Metal–organic layers stabilize earth-abundant metal–terpyridine diradical complexes for catalytic C–H activation

Lin, Zekai; Thacker, Nathan C.; Sawano, Takahiro; Drake, Tasha; Ji, Pengfei; Lan, Guangxu; Cao, Lingyun; Liu, Shubin; Wang, Cheng; Lin, Wenbin

doi:10.1039/C7SC03537C

Title: Metal–organic layers stabilize earth-abundant metal–terpyridine diradical complexes for catalytic C–H activation

Journal Article · Mon Jan 01 00:00:00 EST 2018 · Chemical Science

DOI:https://doi.org/10.1039/C7SC03537C· OSTI ID:1408785

Lin, Zekai ^[1]; Thacker, Nathan C. ^[1]; Sawano, Takahiro ^[1]; Drake, Tasha ^[1]; Ji, Pengfei ^[1]; Lan, Guangxu ^[1]; Cao, Lingyun ^[2]; Liu, Shubin ^[3];

^[2];

^[4]

Department of Chemistry, University of Chicago, Chicago, USA
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University
Research Computing Center, University of North Carolina, USA
Department of Chemistry, University of Chicago, Chicago, USA, Collaborative Innovation Center of Chemistry for Energy Materials

Metal–organic layers stabilize Fe ^II or Co ^II -terpyridine diradical complexes to catalyze alkylazide C _sp3 –H amination and benzylic C–H borylation, respectively.

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1408785

Journal Information:: Chemical Science, Journal Name: Chemical Science Vol. 9 Journal Issue: 1; ISSN 2041-6520

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

Citation Metrics:

Cited by: 71 works

Citation information provided by
Web of Science

References (74)

