Correlations between Transition Metal Chemistry, Local Structure and Global Structure in Li2Ru0.5Mn0.5O3 Investigated in a Wide Voltage Window

Lyu, Yingchun; Hu, Enyuan; Xiao, Dongdong; Wang, Yi; Yu, Xiqian; Xu, Guiliang; Ehrlich, Steven N.; Amine, Khalil; Gu, Lin; Yang, Xiao -Qing; Li, Hong

doi:10.1021/acs.chemmater.7b02299

Title: Correlations between Transition Metal Chemistry, Local Structure and Global Structure in Li₂Ru_0.5Mn_0.5O₃ Investigated in a Wide Voltage Window

Journal Article · Fri Oct 20 00:00:00 EDT 2017 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.7b02299· OSTI ID:1405938

^[1]; Hu, Enyuan ^[2]; Xiao, Dongdong ^[3]; Wang, Yi ^[3];

^[3]; Xu, Guiliang ^[4]; Ehrlich, Steven N. ^[2];

^[4];

^[5]; Yang, Xiao -Qing ^[2];

^[3]

Chinese Academy of Sciences (CAS), Beijing (China); Shanghai Univ., Shanghai (China)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Chinese Academy of Sciences (CAS), Beijing (China)
Argonne National Lab. (ANL), Argonne, IL (United States)
Chinese Academy of Sciences (CAS), Beijing (China); Collaborative Innovation Center of Quantum Matter, Beijing (China)

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source; Argonne National Laboratory (ANL), Argonne, IL (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

Grant/Contract Number:: SC0012704; AC02-06CH11357

OSTI ID:: 1405938

Alternate ID(s):: OSTI ID: 1461410; OSTI ID: 1768772

Report Number(s):: BNL-114463-2017-JA; BNL-221100-2021-JAAM; R&D Project: MA453MAEA; VT1201000; TRN: US1702902

Journal Information:: Chemistry of Materials, Vol. 29, Issue 21; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 38 works

Citation information provided by
Web of Science

References (80)

