Infrared Stark and Zeeman spectroscopy of OH–CO: The entrance channel complex along the OH + CO → trans-HOCO reaction pathway

Brice, Joseph T.; Liang, Tao; Raston, Paul L.; McCoy, Anne B.; Douberly, Gary E.

doi:10.1063/1.4963226

Infrared Stark and Zeeman spectroscopy of OH–CO: The entrance channel complex along the OH + CO → trans-HOCO reaction pathway

Journal Article · Tue Sep 27 00:00:00 EDT 2016 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.4963226· OSTI ID:1409062

Brice, Joseph T. ^[1]; Liang, Tao ^[2]; ^[3]; McCoy, Anne B. ^[4]; ^[2]

Univ. of Georgia, Athens, GA (United States); University of Georgia, Athens, GA
Univ. of Georgia, Athens, GA (United States)
James Madison Univ., Harrisonburg, VA (United States)
Univ. of Washington, Seattle, WA (United States)

Here, sequential capture of OH and CO by superfluid helium droplets leads exclusively to the formation of the linear, entrance-channel complex, OH-CO. This species is characterized by infrared laser Stark and Zeeman spectroscopy via measurements of the fundamental OH stretching vibration. Experimental dipole moments are in disagreement with ab initio calculations at the equilibrium geometry, indicating large-amplitude motion on the ground state potential energy surface. Vibrational averaging along the hydroxyl bending coordinate recovers 80% of the observed deviation from the equilibrium dipole moment. Inhomogeneous line broadening in the zero-field spectrum is modeled with an effective Hamiltonian approach that aims to account for the anisotropic molecule-helium interaction potential that arises as the OH-CO complex is displaced from the center of the droplet.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Georgia Research Foundation, Athens, GA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: SC0008086

OSTI ID:: 1409062

Alternate ID(s):: OSTI ID: 1328586

Journal Information:: Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 12 Vol. 145; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

References (75)

