Phase transition and equation of state of dense hydrous silica up to 63&nbsp;GPa

Nisr, C.; Leinenweber, K.; Prakapenka, V.; Prescher, C.; Tkachev, S.; Shim, S. -H.  Dan

doi:10.1002/2017JB014055

Phase transition and equation of state of dense hydrous silica up to 63 GPa

Journal Article · Tue Aug 01 00:00:00 EDT 2017 · Journal of Geophysical Research. Solid Earth

DOI:https://doi.org/10.1002/2017JB014055· OSTI ID:1409086

Nisr, C. ^[1]; Leinenweber, K. ^[1]; ^[2]; ^[2]; ^[2]; ^[1]

Arizona State Univ., Tempe, AZ (United States)
Univ. of Chicago, IL (United States)

Although it has previously been considered to be essentially anhydrous, Al-free stishovite can contain up to ~1.3 wt % of H₂O, perhaps through the direct substitution (Si⁴⁺ → 4H⁺), according to recent studies. Yet the stability of such substitution and its impact on the properties of silica and rutile-structured hydrous phases (such as $$δ$$-AlOOH and phase H) are unknown at the conditions of the deeper mantle. We have synthesized hydrous and anhydrous Al-free stishovite samples at 723 K and 9 GPa, and 1473 K and 10 GPa, respectively. Synchrotron X-ray diffraction patterns show that the unit cell volume of hydrous stishovite is 1.3% greater than that of anhydrous stishovite at 1 bar, suggesting significant incorporation of OH in the crystal structure (3.2 ± 0.5 wt % H₂O). At 300 K, we found a lower and broader transition pressure from rutile type to CaCl₂ type (28–42 GPa) in hydrous dense silica. We also found that hydrous silica polymorphs are more compressible than their anhydrous counterparts. After the phase transition, the unit cell volume of hydrous silica becomes the same as that of anhydrous silica, showing that the proton incorporation through a direct substitution can be further stabilized at high pressure. The lower pressure transition and the pressure stabilization of the proton incorporation in silica would provide ways to transport and store water in the lower mantle in silica-rich heterogeneities, such as subducted oceanic crust.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: National Aeronautic and Space Administration (NASA); National Science Foundation (NSF); USDOE

Grant/Contract Number:: AC02-06CH11357; FG02-94ER14466

OSTI ID:: 1409086

Alternate ID(s):: OSTI ID: 1389093

Journal Information:: Journal of Geophysical Research. Solid Earth, Journal Name: Journal of Geophysical Research. Solid Earth Journal Issue: 9 Vol. 122; ISSN 2169-9313

Publisher:: American Geophysical UnionCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

References (47)