Metal–organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations Chughtai, Adeel H.; Ahmad, Nazir; Younus, Hussein A. Chemical Society Reviews, Vol. 44, Issue 19 https://doi.org/10.1039/C4CS00395K	journal	January 2015
Nanoscale Metal–Organic Frameworks for the Co-Delivery of Cisplatin and Pooled siRNAs to Enhance Therapeutic Efficacy in Drug-Resistant Ovarian Cancer Cells He, Chunbai; Lu, Kuangda; Liu, Demin Journal of the American Chemical Society, Vol. 136, Issue 14 https://doi.org/10.1021/ja4098862	journal	February 2014
Robust, Chiral, and Porous BINAP-Based Metal–Organic Frameworks for Highly Enantioselective Cyclization Reactions Sawano, Takahiro; Thacker, Nathan C.; Lin, Zekai Journal of the American Chemical Society, Vol. 137, Issue 38 https://doi.org/10.1021/jacs.5b09225	journal	September 2015
C–H Functionalization Reactivity of a Nickel–Imide Wiese, Stefan; McAfee, Jason L.; Pahls, Dale R. Journal of the American Chemical Society, Vol. 134, Issue 24 https://doi.org/10.1021/ja302149k	journal	June 2012
Electronic absorption spectra of the iron(II) complexes of 2,2'-bipyridine, 2,2'-bipyrimidine, 1,10-phenanthroline, and 2,2':6',2''-terpyridine and their reduction products Braterman, Paul S.; Song, Jae Inh; Peacock, Robert D. Inorganic Chemistry, Vol. 31, Issue 4 https://doi.org/10.1021/ic00030a006	journal	February 1992
Asymmetric Catalysis with Chiral Porous Metal–Organic Frameworks: Critical Issues Wang, Cheng; Zheng, Min; Lin, Wenbin The Journal of Physical Chemistry Letters, Vol. 2, Issue 14 https://doi.org/10.1021/jz200492d	journal	June 2011
Functional soft materials from metallopolymers and metallosupramolecular polymers Whittell, George R.; Hager, Martin D.; Schubert, Ulrich S. Nature Materials, Vol. 10, Issue 3 https://doi.org/10.1038/nmat2966	journal	February 2011
Electronic Structures of the Electron Transfer Series [M(bpy) ₃ ] ⁿ , [M(tpy) ₂ ] ⁿ , and [Fe( ^t bpy) ₃ ] ⁿ (M = Fe, Ru; n = 3+, 2+, 1+, 0, 1-): A Mössbauer Spectroscopic and DFT Study : [M(bpy) England, Jason; Scarborough, Christopher C.; Weyhermüller, Thomas European Journal of Inorganic Chemistry, Vol. 2012, Issue 29 https://doi.org/10.1002/ejic.201200232	journal	June 2012
Metal–organic framework materials as catalysts Lee, JeongYong; Farha, Omar K.; Roberts, John Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459 https://doi.org/10.1039/b807080f	journal	January 2009
Terpyridines and their Complexes with First Row Transition Metal Ions:Cytotoxicity, Nuclease Activity and Self-Assembly of Biomacromolecules Winter, Andreas; Gottschaldt, Michael; R. Newkome, George Current Topics in Medicinal Chemistry, Vol. 12, Issue 3 https://doi.org/10.2174/156802612799078919	journal	February 2012
Crystal Engineering of NLO Materials Based on Metal−Organic Coordination Networks Evans, Owen R.; Lin, Wenbin Accounts of Chemical Research, Vol. 35, Issue 7 https://doi.org/10.1021/ar0001012	journal	July 2002
Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination Hennessy, E. T.; Betley, T. A. Science, Vol. 340, Issue 6132 https://doi.org/10.1126/science.1233701	journal	May 2013
Benzyltriboronates: Building Blocks for Diastereoselective Carbon–Carbon Bond Formation Palmer, W. Neil; Zarate, Cayetana; Chirik, Paul J. Journal of the American Chemical Society, Vol. 139, Issue 7 https://doi.org/10.1021/jacs.6b12896	journal	February 2017
The Marriage of Terpyridines and Inorganic Nanoparticles: Synthetic Aspects, Characterization Techniques, and Potential Applications Winter, Andreas; Hager, Martin D.; Newkome, George R. Advanced Materials, Vol. 23, Issue 48 https://doi.org/10.1002/adma.201103612	journal	November 2011
Iridium-Catalyzed Borylation of Primary Benzylic C–H Bonds without a Directing Group: Scope, Mechanism, and Origins of Selectivity Larsen, Matthew A.; Wilson, Conner V.; Hartwig, John F. Journal of the American Chemical Society, Vol. 137, Issue 26 https://doi.org/10.1021/jacs.5b04899	journal	June 2015