Superfluid Helium Droplets: A Uniquely Cold Nanomatrix for Molecules and Molecular Complexes Toennies, J. Peter; Vilesov, Andrey F. Angewandte Chemie International Edition, Vol. 43, Issue 20 https://doi.org/10.1002/anie.200300611	journal	May 2004
Potential energy surfaces and properties of ICN ⁻ and ICN McCoy, Anne B. International Journal of Quantum Chemistry, Vol. 113, Issue 3 https://doi.org/10.1002/qua.24011	journal	March 2012
Transient Infrared Absorption Spectrum of the ν1 Fundamental of trans-HOCO Petty, J. T.; Moore, C. B. Journal of Molecular Spectroscopy, Vol. 161, Issue 1 https://doi.org/10.1006/jmsp.1993.1223	journal	September 1993
Far-Infrared Laser Magnetic Resonance of X̃2A′ trans-DOCO Radford, H. E.; Moore, M. A.; Sears, T. J. Journal of Molecular Spectroscopy, Vol. 165, Issue 1 https://doi.org/10.1006/jmsp.1994.1116	journal	May 1994
The mechanism of the OH + CO reaction and the stability of the HOCO radical Smith, Ian W. M. Chemical Physics Letters, Vol. 49, Issue 1 https://doi.org/10.1016/0009-2614(77)80453-3	journal	July 1977
Electronic spectroscopy of the OH–CO reactant complex Greenslade, Margaret E.; Tsiouris, Maria; Timothy Bonn, R. Chemical Physics Letters, Vol. 354, Issue 3-4 https://doi.org/10.1016/S0009-2614(02)00061-1	journal	March 2002
Rotational Spectroscopy of Diatomic Molecules Brown, John M.; Carrington, Alan https://doi.org/10.1017/CBO9780511814808	book	January 2003
Four Tautomers of Isolated Guanine from Infrared Laser Spectroscopy in Helium Nanodroplets Choi, Myong Yong; Miller, Roger E. Journal of the American Chemical Society, Vol. 128, Issue 22 https://doi.org/10.1021/ja060741l	journal	June 2006
Electron Affinities, Well Depths, and Vibrational Spectroscopy of cis - and trans -HOCO Johnson, Christopher J.; Harding, Michael E.; Poad, Berwyck L. J. Journal of the American Chemical Society, Vol. 133, Issue 49 https://doi.org/10.1021/ja207724f	journal	December 2011
The Growth of HF Polymers in Helium Nanodroplets: Probing the Barriers to Ring Insertion Douberly, G. E.; Miller, R. E. The Journal of Physical Chemistry B, Vol. 107, Issue 19 https://doi.org/10.1021/jp022360+	journal	April 2003
Structures and Bonding Nature of Small Monoligated Copper Clusters (HCN−Cu _n , n = 1−3) through High-Resolution Infrared Spectroscopy and Theory Stiles, Paul L.; Miller, Roger E. The Journal of Physical Chemistry A, Vol. 110, Issue 34 https://doi.org/10.1021/jp063187a	journal	August 2006
High-Resolution Infrared Spectroscopy of HCN−Ag _n ( n = 1−4) Complexes Solvated in Superfluid Helium Droplets ^† Stiles, Paul L.; Miller, Roger E. The Journal of Physical Chemistry A, Vol. 111, Issue 31 https://doi.org/10.1021/jp0707945	journal	August 2007
Infrared Spectroscopy of Prereactive Aluminum−, Gallium−, and Indium−HCN Entrance Channel Complexes Solvated in Helium Nanodroplets ^† Merritt, Jeremy M.; Douberly, Gary E.; Stiles, Paul L. The Journal of Physical Chemistry A, Vol. 111, Issue 49 https://doi.org/10.1021/jp074981e	journal	December 2007
Quantum Cascade Laser Spectroscopy and Photoinduced Chemistry of Al–(CO) _n Clusters in Helium Nanodroplets Liang, Tao; Flynn, Steven D.; Morrison, Alexander M. The Journal of Physical Chemistry A, Vol. 115, Issue 26 https://doi.org/10.1021/jp203367t	journal	July 2011
Quasi-Classical Trajectory Study of the HO + CO → H + CO ₂ Reaction on a New ab Initio Based Potential Energy Surface Li, Jun; Xie, Changjian; Ma, Jianyi The Journal of Physical Chemistry A, Vol. 116, Issue 21 https://doi.org/10.1021/jp302278r	journal	May 2012