Stability of hydrous phase H MgSiO ₄ H ₂ under lower mantle conditions Ohtani, Eiji; Amaike, Yohei; Kamada, Seiji Geophysical Research Letters, Vol. 41, Issue 23 https://doi.org/10.1002/2014GL061690	journal	December 2014
Dry (Mg,Fe)SiO ₃ perovskite in the Earth's lower mantle Panero, Wendy R.; Pigott, Jeffrey S.; Reaman, Daniel M. Journal of Geophysical Research: Solid Earth, Vol. 120, Issue 2 https://doi.org/10.1002/2014JB011397	journal	February 2015
Stability, metastability, and elastic properties of a dense silica polymorph, seifertite: PROPERTIES OF SEIFERTITE Grocholski, B.; Shim, S. -H.; Prakapenka, V. B. Journal of Geophysical Research: Solid Earth, Vol. 118, Issue 9 https://doi.org/10.1002/jgrb.50360	journal	September 2013
Studies of OH in nominally anhydrous minerals Rossman, G. R. Physics and Chemistry of Minerals, Vol. 23, Issue 4-5 https://doi.org/10.1007/BF00207777	journal	July 1996
The equation of state of Al,H-bearing SiO2 stishovite to 58 GPa Lakshtanov, Dmitry L.; Vanpeteghem, Carine B.; Jackson, Jennifer M. Physics and Chemistry of Minerals, Vol. 32, Issue 7 https://doi.org/10.1007/s00269-005-0016-3	journal	September 2005
On the mechanisms for H and Al incorporation in stishovite Bromiley, Geoffrey D.; Bromiley, Fiona A.; Bromiley, David W. Physics and Chemistry of Minerals, Vol. 33, Issue 8-9 https://doi.org/10.1007/s00269-006-0107-9	journal	October 2006
A new hydrous phase δ-AlOOH synthesized at 21 GPa and 1000 °C Suzuki, A.; Ohtani, E.; Kamada, T. Physics and Chemistry of Minerals, Vol. 27, Issue 10 https://doi.org/10.1007/s002690000120	journal	December 2000
Phase transformations in subducted oceanic crust and buoyancy relationships at depths of 600–800 km in the mantle Irifune, T.; Ringwood, A. E. Earth and Planetary Science Letters, Vol. 117, Issue 1-2 https://doi.org/10.1016/0012-821X(93)90120-X	journal	May 1993
Water partitioning between nominally anhydrous minerals in the MgO–SiO2–H2O system up to 24 GPa: implications for the distribution of water in the Earth's mantle Bolfan-Casanova, N. Earth and Planetary Science Letters, Vol. 182, Issue 3-4 https://doi.org/10.1016/S0012-821X(00)00244-2	journal	November 2000
Phase transition and density of subducted MORB crust in the lower mantle Hirose, Kei; Takafuji, Naoto; Sata, Nagayoshi Earth and Planetary Science Letters, Vol. 237, Issue 1-2 https://doi.org/10.1016/j.epsl.2005.06.035	journal	August 2005
High hydrogen solubility in Al-rich stishovite and water transport in the lower mantle Litasov, Konstantin D.; Kagi, Hiroyuki; Shatskiy, Anton Earth and Planetary Science Letters, Vol. 262, Issue 3-4 https://doi.org/10.1016/j.epsl.2007.08.015	journal	October 2007
Water distribution across the mantle transition zone and its implications for global material circulation Karato, Shun-ichiro Earth and Planetary Science Letters, Vol. 301, Issue 3-4 https://doi.org/10.1016/j.epsl.2010.11.038	journal	January 2011
Stability of a hydrous δ-phase, AlOOH–MgSiO2(OH)2, and a mechanism for water transport into the base of lower mantle Ohira, Itaru; Ohtani, Eiji; Sakai, Takeshi Earth and Planetary Science Letters, Vol. 401 https://doi.org/10.1016/j.epsl.2014.05.059	journal	September 2014
Equation of state and post-stishovite transformation of Al-bearing silica up to 100GPa and 3000K Bolfan-Casanova, N.; Andrault, D.; Amiguet, E. Physics of the Earth and Planetary Interiors, Vol. 174, Issue 1-4 https://doi.org/10.1016/j.pepi.2008.06.024	journal	May 2009
Post-stishovite transition in hydrous aluminous SiO2 Umemoto, Koichiro; Kawamura, Katsuyuki; Hirose, Kei Physics of the Earth and Planetary Interiors, Vol. 255 https://doi.org/10.1016/j.pepi.2016.03.008	journal	June 2016
High-pressure elasticity of stishovite and the P 4 ₂ / mnm ⇌ Pnnm phase transition Carpenter, Michael A.; Hemley, Russell J.; Mao, Ho-kwang Journal of Geophysical Research: Solid Earth, Vol. 105, Issue B5 https://doi.org/10.1029/1999JB900419	journal	May 2000
High concentration of water in stishovite in the MORB system Chung, Jung In Geophysical Research Letters, Vol. 29, Issue 21 https://doi.org/10.1029/2002GL015579	journal	January 2002
Transport of water into the lower mantle: Role of stishovite: TRANSPORT OF WATER INTO THE LOWER MANTLE Panero, Wendy R.; Benedetti, Laura Robin; Jeanloz, Raymond Journal of Geophysical Research: Solid Earth, Vol. 108, Issue B1 https://doi.org/10.1029/2002JB002053	journal	January 2003
Seismic evidence for a chemical heterogeneity in the midmantle: A strong and slightly dipping seismic reflector beneath the Mariana subduction zone: SEISMIC REFLECTORS IN THE MIDMANTLE Niu, Fenglin; Kawakatsu, Hitoshi; Fukao, Yoshio Journal of Geophysical Research: Solid Earth, Vol. 108, Issue B9 https://doi.org/10.1029/2002JB002384	journal	September 2003
Water partitioning at 660 km depth and evidence for very low water solubility in magnesium silicate perovskite: WATER PARTITIONING Bolfan-Casanova, Nathalie; Keppler, Hans; Rubie, David C. Geophysical Research Letters, Vol. 30, Issue 17 https://doi.org/10.1029/2003GL017182	journal	September 2003
Phase relations and equation of state of a natural MORB: Implications for the density profile of subducted oceanic crust in the Earth's lower mantle Ricolleau, Angèle; Perrillat, Jean-Philippe; Fiquet, Guillaume Journal of Geophysical Research, Vol. 115, Issue B8 https://doi.org/10.1029/2009JB006709	journal	January 2010
Finite strain isotherm and velocities for single-crystal and polycrystalline NaCl at high pressures and 300°K Birch, Francis Journal of Geophysical Research, Vol. 83, Issue B3, p. 1257-1268 https://doi.org/10.1029/JB083iB03p01257	journal	January 1978