Square-Planar Pd(II), Pt(II), and Au(III) Terpyridine Complexes: Their Syntheses, Physical Properties, Supramolecular Constructs, and Biomedical Activities Eryazici, Ibrahim; Moorefield, Charles N.; Newkome, George R. Chemical Reviews, Vol. 108, Issue 6 https://doi.org/10.1021/cr0781059	journal	June 2008
Catalytic Synthesis of N-Heterocycles via Direct C(sp ³ )–H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand Bagh, Bidraha; Broere, Daniël L. J.; Sinha, Vivek Journal of the American Chemical Society, Vol. 139, Issue 14 https://doi.org/10.1021/jacs.7b00270	journal	March 2017
Oxidation of ethane to ethanol by N2O in a metal–organic framework with coordinatively unsaturated iron(II) sites Xiao, Dianne J.; Bloch, Eric D.; Mason, Jarad A. Nature Chemistry, Vol. 6, Issue 7 https://doi.org/10.1038/nchem.1956	journal	May 2014
Manganese terpyridine artificial metalloenzymes for benzylic oxygenation and olefin epoxidation Zhang, Chen; Srivastava, Poonam; Ellis-Guardiola, Ken Tetrahedron, Vol. 70, Issue 27-28 https://doi.org/10.1016/j.tet.2014.03.008	journal	July 2014
Hydrogen storage in metal–organic frameworks Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R. Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314 https://doi.org/10.1039/b802256a	journal	January 2009
Light-Emitting Self-Assembled Materials Based on d ⁸ and d ¹⁰ Transition Metal Complexes Yam, Vivian Wing-Wah; Au, Vonika Ka-Man; Leung, Sammual Yu-Lut Chemical Reviews, Vol. 115, Issue 15 https://doi.org/10.1021/acs.chemrev.5b00074	journal	July 2015
Diradicals Abe, Manabu Chemical Reviews, Vol. 113, Issue 9 https://doi.org/10.1021/cr400056a	journal	July 2013
Highly Efficient Cooperative Catalysis by Co ^III (Porphyrin) Pairs in Interpenetrating Metal-Organic Frameworks Lin, Zekai; Zhang, Zhi-Ming; Chen, Yu-Sheng Angewandte Chemie International Edition, Vol. 55, Issue 44 https://doi.org/10.1002/anie.201605802	journal	October 2016
Catalytic Hydrosilylation of Alkenes by Iron Complexes Containing Terpyridine Derivatives as Ancillary Ligands Kamata, Kouji; Suzuki, Atsuko; Nakai, Yuta Organometallics, Vol. 31, Issue 10 https://doi.org/10.1021/om300279t	journal	May 2012
Hydrogen Storage in Microporous Metal-Organic Frameworks Rosi, Nathaniel L.; Eckert, Juergen; Eddaoudi, Mohamed Science, Vol. 300, Issue 5622, p. 1127-1129 https://doi.org/10.1126/science.1083440	journal	May 2003
Nanoscale Metal–Organic Frameworks for Biomedical Imaging and Drug Delivery Della Rocca, Joseph; Liu, Demin; Lin, Wenbin Accounts of Chemical Research, Vol. 44, Issue 10, p. 957-968 https://doi.org/10.1021/ar200028a	journal	October 2011
Top-down fabrication of crystalline metal–organic framework nanosheets Li, Pei-Zhou; Maeda, Yasushi; Xu, Qiang Chemical Communications, Vol. 47, Issue 29, p. 8436-8438 https://doi.org/10.1039/c1cc12510a	journal	January 2011
Enantioselective catalysis with homochiral metal–organic frameworks Ma, Liqing; Abney, Carter; Lin, Wenbin Chemical Society Reviews, Vol. 38, Issue 5, p. 1248-1256 https://doi.org/10.1039/b807083k	journal	January 2009
Formation of Aryl- and Benzylboronate Esters by Rhodium-Catalyzed C−H Bond Functionalization with Pinacolborane Shimada, Shigeru; Batsanov, Andrei S.; Howard, Judith A. K. Angewandte Chemie International Edition, Vol. 40, Issue 11 https://doi.org/10.1002/1521-3773(20010601)40:11<2168::AID-ANIE2168>3.0.CO;2-0	journal	June 2001
Molecular and Electronic Structures of Six-Coordinate “Low-Valent” [M( ^Me bpy) ₃ ] ⁰ (M = Ti, V, Cr, Mo) and [M(tpy) ₂ ] ⁰ (M = Ti, V, Cr), and Seven-Coordinate [MoF( ^Me bpy) ₃ ](PF ₆ ) and [MX(tpy) ₂ ](PF ₆ ) (M = Mo, X = Cl and M = W, X = F) Wang, Mei; Weyhermüller, Thomas; England, Jason Inorganic Chemistry, Vol. 52, Issue 21 https://doi.org/10.1021/ic402037e	journal	October 2013
Nanoscale Metal−Organic Frameworks as Potential Multimodal Contrast Enhancing Agents Rieter, William J.; Taylor, Kathryn M. L.; An, Hongyu Journal of the American Chemical Society, Vol. 128, Issue 28 https://doi.org/10.1021/ja0627444	journal	July 2006