HO + CO Reaction Rates and H/D Kinetic Isotope Effects: Master Equation Models with ab Initio SCTST Rate Constants Weston, Ralph E.; Nguyen, Thanh Lam; Stanton, John F. The Journal of Physical Chemistry A, Vol. 117, Issue 5 https://doi.org/10.1021/jp311928w	journal	January 2013
Anomalous Λ-Doubling in the Infrared Spectrum of the Hydroxyl Radical in Helium Nanodroplets Raston, Paul L.; Liang, Tao; Douberly, Gary E. The Journal of Physical Chemistry A, Vol. 117, Issue 34 https://doi.org/10.1021/jp312335q	journal	February 2013
Sub-Doppler Spectroscopy of the trans -HOCO Radical in the OH Stretching Mode Chang, Chih-Hsuan; Buckingham, Grant T.; Nesbitt, David J. The Journal of Physical Chemistry A, Vol. 117, Issue 50 https://doi.org/10.1021/jp403386d	journal	June 2013
Mode-Specific Tunneling in the Unimolecular Dissociation of cis -HOCO to H + CO ₂ Wang, Xiaohong; Bowman, Joel M. The Journal of Physical Chemistry A, Vol. 118, Issue 4 https://doi.org/10.1021/jp5000655	journal	January 2014
Liquid Hot NAGMA Cooled to 0.4 K: Benchmark Thermochemistry of a Gas-Phase Peptide Leavitt, Christopher M.; Moore, Kevin B.; Raston, Paul L. The Journal of Physical Chemistry A, Vol. 118, Issue 41 https://doi.org/10.1021/jp5092653	journal	October 2014
(HCN) _m −M _n (M = K, Ca, Sr): Vibrational Excitation Induced Solvation and Desolvation of Dopants in and on Helium Nanodroplets Douberly, Gary E.; Stiles, Paul L.; Miller, Roger E. The Journal of Physical Chemistry A, Vol. 114, Issue 10 https://doi.org/10.1021/jp908834m	journal	March 2010
OH(OD) + CO: Measurements and an Optimized RRKM Fit Golden, D. M.; Smith, G. P.; McEwen, A. B. The Journal of Physical Chemistry A, Vol. 102, Issue 44 https://doi.org/10.1021/jp982110m	journal	October 1998
Reaction of HO with CO: Tunneling Is Indeed Important Nguyen, Thanh Lam; Xue, Bert C.; Weston, Ralph E. The Journal of Physical Chemistry Letters, Vol. 3, Issue 11 https://doi.org/10.1021/jz300443a	journal	May 2012
Quantum Dynamics of the HO + CO → H + CO ₂ Reaction on an Accurate Potential Energy Surface Ma, Jianyi; Li, Jun; Guo, Hua The Journal of Physical Chemistry Letters, Vol. 3, Issue 17 https://doi.org/10.1021/jz301064w	journal	August 2012
Dipole Moment of the HOOO Radical: Resolution of a Structural Enigma Liang, Tao; Magers, D. Brandon; Raston, Paul L. The Journal of Physical Chemistry Letters, Vol. 4, Issue 21 https://doi.org/10.1021/jz401927b	journal	October 2013
A high-resolution infrared spectroscopic investigation of the halogen atom–HCN entrance channel complexes solvated in superfluid helium droplets Merritt, Jeremy M.; Küpper, Jochen; Miller, Roger E. Phys. Chem. Chem. Phys., Vol. 9, Issue 3 https://doi.org/10.1039/B611340K	journal	January 2007
Spectroscopy and dynamics of the HOCO radical: insights into the OH + CO → H + CO ₂ reaction Johnson, Christopher J.; Otto, Rico; Continetti, Robert E. Phys. Chem. Chem. Phys., Vol. 16, Issue 36 https://doi.org/10.1039/C4CP02593H	journal	January 2014
Rate measurements of reactions of OH by resonance absorption. Part 2.—Reactions of OH with CO, C ₂ H ₄ and C ₂ H ₂ Smith, Ian W. M.; Zellner, Reinhard J. Chem. Soc., Faraday Trans. 2, Vol. 69, Issue 0 https://doi.org/10.1039/F29736901617	journal	January 1973
Mapping the OH+CO→HOCO reaction pathway through IR spectroscopy of the OH–CO reactant complex Lester, Marsha I.; Pond, Bethany V.; Marshall, Mark D. Faraday Discussions, Vol. 118 https://doi.org/10.1039/b009421h	journal	January 2001
Rotovibrational spectroscopy of hydrogen peroxide embedded in superfluid helium nanodroplets Raston, Paul L.; Knapp, Chrissy J.; Jäger, Wolfgang Physical Chemistry Chemical Physics, Vol. 13, Issue 42 https://doi.org/10.1039/c1cp21348b	journal	January 2011