Seismic evidence for a 920-km discontinuity in the mantle Kawakatsu, Hitoshi; Niu, Fenglin Nature, Vol. 371, Issue 6495 https://doi.org/10.1038/371301a0	journal	September 1994
Transformation of stishovite to a denser phase at lower-mantle pressures Kingma, Kathleen J.; Cohen, Ronald E.; Hemley, Russell J. Nature, Vol. 374, Issue 6519 https://doi.org/10.1038/374243a0	journal	March 1995
Stability of hydrous silicate at high pressures and water transport to the deep lower mantle Nishi, M.; Irifune, T.; Tsuchiya, J. Nature Geoscience, Vol. 7, Issue 3 https://doi.org/10.1038/ngeo2074	journal	February 2014
Search for seismic discontinuities in the lower mantle Vinnik, Lev; Kato, Mamoru; Kawakatsu, Hitoshi Geophysical Journal International, Vol. 147, Issue 1 https://doi.org/10.1046/j.1365-246X.2001.00516.x	journal	September 2001
Toward an internally consistent pressure scale Fei, Y.; Ricolleau, A.; Frank, M. Proceedings of the National Academy of Sciences, Vol. 104, Issue 22 https://doi.org/10.1073/pnas.0609013104	journal	May 2007
The post-stishovite phase transition in hydrous alumina-bearing SiO2 in the lower mantle of the earth Lakshtanov, D. L.; Sinogeikin, S. V.; Litasov, K. D. Proceedings of the National Academy of Sciences, Vol. 104, Issue 34 https://doi.org/10.1073/pnas.0706113104	journal	August 2007
Ultrahydrous stishovite from high-pressure hydrothermal treatment of SiO2 Spektor, K.; Nylen, J.; Stoyanov, E. Proceedings of the National Academy of Sciences, Vol. 108, Issue 52 https://doi.org/10.1073/pnas.1117152108	journal	December 2011
The COMPRES/GSECARS gas-loading system for diamond anvil cells at the Advanced Photon Source Rivers, Mark; Prakapenka, Vitali; Kubo, Atsushi High Pressure Research, Vol. 28, Issue 3 https://doi.org/10.1080/08957950802333593	journal	September 2008
DIOPTAS : a program for reduction of two-dimensional X-ray diffraction data and data exploration Prescher, Clemens; Prakapenka, Vitali B. High Pressure Research, Vol. 35, Issue 3 https://doi.org/10.1080/08957959.2015.1059835	journal	May 2015
Strength and Elasticity of S i O 2 across the Stishovite– C a C l 2 -type Structural Phase Boundary Shieh, Sean R.; Duffy, Thomas S.; Li, Baosheng Physical Review Letters, Vol. 89, Issue 25 https://doi.org/10.1103/PhysRevLett.89.255507	journal	December 2002
Redetermination of the high-pressure modification of AlOOH from single-crystal synchrotron data Komatsu, Kazuki; Kuribayashi, Takahiro; Sano, Asami Acta Crystallographica Section E Structure Reports Online, Vol. 62, Issue 11 https://doi.org/10.1107/S160053680603916X	journal	October 2006
Deep Mantle Cycling of Oceanic Crust: Evidence from Diamonds and Their Mineral Inclusions Walter, M. J.; Kohn, S. C.; Araujo, D. Science, Vol. 334, Issue 6052 https://doi.org/10.1126/science.1209300	journal	September 2011
Negative Pressure-Temperature Slopes for Reactions Formign MgSiO3 Perovskite from Calorimetry Ito, E.; Akaogi, M.; Topor, L. Science, Vol. 249, Issue 4974 https://doi.org/10.1126/science.249.4974.1275	journal	September 1990
Water in Earth's Mantle: The Role of Nominally Anhydrous Minerals Bell, D. R.; Rossman, G. R. Science, Vol. 255, Issue 5050 https://doi.org/10.1126/science.255.5050.1391	journal	March 1992
Hydrogen in Stishovite, with Implications for Mantle Water Content Pawley, A. R.; McMillan, P. F.; Holloway, J. R. Science, Vol. 261, Issue 5124 https://doi.org/10.1126/science.261.5124.1024	journal	August 1993
P`P` Precursors Under Africa: Evidence for Mid-Mantle Reflectors LeStunff, Y.; Wicks, C. W.; Romanowicz, B. Science, Vol. 270, Issue 5233 https://doi.org/10.1126/science.270.5233.74	journal	October 1995
Pressure-Induced Landau-Type Transition in Stishovite Andrault, D. Science, Vol. 282, Issue 5389 https://doi.org/10.1126/science.282.5389.720	journal	October 1998
WATER, MELTING, AND THE DEEP EARTH H ₂ O CYCLE Hirschmann, Marc M. Annual Review of Earth and Planetary Sciences, Vol. 34, Issue 1 https://doi.org/10.1146/annurev.earth.34.031405.125211	journal	May 2006
H in rutile-type compounds; II, Crystal chemistry of Al substitution in H-bearing stishovite Smyth, Joseph R.; Swope, R. Jeffrey; Pawley, Alison R. American Mineralogist, Vol. 80, Issue 5-6 https://doi.org/10.2138/am-1995-5-605	journal	June 1995
Equation of state of stishovite to lower mantle pressures Andrault, Denis; Angel, Ross J.; Mosenfelder, Jed L. American Mineralogist, Vol. 88, Issue 2-3 https://doi.org/10.2138/am-2003-2-307	journal	February 2003
Formation of hydrous stishovite from coesite in high-pressure hydrothermal environments Spektor, Kristina; Nylen, Johanna; Mathew, Renny American Mineralogist, Vol. 101, Issue 11 https://doi.org/10.2138/am-2016-5609	journal	November 2016
Raman spectroscopy of water-rich stishovite and dense high-pressure silica up to 55 GPa Nisr, Carole; Shim, Sang-Heon; Leinenweber, Kurt American Mineralogist, Vol. 102, Issue 11 https://doi.org/10.2138/am-2017-5944	journal	November 2017
Change in compressibility of -AlOOH and -AlOOD at high pressure: A study of isotope effect and hydrogen-bond symmetrization Sano-Furukawa, A.; Kagi, H.; Nagai, T. American Mineralogist, Vol. 94, Issue 8-9 https://doi.org/10.2138/am.2009.3109	journal	August 2009
Cell assemblies for reproducible multi-anvil experiments (the COMPRES assemblies) Leinenweber, K. D.; Tyburczy, J. A.; Sharp, T. G. American Mineralogist, Vol. 97, Issue 2-3 https://doi.org/10.2138/am.2012.3844	journal	January 2012
Raman spectroscopy of water-rich stishovite and dense high-pressure silica up to 55 GPa Nisr, Carole; Shim, Sang-Heon; Leinenweber, Kurt American Mineralogist, Vol. 102, Issue 11 https://doi.org/10.2138/am‐2017‐5944	journal	November 2017