Correlating cation ordering and voltage fade in a lithium–manganese-rich lithium-ion battery cathode oxide: a joint magnetic susceptibility and TEM study Mohanty, Debasish; Sefat, Athena S.; Li, Jianlin Physical Chemistry Chemical Physics, Vol. 15, Issue 44 https://doi.org/10.1039/c3cp53658k	journal	January 2013
Voltage Fade of Layered Oxides: Its Measurement and Impact on Energy Density Bettge, Martin; Li, Yan; Gallagher, Kevin Journal of The Electrochemical Society, Vol. 160, Issue 11 https://doi.org/10.1149/2.034311jes	journal	January 2013
Mitigating Voltage Fade in Cathode Materials by Improving the Atomic Level Uniformity of Elemental Distribution Zheng, Jianming; Gu, Meng; Genc, Arda Nano Letters, Vol. 14, Issue 5 https://doi.org/10.1021/nl500486y	journal	April 2014
Understanding the Rate Capability of High-Energy-Density Li-Rich Layered Li _1.2 Ni _0.15 Co _0.1 Mn _0.55 O ₂ Cathode Materials Yu, Xiqian; Lyu, Yingchun; Gu, Lin Advanced Energy Materials, Vol. 4, Issue 5 https://doi.org/10.1002/aenm.201300950	journal	December 2013
Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries Thackeray, Michael M.; Johnson, Christopher S.; Vaughey, John T. Journal of Materials Chemistry, Vol. 15, Issue 23, p. 2257-2267 https://doi.org/10.1039/b417616m	journal	March 2005
Insignificant impact of designed oxygen release from high capacity Li[(Ni1/2Mn1/2)xCoy(Li1/3Mn2/3)1/3]O2 (x+y=2/3) positive electrodes during the cycling of Li-ion cells Jiang, J.; Dahn, J. R. Electrochimica Acta, Vol. 51, Issue 17 https://doi.org/10.1016/j.electacta.2005.10.006	journal	April 2006
Cation Ordering in Layered O3 Li[Ni _x Li _1/3 _- ₂ _x _/3 Mn _2/ ₃ _- _x _/3 ]O ₂ (0 ≤ x ≤ ¹ / ₂ ) Compounds Meng, Y. S.; Ceder, G.; Grey, C. P. Chemistry of Materials, Vol. 17, Issue 9 https://doi.org/10.1021/cm047779m	journal	May 2005
Structural transformation of a lithium-rich Li1.2Co0.1Mn0.55Ni0.15O2 cathode during high voltage cycling resolved by in situ X-ray diffraction Mohanty, Debasish; Kalnaus, Sergiy; Meisner, Roberta A. Journal of Power Sources, Vol. 229 https://doi.org/10.1016/j.jpowsour.2012.11.144	journal	May 2013
Formation of the Spinel Phase in the Layered Composite Cathode Used in Li-Ion Batteries Gu, Meng; Belharouak, Ilias; Zheng, Jianming ACS Nano, Vol. 7, Issue 1 https://doi.org/10.1021/nn305065u	journal	December 2012
Nanoscale Phase Separation, Cation Ordering, and Surface Chemistry in Pristine Li _1.2 Ni _0.2 Mn _0.6 O ₂ for Li-Ion Batteries Gu, Meng; Genc, Arda; Belharouak, Ilias Chemistry of Materials, Vol. 25, Issue 11 https://doi.org/10.1021/cm4009392	journal	May 2013
The role of composition in the atomic structure, oxygen loss, and capacity of layered Li–Mn–Ni oxide cathodes Jarvis, Karalee A.; Wang, Chih-Chieh; Manthiram, Arumugam J. Mater. Chem. A, Vol. 2, Issue 5 https://doi.org/10.1039/C3TA12440A	journal	January 2014
Solid-State NMR of the Family of Positive Electrode Materials Li ₂ Ru _{1– y} Sn _y O ₃ for Lithium-Ion Batteries Salager, Elodie; Sarou-Kanian, Vincent; Sathiya, M. Chemistry of Materials, Vol. 26, Issue 24 https://doi.org/10.1021/cm503280s	journal	December 2014
Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries McCalla, E.; Abakumov, A. M.; Saubanere, M. Science, Vol. 350, Issue 6267 https://doi.org/10.1126/science.aac8260	journal	December 2015
Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni_0.2Li_0.2Mn_0.6]O₂ Armstrong, A. Robert; Holzapfel, Michael; Novák, Petr Journal of the American Chemical Society, Vol. 128, Issue 26 https://doi.org/10.1021/ja062027+	journal	June 2006
High Performance Li ₂ Ru _{1– y} Mn _y O ₃ (0.2 ≤ y ≤ 0.8) Cathode Materials for Rechargeable Lithium-Ion Batteries: Their Understanding Sathiya, M.; Ramesha, K.; Rousse, G. Chemistry of Materials, Vol. 25, Issue 7 https://doi.org/10.1021/cm400193m	journal	March 2013