Finite size effects and rotational relaxation in superfluid helium nanodroplets: Microwave-infrared double-resonance spectroscopy of cyanoacetylene Callegari, C.; Reinhard, I.; Lehmann, K. K. The Journal of Chemical Physics, Vol. 113, Issue 11 https://doi.org/10.1063/1.1288604	journal	September 2000
First overtone helium nanodroplet isolation spectroscopy of molecules bearing the acetylenic CH chromophore Callegari, C.; Conjusteau, A.; Reinhard, I. The Journal of Chemical Physics, Vol. 113, Issue 23 https://doi.org/10.1063/1.1324003	journal	December 2000
Exploring the OH+CO reaction coordinate via infrared spectroscopy of the OH–CO reactant complex Lester, Marsha I.; Pond, Bethany V.; Anderson, David T. The Journal of Chemical Physics, Vol. 113, Issue 22 https://doi.org/10.1063/1.1330235	journal	December 2000
Rotation in liquid [sup 4]He: Lessons from a highly simplified model Lehmann, Kevin K. The Journal of Chemical Physics, Vol. 114, Issue 10 https://doi.org/10.1063/1.1334620	journal	January 2001
Inhomogeneous broadening of the zero phonon line of phthalocyanine in superfluid helium droplets Slenczka, Alkwin; Dick, Bernhard; Hartmann, Matthias The Journal of Chemical Physics, Vol. 115, Issue 22 https://doi.org/10.1063/1.1409353	journal	January 2001
Inhomogeneous line shape theory of electronic transitions for molecules embedded in superfluid helium droplets Dick, Bernhard; Slenczka, Alkwin The Journal of Chemical Physics, Vol. 115, Issue 22 https://doi.org/10.1063/1.1409354	journal	January 2001
Intermolecular vibrations of the hydrogen bonded OH–CO reactant complex Marshall, Mark D.; Pond, Bethany V.; Lester, Marsha I. The Journal of Chemical Physics, Vol. 118, Issue 3 https://doi.org/10.1063/1.1527921	journal	January 2003
Decay dynamics of the vibrationally activated OH–CO reactant complex Pond, Bethany V.; Lester, Marsha I. The Journal of Chemical Physics, Vol. 118, Issue 5 https://doi.org/10.1063/1.1533753	journal	February 2003
Infrared action spectroscopy and time-resolved dynamics of the OD–CO reactant complex Pollack, Ilana B.; Tsiouris, Maria; Leung, Helen O. The Journal of Chemical Physics, Vol. 119, Issue 1 https://doi.org/10.1063/1.1577320	journal	July 2003
Infrared spectra of trans -HOCO, HCOOH+, and HCO2− trapped in solid neon Forney, Daniel; Jacox, Marilyn E.; Thompson, Warren E. The Journal of Chemical Physics, Vol. 119, Issue 20 https://doi.org/10.1063/1.1621382	journal	November 2003
Infrared Spectrum and Structure of Intermediates in the Reaction of OH with CO Milligan, Dolphus E.; Jacox, Marilyn E. The Journal of Chemical Physics, Vol. 54, Issue 3 https://doi.org/10.1063/1.1675022	journal	February 1971
Infrared–infrared double resonance spectroscopy of cyanoacetylene in helium nanodroplets Merritt, J. M.; Douberly, G. E.; Miller, R. E. The Journal of Chemical Physics, Vol. 121, Issue 3 https://doi.org/10.1063/1.1763147	journal	July 2004
Computational spectroscopy of helium-solvated molecules: Effective inertia, from small He clusters toward the nanodroplet regime Paolini, Stefano; Fantoni, Stefano; Moroni, Saverio The Journal of Chemical Physics, Vol. 123, Issue 11 https://doi.org/10.1063/1.2032969	journal	September 2005
Evidence for an energy level substructure of molecular states in helium droplets Lehnig, Rudolf; Blinov, Nicholas V.; Jäger, Wolfgang The Journal of Chemical Physics, Vol. 127, Issue 24 https://doi.org/10.1063/1.2822041	journal	December 2007
