Measuring Long-Range 13C–13C Correlations on a Surface under Natural Abundance Using Dynamic Nuclear Polarization-Enhanced Solid-State Nuclear Magnetic Resonance [Measuring Long Range 13C–13C Correlations on Surface under Natural Abundance Using DNP-enhanced Solid-state NMR]

Kobayashi, Takeshi; Slowing, Igor I.; Pruski, Marek

doi:10.1021/acs.jpcc.7b08841

Measuring Long-Range ¹³C–¹³C Correlations on a Surface under Natural Abundance Using Dynamic Nuclear Polarization-Enhanced Solid-State Nuclear Magnetic Resonance [Measuring Long Range ¹³C–¹³C Correlations on Surface under Natural Abundance Using DNP-enhanced Solid-state NMR]

Journal Article · Fri Oct 13 00:00:00 EDT 2017 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.7b08841· OSTI ID:1408771

Kobayashi, Takeshi ^[1]; ^[2]; ^[2]

Ames Lab., Ames, IA (United States)
Ames Lab. and Iowa State Univ., Ames, IA (United States)

Here, we report that spatial (<1 nm) proximity between different molecules in solid bulk materials and, for the first time, different moieties on the surface of a catalyst, can be established without isotope enrichment by means of homonuclear CHHC solid-state nuclear magnetic resonance experiment. This ¹³C–¹³C correlation measurement, which hitherto was not possible for natural-abundance solids, was enabled by the use of dynamic nuclear polarization. Importantly, it allows the study of long-range correlations in a variety of materials with high resolution.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1408771

Report Number(s):: IS-J--9435

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 44 Vol. 121; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited By (3)

Hadamard acquisition of ¹³ C- ¹³ C 2-D correlation NMR spectra Paluch, Piotr; Kupče, Ēriks; Trébosc, Julien Magnetic Resonance in Chemistry https://doi.org/10.1002/mrc.4969	journal	December 2019
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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Dynamic Nuclear Polarization
Solid-state NMR
catalyst surface
homonuclear correlation
natural abundance