The intriguing question of anionic redox in high-energy density cathodes for Li-ion batteries Saubanère, M.; McCalla, E.; Tarascon, J. -M. Energy & Environmental Science, Vol. 9, Issue 3 https://doi.org/10.1039/C5EE03048J	journal	January 2016
Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen Luo, Kun; Roberts, Matthew R.; Hao, Rong Nature Chemistry, Vol. 8, Issue 7 https://doi.org/10.1038/nchem.2471	journal	March 2016
The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials Seo, Dong-Hwa; Lee, Jinhyuk; Urban, Alexander Nature Chemistry, Vol. 8, Issue 7 https://doi.org/10.1038/nchem.2524	journal	May 2016
Origin of stabilization and destabilization in solid-state redox reaction of oxide ions for lithium-ion batteries Yabuuchi, Naoaki; Nakayama, Masanobu; Takeuchi, Mitsue Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13814	journal	December 2016
Anionic redox processes for electrochemical devices Grimaud, A.; Hong, W. T.; Shao-Horn, Y. Nature Materials, Vol. 15, Issue 2 https://doi.org/10.1038/nmat4551	journal	January 2016
Structural integrity—Searching the key factor to suppress the voltage fade of Li-rich layered cathode materials through 3D X-ray imaging and spectroscopy techniques Xu, Yahong; Hu, Enyuan; Yang, Feifei Nano Energy, Vol. 28 https://doi.org/10.1016/j.nanoen.2016.08.039	journal	October 2016
Explore the Effects of Microstructural Defects on Voltage Fade of Li- and Mn-Rich Cathodes Hu, Enyuan; Lyu, Yingchun; Xin, Huolin L. Nano Letters, Vol. 16, Issue 10 https://doi.org/10.1021/acs.nanolett.6b01609	journal	September 2016
Li‐ and Mn‐Rich Cathode Materials: Challenges to Commercialization Zheng, Jianming; Myeong, Seungjun; Cho, Woongrae Advanced Energy Materials, Vol. 7, Issue 6 https://doi.org/10.1002/aenm.201601284	journal	December 2016
Structural and Electrochemical Characterizations on Li ₂ MnO ₃ -LiCoO ₂ -LiCrO ₂ System as Positive Electrode Materials for Rechargeable Lithium Batteries Yabuuchi, Naoaki; Yamamoto, Kazuyo; Yoshii, Kazuhiro Journal of The Electrochemical Society, Vol. 160, Issue 1 https://doi.org/10.1149/2.045301jes	journal	November 2012
Feasibility of Using Li ₂ MoO ₃ in Constructing Li-Rich High Energy Density Cathode Materials Ma, Jun; Zhou, Yong-Ning; Gao, Yurui Chemistry of Materials, Vol. 26, Issue 10 https://doi.org/10.1021/cm501025r	journal	May 2014
Tuning charge–discharge induced unit cell breathing in layer-structured cathode materials for lithium-ion batteries Zhou, Yong-Ning; Ma, Jun; Hu, Enyuan Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6381	journal	November 2014
High-capacity electrode materials for rechargeable lithium batteries: Li ₃ NbO ₄ -based system with cation-disordered rocksalt structure Yabuuchi, Naoaki; Takeuchi, Mitsue; Nakayama, Masanobu Proceedings of the National Academy of Sciences, Vol. 112, Issue 25 https://doi.org/10.1073/pnas.1504901112	journal	June 2015
Synthesis, phase relation and electrical and electrochemical properties of ruthenium-substituted Li2MnO3 as a novel cathode material Mori, Daisuke; Sakaebe, Hikari; Shikano, Masahiro Journal of Power Sources, Vol. 196, Issue 16 https://doi.org/10.1016/j.jpowsour.2010.11.150	journal	August 2011
Probing Reversible Multielectron Transfer and Structure Evolution of Li _1.2 Cr _0.4 Mn _0.4 O ₂ Cathode Material for Li-Ion Batteries in a Voltage Range of 1.0–4.8 V Lyu, Yingchun; Zhao, Nijie; Hu, Enyuan Chemistry of Materials, Vol. 27, Issue 15 https://doi.org/10.1021/acs.chemmater.5b01362	journal	July 2015
Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries Lee, J.; Urban, A.; Li, X. Science, Vol. 343, Issue 6170 https://doi.org/10.1126/science.1246432	journal	January 2014