Robust and Porous β-Diketiminate-Functionalized Metal–Organic Frameworks for Earth-Abundant-Metal-Catalyzed C–H Amination and Hydrogenation Thacker, Nathan C.; Lin, Zekai; Zhang, Teng Journal of the American Chemical Society, Vol. 138, Issue 10 https://doi.org/10.1021/jacs.5b13394	journal	March 2016
Engineering Chiral Polyoxometalate Hybrid Metal–Organic Frameworks for Asymmetric Dihydroxylation of Olefins Han, Qiuxia; He, Cheng; Zhao, Min Journal of the American Chemical Society, Vol. 135, Issue 28 https://doi.org/10.1021/ja401758c	journal	May 2013
Ligand Effects on Hydrogen Atom Transfer from Hydrocarbons to Three-Coordinate Iron Imides Cowley, Ryan E.; Holland, Patrick L. Inorganic Chemistry, Vol. 51, Issue 15 https://doi.org/10.1021/ic300870y	journal	July 2012
Single-Site Heterogeneous Catalysts for Olefin Polymerization Enabled by Cation Exchange in a Metal-Organic Framework Comito, Robert J.; Fritzsching, Keith J.; Sundell, Benjamin J. Journal of the American Chemical Society, Vol. 138, Issue 32 https://doi.org/10.1021/jacs.6b05200	journal	August 2016
Ligand Redox Effects in the Synthesis, Electronic Structure, and Reactivity of an Alkyl−Alkyl Cross-Coupling Catalyst Jones, Gavin D.; Martin, Jason L.; McFarland, Chris Journal of the American Chemical Society, Vol. 128, Issue 40 https://doi.org/10.1021/ja063334i	journal	October 2006
Anomalous paramagnetism of copper acetate Bleaney, Brebis; Powers, K. D. Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, Vol. 214, Issue 1119, p. 451-465 https://doi.org/10.1098/rspa.1952.0181	journal	October 1952
Bis(imino)pyridine Iron Dinitrogen Compounds Revisited: Differences in Electronic Structure Between Four- and Five-Coordinate Derivatives. Stieber, S. Chantal E.; Milsmann, Carsten; Hoyt, Jordan M. Inorganic Chemistry, Vol. 51, Issue 6 https://doi.org/10.1021/ic202750n	journal	March 2012
Copper-Nitrene Complexes in Catalytic CH Amination Badiei, Yosra M.; Dinescu, Adriana; Dai, Xuliang Angewandte Chemie International Edition, Vol. 47, Issue 51 https://doi.org/10.1002/anie.200804304	journal	December 2008
Nanoscale Coordination Polymers for Platinum-Based Anticancer Drug Delivery Rieter, William J.; Pott, Kimberly M.; Taylor, Kathryn M. L. Journal of the American Chemical Society, Vol. 130, Issue 35 https://doi.org/10.1021/ja803383k	journal	September 2008
Luminescent metal–organic frameworks for chemical sensing and explosive detection Hu, Zhichao; Deibert, Benjamin J.; Li, Jing Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00010B	journal	January 2014
Rational Synthesis of Noncentrosymmetric Metal–Organic Frameworks for Second-Order Nonlinear Optics Wang, Cheng; Zhang, Teng; Lin, Wenbin Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200252n	journal	September 2011
Metal-organic framework nanosheets as building blocks for molecular sieving membranes Peng, Y.; Li, Y.; Ban, Y. Science, Vol. 346, Issue 6215 https://doi.org/10.1126/science.1254227	journal	December 2014
Singlet Oxygen-Engaged Selective Photo-Oxidation over Pt Nanocrystals/Porphyrinic MOF: The Roles of Photothermal Effect and Pt Electronic State Chen, Yu-Zhen; Wang, Zhiyong U.; Wang, Hengwei Journal of the American Chemical Society, Vol. 139, Issue 5 https://doi.org/10.1021/jacs.6b12074	journal	January 2017
Metal–Organic Frameworks Stabilize Solution-Inaccessible Cobalt Catalysts for Highly Efficient Broad-Scope Organic Transformations Zhang, Teng; Manna, Kuntal; Lin, Wenbin Journal of the American Chemical Society, Vol. 138, Issue 9 https://doi.org/10.1021/jacs.6b00849	journal	February 2016
Pd Nanocubes@ZIF-8: Integration of Plasmon-Driven Photothermal Conversion with a Metal-Organic Framework for Efficient and Selective Catalysis Yang, Qihao; Xu, Qiang; Yu, Shu-Hong Angewandte Chemie International Edition, Vol. 55, Issue 11 https://doi.org/10.1002/anie.201510655	journal	January 2016
Carbon Dioxide Capture in Metal–Organic Frameworks Sumida, Kenji; Rogow, David L.; Mason, Jarad A. Chemical Reviews, Vol. 112, Issue 2, p. 724-781 https://doi.org/10.1021/cr2003272	journal	September 2011