Using He droplets for measurements of interconversion enthalpy of conformers in 2-chloroethanol Skvortsov, Dmitry S.; Vilesov, Andrey F. The Journal of Chemical Physics, Vol. 130, Issue 15 https://doi.org/10.1063/1.3111969	journal	April 2009
Observation of the pure rotational spectra of trans - and cis -HOCO Oyama, Takahiro; Funato, Wataru; Sumiyoshi, Yoshihiro The Journal of Chemical Physics, Vol. 134, Issue 17 https://doi.org/10.1063/1.3578179	journal	May 2011
Communication: New insight into the barrier governing CO2 formation from OH + CO Johnson, Christopher J.; Poad, Berwyck L. J.; Shen, Ben B. The Journal of Chemical Physics, Vol. 134, Issue 17 https://doi.org/10.1063/1.3589860	journal	May 2011
Communication: State-to-state quantum dynamics study of the OH + CO → H + CO ₂ reaction in full dimensions ( J = 0) Liu, Shu; Xu, Xin; Zhang, Dong H. The Journal of Chemical Physics, Vol. 135, Issue 14 https://doi.org/10.1063/1.3653787	journal	October 2011
Communication: A chemically accurate global potential energy surface for the HO + CO → H + CO ₂ reaction Li, Jun; Wang, Yimin; Jiang, Bin The Journal of Chemical Physics, Vol. 136, Issue 4 https://doi.org/10.1063/1.3680256	journal	January 2012
The vibrational spectrum of the t ‐HOCO free radical trapped in solid argon Jacox, Marilyn E. The Journal of Chemical Physics, Vol. 88, Issue 8 https://doi.org/10.1063/1.453772	journal	April 1988
Gaussian basis sets for use in correlated molecular calculations. I. The atoms boron through neon and hydrogen Dunning, Thom H. The Journal of Chemical Physics, Vol. 90, Issue 2 https://doi.org/10.1063/1.456153	journal	January 1989
A novel discrete variable representation for quantum mechanical reactive scattering via the S ‐matrix Kohn method Colbert, Daniel T.; Miller, William H. The Journal of Chemical Physics, Vol. 96, Issue 3 https://doi.org/10.1063/1.462100	journal	February 1992
The rotational spectrum of trans ‐HOCO and DOCO Radford, H. E.; Wei, Wang; Sears, Trevor J. The Journal of Chemical Physics, Vol. 97, Issue 6 https://doi.org/10.1063/1.462938	journal	September 1992
Transient diode laser absorption spectroscopy of the ν ₂ fundamental of trans ‐HOCO and DOCO Sears, Trevor J.; Fawzy, Wafaa M.; Johnson, Philip M. The Journal of Chemical Physics, Vol. 97, Issue 6 https://doi.org/10.1063/1.462939	journal	September 1992
b ‐dipole transitions in trans ‐HOCO observed by far infrared laser magnetic resonance Sears, Trevor J.; Radford, H. E.; Moore, Mary Ann The Journal of Chemical Physics, Vol. 98, Issue 9 https://doi.org/10.1063/1.465098	journal	May 1993
Transient infrared absorption spectrum of the ν1 fundamental of trans‐DOCO Petty, Jeffrey T.; Moore, C. Bradley The Journal of Chemical Physics, Vol. 99, Issue 1 https://doi.org/10.1063/1.465773	journal	July 1993
High pressure range of addition reactions of HO. II. Temperature and pressure dependence of the reaction HO+CO⇔HOCO→H+CO ₂ Fulle, D.; Hamann, H. F.; Hippler, H. The Journal of Chemical Physics, Vol. 105, Issue 3 https://doi.org/10.1063/1.471991	journal	July 1996
Reactive quenching of OH A ² Σ ⁺ by O ₂ and CO: Experimental and nonadiabatic theoretical studies of H- and O-atom product channels Lehman, Julia H.; Lester, Marsha I.; Yarkony, David R. The Journal of Chemical Physics, Vol. 137, Issue 9 https://doi.org/10.1063/1.4748376	journal	September 2012
Infrared spectroscopy of HOOO and DOOO in ⁴ He nanodroplets Raston, Paul L.; Liang, Tao; Douberly, Gary E. The Journal of Chemical Physics, Vol. 137, Issue 18 https://doi.org/10.1063/1.4764298	journal	November 2012
