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Title: Active sites engineering of metal-organic frameworks for heterogeneous catalysis

Abstract

In conclusion, we have for the first time developed a novel solid base catalyst, Ndoped MOF-253 derived porous carbons (Cz-MOF-253). Cz-MOF-253 is highly porous and exhibit high efficiency in Knoevenagel condensation reaction. Furthermore, Cz-MOF-253 is robust and can be reused up to five times. In comparison, the analogous nitrogen-free catalyst-Cz-DUT-5, and other nitrogen- MOFs derived carbon showed an inferior performance. Moreover, the high basicity and porous nature enable the design of bifunctional catalyst and facilitate tandem condensation-hydrogenation reactions. This work delineates the first attempt that demonstrates MOF-derived carbons as solid base catalyst and its potential application in tandem catalysis. Future work on exploring new catalytic reactions based on such porous Lewis basic MOF-derived carbons is currently underway.

Authors:
 [1]
  1. Iowa State Univ., Ames, IA (United States)
Publication Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1409199
Report Number(s):
IS-3200
DOE Contract Number:  
AC02-07CH11358
Resource Type:
Thesis/Dissertation
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Li, Xinle. Active sites engineering of metal-organic frameworks for heterogeneous catalysis. United States: N. p., 2016. Web. doi:10.2172/1409199.
Li, Xinle. Active sites engineering of metal-organic frameworks for heterogeneous catalysis. United States. doi:10.2172/1409199.
Li, Xinle. Sat . "Active sites engineering of metal-organic frameworks for heterogeneous catalysis". United States. doi:10.2172/1409199. https://www.osti.gov/servlets/purl/1409199.
@article{osti_1409199,
title = {Active sites engineering of metal-organic frameworks for heterogeneous catalysis},
author = {Li, Xinle},
abstractNote = {In conclusion, we have for the first time developed a novel solid base catalyst, Ndoped MOF-253 derived porous carbons (Cz-MOF-253). Cz-MOF-253 is highly porous and exhibit high efficiency in Knoevenagel condensation reaction. Furthermore, Cz-MOF-253 is robust and can be reused up to five times. In comparison, the analogous nitrogen-free catalyst-Cz-DUT-5, and other nitrogen- MOFs derived carbon showed an inferior performance. Moreover, the high basicity and porous nature enable the design of bifunctional catalyst and facilitate tandem condensation-hydrogenation reactions. This work delineates the first attempt that demonstrates MOF-derived carbons as solid base catalyst and its potential application in tandem catalysis. Future work on exploring new catalytic reactions based on such porous Lewis basic MOF-derived carbons is currently underway.},
doi = {10.2172/1409199},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {12}
}

Thesis/Dissertation:
Other availability
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