Electrochemical and structural studies of the carbon-coated Li[CrxLi(1/3−x/3)Ti(2/3−2x/3)]O2 (x=0.3, 0.35, 0.4, 0.45) Mi, Xin; Li, Hong; Huang, Xuejie Journal of Power Sources, Vol. 174, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.06.104	journal	December 2007
Continuous activation of Li2MnO3 component upon cycling in Li1.167Ni0.233Co0.100Mn0.467Mo0.033O2 cathode material for lithium ion batteries Yu, Seung-Ho; Yoon, Taeho; Mun, Junyoung Journal of Materials Chemistry A, Vol. 1, Issue 8 https://doi.org/10.1039/c2ta00309k	journal	January 2013
Influence of Ru substitution on Li-rich 0.55Li2MnO3·0.45LiNi1/3Co1/3Mn1/3O2 cathode for Li-ion batteries Song, Bohang; Lai, Man On; Lu, Li Electrochimica Acta, Vol. 80 https://doi.org/10.1016/j.electacta.2012.06.118	journal	October 2012
Origin of voltage decay in high-capacity layered oxide electrodes Sathiya, M.; Abakumov, A. M.; Foix, D. Nature Materials, Vol. 14, Issue 2 https://doi.org/10.1038/nmat4137	journal	December 2014
Atomic Structure of a Lithium-Rich Layered Oxide Material for Lithium-Ion Batteries: Evidence of a Solid Solution Jarvis, Karalee A.; Deng, Zengqiang; Allard, Lawrence F. Chemistry of Materials, Vol. 23, Issue 16 https://doi.org/10.1021/cm200831c	journal	August 2011
Identifying surface structural changes in layered Li-excess nickel manganese oxides in high voltage lithium ion batteries: A joint experimental and theoretical study Xu, Bo; Fell, Christopher R.; Chi, Miaofang Energy & Environmental Science, Vol. 4, Issue 6 https://doi.org/10.1039/c1ee01131f	journal	January 2011
Direct Atomic-Resolution Observation of Two Phases in the Li _1.2 Mn _0.567 Ni _0.166 Co _0.067 O ₂ Cathode Material for Lithium-Ion Batteries Yu, Haijun; Ishikawa, Ryo; So, Yeong-Gi Angewandte Chemie International Edition, Vol. 52, Issue 23 https://doi.org/10.1002/anie.201301236	journal	April 2013
Evolutions of Li _1.2 Mn _0.61 Ni _0.18 Mg _0.01 O ₂ during the Initial Charge/Discharge Cycle Studied by Advanced Electron Microscopy Boulineau, Adrien; Simonin, Loïc; Colin, Jean-François Chemistry of Materials, Vol. 24, Issue 18 https://doi.org/10.1021/cm301140g	journal	September 2012
Analytical electron microscopy of Li1.2Co0.4Mn0.4O2 for lithium-ion batteries Wen, J. G.; Bareño, J.; Lei, C. H. Solid State Ionics, Vol. 182, Issue 1 https://doi.org/10.1016/j.ssi.2010.11.030	journal	February 2011
High-energy ‘composite’ layered manganese-rich cathode materials via controlling Li2MnO3 phase activation for lithium-ion batteries Yu, Haijun; Kim, Hyunjeong; Wang, Yarong Physical Chemistry Chemical Physics, Vol. 14, Issue 18 https://doi.org/10.1039/c2cp40745k	journal	January 2012
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes Sathiya, M.; Rousse, G.; Ramesha, K. Nature Materials, Vol. 12, Issue 9 https://doi.org/10.1038/nmat3699	journal	July 2013
Reinvestigation of Li ₂ MnO ₃ Structure: Electron Diffraction and High Resolution TEM Boulineau, A.; Croguennec, L.; Delmas, C. Chemistry of Materials, Vol. 21, Issue 18 https://doi.org/10.1021/cm900998n	journal	September 2009
Structure of Li2MnO3 with different degrees of defects Boulineau, A.; Croguennec, L.; Delmas, C. Solid State Ionics, Vol. 180, Issue 40 https://doi.org/10.1016/j.ssi.2009.10.020	journal	January 2010
A profile refinement method for nuclear and magnetic structures Rietveld, H. M. Journal of Applied Crystallography, Vol. 2, Issue 2, p. 65-71 https://doi.org/10.1107/S0021889869006558	journal	June 1969
New-Type Phase Transition of Li ₂ RuO ₃ with Honeycomb Structure Miura, Yoko; Yasui, Yukio; Sato, Masatoshi Journal of the Physical Society of Japan, Vol. 76, Issue 3 https://doi.org/10.1143/JPSJ.76.033705	journal	March 2007
Valence bond liquid phase in the honeycomb lattice material ${Li}_{2} Ru O_{3}$ Kimber, Simon A. J.; Mazin, I. I.; Shen, Juan Physical Review B, Vol. 89, Issue 8 https://doi.org/10.1103/PhysRevB.89.081408	journal	February 2014