Chemoselective single-site Earth-abundant metal catalysts at metal–organic framework nodes Manna, Kuntal; Ji, Pengfei; Lin, Zekai Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12610	journal	August 2016
Highly efficient oxidative carbon–carbon coupling with SBA-15-support iron terpyridine catalyst Liu, Peng; Zhou, Cong-Ying; Xiang, Song Chemical Communications, Vol. 46, Issue 16 https://doi.org/10.1039/c001209b	journal	January 2010
Cobalt-Catalyzed C(sp ² )–H Borylation with an Air-Stable, Readily Prepared Terpyridine Cobalt(II) Bis(acetate) Precatalyst Léonard, Nadia G.; Bezdek, Máté J.; Chirik, Paul J. Organometallics, Vol. 36, Issue 1 https://doi.org/10.1021/acs.organomet.6b00630	journal	October 2016
Localized states in reduced and excited-state ruthenium(II) terpyridyls Berger, Robert M.; McMillin, David R. Inorganic Chemistry, Vol. 27, Issue 23 https://doi.org/10.1021/ic00296a032	journal	November 1988
Large-Area, Free-Standing, Two-Dimensional Supramolecular Polymer Single-Layer Sheets for Highly Efficient Electrocatalytic Hydrogen Evolution Dong, Renhao; Pfeffermann, Martin; Liang, Haiwei Angewandte Chemie International Edition, Vol. 54, Issue 41 https://doi.org/10.1002/anie.201506048	journal	August 2015
Electrochemistry and Spectroscopy of Organometallic Terpyridine Nickel Complexes Hamacher, Claudia; Hurkes, Natascha; Kaiser, André Inorganic Chemistry, Vol. 48, Issue 20 https://doi.org/10.1021/ic900753r	journal	October 2009
Reduction Chemistry of Aryl- and Alkyl-Substituted Bis(imino)pyridine Iron Dihalide Compounds: Molecular and Electronic Structures of [(PDI) ₂ Fe] Derivatives Wile, Bradley M.; Trovitch, Ryan J.; Bart, Suzanne C. Inorganic Chemistry, Vol. 48, Issue 9 https://doi.org/10.1021/ic801623m	journal	May 2009
Metal–Organic Frameworks Stabilize Mono(phosphine)–Metal Complexes for Broad-Scope Catalytic Reactions Sawano, Takahiro; Lin, Zekai; Boures, Dean Journal of the American Chemical Society, Vol. 138, Issue 31 https://doi.org/10.1021/jacs.6b06239	journal	July 2016
Destruction of chemical warfare agents using metal–organic frameworks Mondloch, Joseph E.; Katz, Michael J.; Isley III, William C. Nature Materials, Vol. 14, Issue 5 https://doi.org/10.1038/nmat4238	journal	March 2015
A New Approach to Non-Coordinating Anions: Lewis Acid Enhancement of Porphyrin Metal Centers in a Zwitterionic Metal–Organic Framework Johnson, Jacob A.; Petersen, Brenna M.; Kormos, Attila Journal of the American Chemical Society, Vol. 138, Issue 32 https://doi.org/10.1021/jacs.6b05626	journal	August 2016
A Chiral Porous Metal–Organic Framework for Highly Sensitive and Enantioselective Fluorescence Sensing of Amino Alcohols Wanderley, Marcela M.; Wang, Cheng; Wu, Chuan-De Journal of the American Chemical Society, Vol. 134, Issue 22 https://doi.org/10.1021/ja302110d	journal	May 2012
Molecular and Electronic Structures of Homoleptic Six-Coordinate Cobalt(I) Complexes of 2,2′:6′,2″-Terpyridine, 2,2′-Bipyridine, and 1,10-Phenanthroline. An Experimental and Computational Study England, Jason; Bill, Eckhard; Weyhermüller, Thomas Inorganic Chemistry, Vol. 54, Issue 24 https://doi.org/10.1021/acs.inorgchem.5b02415	journal	December 2015
Metal–Organic Frameworks for Separations Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai Chemical Reviews, Vol. 112, Issue 2, p. 869-932 https://doi.org/10.1021/cr200190s	journal	September 2011
Porous Metal–Organic Frameworks for Heterogeneous Biomimetic Catalysis Zhao, Min; Ou, Sha; Wu, Chuan-De Accounts of Chemical Research, Vol. 47, Issue 4, p. 1199-1207 https://doi.org/10.1021/ar400265x	journal	February 2014
Freeze Drying Significantly Increases Permanent Porosity and Hydrogen Uptake in 4,4-Connected Metalâ€“Organic Frameworks Ma, Liqing; Jin, Athena; Xie, Zhigang Angewandte Chemie International Edition, Vol. 48, Issue 52 https://doi.org/10.1002/anie.200904983	journal	December 2009
