Buckling Instabilities in Polymer Brush Surfaces via Postpolymerization Modification

Guo, Wei; Reese, Cassandra M.; Xiong, Li; Logan, Phillip K.; Thompson, Brittany J.; Stafford, Christopher M.; Ievlev, Anton V.; Lokitz, Bradley S.; Ovchinnikova, Olga S.; Patton, Derek L.

doi:10.1021/acs.macromol.7b01888

Title: Buckling Instabilities in Polymer Brush Surfaces via Postpolymerization Modification

Journal Article · Mon Oct 30 00:00:00 EDT 2017 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.7b01888· OSTI ID:1407766

Guo, Wei ^[1]; Reese, Cassandra M. ^[1]; Xiong, Li ^[1]; Logan, Phillip K. ^[1]; Thompson, Brittany J. ^[1]; Stafford, Christopher M. ^[2];

^[3];

^[3]; Ovchinnikova, Olga S. ^[3];

^[1]

Univ. of Southern Mississippi, Hattiesburg, MS (United States)
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

We report a simple route to engineer ultrathin polymer brush surfaces with wrinkled morphologies using postpolymerization modification (PPM), where the length scale of the buckled features can be tuned using PPM reaction time. Here, we show that partial crosslinking of the outer layer of the polymer brush under poor solvent conditions is critical to obtain wrinkled morphologies upon swelling.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1407766

Journal Information:: Macromolecules, Vol. 50, Issue 21; ISSN 0024-9297

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 12 works

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polymer brush
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Title: Buckling Instabilities in Polymer Brush Surfaces via Postpolymerization Modification

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