Automation of an “Aculight” continuous-wave optical parametric oscillator Morrison, Alexander M.; Liang, Tao; Douberly, Gary E. Review of Scientific Instruments, Vol. 84, Issue 1 https://doi.org/10.1063/1.4776179	journal	January 2013
High resolution vibronic spectra of the amino acids tryptophan and tyrosine in 0.38 K cold helium droplets Lindinger, Albrecht; Toennies, J. Peter; Vilesov, Andrei F. The Journal of Chemical Physics, Vol. 110, Issue 3 https://doi.org/10.1063/1.478018	journal	January 1999
Full-dimensional characterization of photoelectron spectra of HOCO ⁻ and DOCO ⁻ and tunneling facilitated decay of HOCO prepared by anion photodetachment Wang, Jun; Li, Jun; Ma, Jianyi The Journal of Chemical Physics, Vol. 140, Issue 18 https://doi.org/10.1063/1.4874975	journal	May 2014
Observation of the Q (3/2) Λ-doublet transitions for X ² Π _3/2 OD in helium nanodroplets Raston, Paul L.; Liang, Tao; Douberly, Gary E. Molecular Physics, Vol. 112, Issue 2 https://doi.org/10.1080/00268976.2013.809807	journal	June 2013
Potential of a neutral impurity in a large ⁴ He cluster Lehmann, Kevin K. Molecular Physics, Vol. 97, Issue 5 https://doi.org/10.1080/002689799163497	journal	September 1999
Infrared spectroscopy of helium nanodroplets: novel methods for physics and chemistry Choi, M. Y.; Douberly, G. E.; Falconer, T. M. International Reviews in Physical Chemistry, Vol. 25, Issue 1-2 https://doi.org/10.1080/01442350600625092	journal	January 2006
Quantum dynamics of complex-forming bimolecular reactions Guo, H. International Reviews in Physical Chemistry, Vol. 31, Issue 1 https://doi.org/10.1080/0144235X.2011.649999	journal	January 2012
Spectroscopy and dynamics in helium nanodroplets Stienkemeier, Frank; Lehmann, Kevin K. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 39, Issue 8 https://doi.org/10.1088/0953-4075/39/8/R01	journal	April 2006
ν 4 band of CH 4 in helium nanodroplets: A probe of the dynamical response of a superfluid Ravi, Aakash; Kuma, Susumu; Yearwood, Christopher Physical Review A, Vol. 84, Issue 2 https://doi.org/10.1103/PhysRevA.84.020502	journal	August 2011
Tunneling Facilitated Dissociation to H + CO 2 in HOCO − Photodetachment Ma, Jianyi; Li, Jun; Guo, Hua Physical Review Letters, Vol. 109, Issue 6 https://doi.org/10.1103/PhysRevLett.109.063202	journal	August 2012
Rotationally Resolved Spectroscopy of S F 6 in Liquid Helium Clusters: A Molecular Probe of Cluster Temperature Hartmann, M.; Miller, R. E.; Toennies, J. P. Physical Review Letters, Vol. 75, Issue 8 https://doi.org/10.1103/PhysRevLett.75.1566	journal	August 1995
Stark Spectroscopy of Polar Molecules Solvated in Liquid Helium Droplets Nauta, K.; Miller, R. E. Physical Review Letters, Vol. 82, Issue 22 https://doi.org/10.1103/PhysRevLett.82.4480	journal	May 1999
Dipole Moments of Molecules Solvated in Helium Nanodroplets Stiles, Paul L.; Nauta, Klaas; Miller, Roger E. Physical Review Letters, Vol. 90, Issue 13 https://doi.org/10.1103/PhysRevLett.90.135301	journal	April 2003
Nonequilibrium Self-Assembly of Long Chains of Polar Molecules in Superfluid Helium Nauta, K. Science, Vol. 283, Issue 5409 https://doi.org/10.1126/science.283.5409.1895	journal	March 1999
Formation of Cyclic Water Hexamer in Liquid Helium: The Smallest Piece of Ice Nauta, K. Science, Vol. 287, Issue 5451 https://doi.org/10.1126/science.287.5451.293	journal	January 2000
Theoretical Methods for Rovibrational States of Floppy Molecules Bacic, Z.; Light, J. C. Annual Review of Physical Chemistry, Vol. 40, Issue 1 https://doi.org/10.1146/annurev.pc.40.100189.002345	journal	October 1989

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