (NE-5)
Grant/Contract Number:
14-6789; AC05-00OR22725
OSTI ID:
1422243
Alternate ID(s):
OSTI ID: 1409255
Journal Information:
Materials, Journal Name: Materials Vol. 10 Journal Issue: 11; ISSN 1996-1944
Publisher:
MDPI AGCopyright Statement
Country of Publication:
Switzerland
Language:
English
Citation Metrics:
Cited by: 31 works
Citation information provided by
Web of Science

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padding-left: 0; line-height:1.8em;"> <li class="authors">Acharya, C.; Chandwadkar, P.; Joseph, D.</li> <li class="mb-0-5 source"> <span class="mr-1">Journal of Radioanalytical and Nuclear Chemistry, Vol. 295, Issue 2</span> <span class="text-muted"><a href="https://doi.org/10.1007/s10967-012-1912-x" class="text-muted" target="_blank" rel="noopener noreferrer">https://doi.org/10.1007/s10967-012-1912-x<span class="fa fa-external-link" aria-hidden="true"></span></a></span> </li> </ul> </td> <td class="small text-muted biblio-refs-td-secondary"> <span class="biblio-refs-type-badge ml-1 type" data-type="journal">journal</span> </td> <td class="small text-muted biblio-refs-td-secondary biblio-refs-td-secondary-date"><span class="date" data-date="2012-07-03">July 2012</span></td> </tr><tr> <td> <a href="https://doi.org/10.1039/c3dt32940b" target="_blank" rel="noopener noreferrer" class="title" data-title="Thermodynamic studies of Uvi complexation with glutardiamidoxime for sequestration of uranium from seawater">Thermodynamic studies of U(vi) complexation with glutardiamidoxime for sequestration of uranium from seawater<span class="fa fa-external-link" aria-hidden="true"></span></a> <ul class="small references-list mb-0 mt-0" style="list-style-type:none; padding-left: 0; line-height:1.8em;"> <li class="authors">Tian, Guoxin; Teat, Simon J.; Rao, Linfeng</li> <li class="mb-0-5 source"> <span class="mr-1">Dalton Transactions, Vol. 42, Issue 16</span> <span class="text-muted"><a href="https://doi.org/10.1039/c3dt32940b" class="text-muted" target="_blank" rel="noopener noreferrer">https://doi.org/10.1039/c3dt32940b<span class="fa fa-external-link" aria-hidden="true"></span></a></span> </li> </ul> </td> <td class="small text-muted biblio-refs-td-secondary"> <span class="biblio-refs-type-badge ml-1 type" data-type="journal">journal</span> </td> <td class="small text-muted biblio-refs-td-secondary biblio-refs-td-secondary-date"><span class="date" data-date="2013-01-01">January 2013</span></td> </tr><tr> <td> <a href="https://doi.org/10.1021/ie00080a018" target="_blank" rel="noopener noreferrer" class="title" data-title="Composite fiber adsorbent for rapid uptake of uranyl from seawater">Composite fiber adsorbent for rapid uptake of uranyl from seawater<span class="fa fa-external-link" aria-hidden="true"></span></a> <ul class="small references-list mb-0 mt-0" style="list-style-type:none; 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