Self-Supporting Metal-Organic Layers as Single-Site Solid Catalysts Cao, Lingyun; Lin, Zekai; Peng, Fei Angewandte Chemie International Edition, Vol. 55, Issue 16 https://doi.org/10.1002/anie.201512054	journal	March 2016
Metal–Organic Framework Materials as Chemical Sensors Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K. Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125 https://doi.org/10.1021/cr200324t	journal	September 2011
Selectivity and Mechanism of Hydrogen Atom Transfer by an Isolable Imidoiron(III) Complex Cowley, Ryan E.; Eckert, Nathan A.; Vaddadi, Sridhar Journal of the American Chemical Society, Vol. 133, Issue 25 https://doi.org/10.1021/ja2005303	journal	June 2011
Cerium-Hydride Secondary Building Units in a Porous Metal–Organic Framework for Catalytic Hydroboration and Hydrophosphination Ji, Pengfei; Sawano, Takahiro; Lin, Zekai Journal of the American Chemical Society, Vol. 138, Issue 45 https://doi.org/10.1021/jacs.6b10055	journal	November 2016
Nickel-catalyzed borylation of arenes and indoles via C–H bond cleavage Furukawa, Takayuki; Tobisu, Mamoru; Chatani, Naoto Chemical Communications, Vol. 51, Issue 30 https://doi.org/10.1039/C5CC01378J	journal	January 2015
Cobalt-Catalyzed Benzylic Borylation: Enabling Polyborylation and Functionalization of Remote, Unactivated C(sp ³ )–H Bonds Palmer, W. Neil; Obligacion, Jennifer V.; Pappas, Iraklis Journal of the American Chemical Society, Vol. 138, Issue 3 https://doi.org/10.1021/jacs.5b12249	journal	January 2016
Catalytic Applications of Terpyridines and their Transition Metal Complexes Winter, Andreas; Newkome, George R.; Schubert, Ulrich S. ChemCatChem, Vol. 3, Issue 9 https://doi.org/10.1002/cctc.201100118	journal	July 2011
Experimental Fingerprints for Redox-Active Terpyridine in [Cr(tpy) ₂ ](PF ₆ ) _n ( n = 3–0), and the Remarkable Electronic Structure of [Cr(tpy) ₂ ] ^1– Scarborough, Christopher C.; Lancaster, Kyle M.; DeBeer, Serena Inorganic Chemistry, Vol. 51, Issue 6 https://doi.org/10.1021/ic2027219	journal	March 2012
Catalytic C−H Bond Amination from High-Spin Iron Imido Complexes King, Evan R.; Hennessy, Elisabeth T.; Betley, Theodore A. Journal of the American Chemical Society, Vol. 133, Issue 13 https://doi.org/10.1021/ja110066j	journal	April 2011
Strategies for Hydrogen Storage in Metal-Organic Frameworks Rowsell, Jesse L. C.; Yaghi, Omar M. Angewandte Chemie International Edition, Vol. 44, Issue 30, p. 4670-4679 https://doi.org/10.1002/anie.200462786	journal	July 2005
Advances in the field of π-conjugated 2,2′:6′,2″-terpyridines Wild, Andreas; Winter, Andreas; Schlütter, Florian Chem. Soc. Rev., Vol. 40, Issue 3 https://doi.org/10.1039/C0CS00074D	journal	January 2011
Preparation, unusual spectral properties, and structural characterization of (terpyridine)(tetrahydroborato-H,H')cobalt Corey, E. J.; Cooper, N. John.; Canning, W. Michael. Inorganic Chemistry, Vol. 21, Issue 1 https://doi.org/10.1021/ic00131a036	journal	January 1982

Similar Records

Metal–organic layers stabilize earth-abundant metal–terpyridine diradical complexes for catalytic C–H activation

Journal Article · Mon Oct 30 00:00:00 EDT 2017 · Chemical Science · OSTI ID:1408785

Lin, Zekai; Thacker, Nathan C.; Sawano, Takahiro; +7 more

Bipyridine- and phenanthroline-based metal-organic frameworks for highly efficient and tandem catalytic organic transformations via directed C-H activation

Journal Article · Mon Feb 16 00:00:00 EST 2015 · Journal of the American Chemical Society · OSTI ID:1408785

Manna, Kuntal; Zhang, Teng; Greene, Francis X.; +1 more

Robust and Porous β-Diketiminate-Functionalized Metal–Organic Frameworks for Earth-Abundant-Metal-Catalyzed C–H Amination and Hydrogenation

Journal Article · Fri May 27 00:00:00 EDT 2016 · Journal of the American Chemical Society · OSTI ID:1408785

Thacker, Nathan C.; Lin, Zekai; Zhang, Teng; +3 more

Title: Metal–organic layers stabilize earth-abundant metal–terpyridine diradical complexes for catalytic C–H activation

Citation Formats

References (74)

Similar Records

Related Subjects