Cited By (1)

High Pressure‐Temperature Study on the Thermal Equations of State of Seifertite andCaCl ₂ ‐Type SiO ₂ Sun, Ningyu; Shi, Weigang; Mao, Zhu Journal of Geophysical Research: Solid Earth, Vol. 124, Issue 12 https://doi.org/10.1029/2019jb017853	journal	December 2019

Similar Records

Phase transformation of hydrous ringwoodite to the lower-mantle phases and the formation of dense hydrous silica

Journal Article · Sat Sep 19 20:00:00 EDT 2020 · American Mineralogist · OSTI ID:1780748

Evidence for the stability of ultrahydrous stishovite in Earth’s lower mantle

Journal Article · Sun Dec 15 19:00:00 EST 2019 · Proceedings of the National Academy of Sciences of the United States of America · OSTI ID:1755916

A new hydrous iron oxide phase stable at mid-mantle pressures

Journal Article · Wed Sep 02 20:00:00 EDT 2020 · Earth and Planetary Science Letters · OSTI ID:1864759

Related Subjects

58 GEOSCIENCES
direct proton substitution
equation of state
hydrous stishovite
phase transition
water in the lower mantle

Phase transition and equation of state of dense hydrous silica up to 63 GPa

Citation Formats

References (47)

Cited By (1)

Similar Records

Related Subjects