Atomic insight into electrochemical inactivity of lithium chromate (LiCrO2): Irreversible migration of chromium into lithium layers in surface regions Lyu, Yingchun; Ben, Liubin; Sun, Yang Journal of Power Sources, Vol. 273 https://doi.org/10.1016/j.jpowsour.2014.09.082	journal	January 2015
Atomic Structure of Li ₂ MnO ₃ after Partial Delithiation and Re-Lithiation Wang, Rui; He, Xiaoqing; He, Lunhua Advanced Energy Materials, Vol. 3, Issue 10 https://doi.org/10.1002/aenm.201200842	journal	June 2013
The role of Li2MO2 structures (M=metal ion) in the electrochemistry of (x)LiMn0.5Ni0.5O2·(1−x)Li2TiO3 electrodes for lithium-ion batteries Johnson, Christopher S.; Kim, Jeom-Soo; Jeremy Kropf, A. Electrochemistry Communications, Vol. 4, Issue 6 https://doi.org/10.1016/S1388-2481(02)00346-6	journal	June 2002
The electrochemical behavior of xLiNiO2·(1 − x)Li2RuO3 and Li2Ru1−yZryO3 electrodes in lithium cells Moore, Gregory J.; Johnson, Christopher S.; Thackeray, Michael M. Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/S0378-7753(03)00184-8	journal	June 2003
Li₂MnO₃-stabilized LiMO₂ (M = Mn, Ni, Co) electrodes for lithium-ion batteries Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S. Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3112-3125 https://doi.org/10.1039/b702425h	journal	January 2007
Detailed Studies of a High-Capacity Electrode Material for Rechargeable Batteries, Li ₂ MnO ₃ −LiCo _1/3 Ni _1/3 Mn _1/3 O ₂ Yabuuchi, Naoaki; Yoshii, Kazuhiro; Myung, Seung-Taek Journal of the American Chemical Society, Vol. 133, Issue 12 https://doi.org/10.1021/ja108588y	journal	March 2011
Relationships between Structural Changes and Electrochemical Kinetics of Li-Excess Li _1.13 Ni _0.3 Mn _0.57 O ₂ during the First Charge Wang, Yuhui; Bie, Xiaofei; Nikolowski, Kristian The Journal of Physical Chemistry C, Vol. 117, Issue 7 https://doi.org/10.1021/jp311518r	journal	February 2013
Examining Hysteresis in Composite x Li ₂ MnO ₃ ·(1– x )LiMO ₂ Cathode Structures Croy, Jason R.; Gallagher, Kevin G.; Balasubramanian, Mahalingam The Journal of Physical Chemistry C, Vol. 117, Issue 13 https://doi.org/10.1021/jp312658q	journal	March 2013
Assignment of pre-edge features in the Ru K-edge X-ray absorption spectra of organometallic ruthenium complexes Getty, Kendra; Delgado-Jaime, Mario Ulises; Kennepohl, Pierre Inorganica Chimica Acta, Vol. 361, Issue 4 https://doi.org/10.1016/j.ica.2007.07.029	journal	March 2008
Corrosion/Fragmentation of Layered Composite Cathode and Related Capacity/Voltage Fading during Cycling Process Zheng, Jianming; Gu, Meng; Xiao, Jie Nano Letters, Vol. 13, Issue 8 https://doi.org/10.1021/nl401849t	journal	July 2013
Density Functional Investigation on Li ₂ MnO ₃ Xiao, Ruijuan; Li, Hong; Chen, Liquan Chemistry of Materials, Vol. 24, Issue 21 https://doi.org/10.1021/cm3027219	journal	October 2012
Electrochemical Activities in Li[sub 2]MnO[sub 3] Yu, Denis Y. W.; Yanagida, Katsunori; Kato, Yoshio Journal of The Electrochemical Society, Vol. 156, Issue 6 https://doi.org/10.1149/1.3110803	journal	January 2009
Structure and lithium deintercalation of Li2−xRuO3 Kobayashi, H. Solid State Ionics, Vol. 82, Issue 1-2 https://doi.org/10.1016/0167-2738(95)00135-S	journal	November 1995
Operando X-ray Absorption Study of the Redox Processes Involved upon Cycling of the Li-Rich Layered Oxide Li _1.20 Mn _0.54 Co _0.13 Ni _0.13 O ₂ in Li Ion Batteries Koga, H.; Croguennec, L.; Ménétrier, M. The Journal of Physical Chemistry C, Vol. 118, Issue 11 https://doi.org/10.1021/jp412197z	journal	March 2014
In Situ X-Ray Absorption Study of a Layered Manganese-Chromium Oxide-Based Cathode Material Balasubramanian, M.; McBreen, J.; Davidson, I. J. Journal of The Electrochemical Society, Vol. 149, Issue 2 https://doi.org/10.1149/1.1431962	journal	January 2002
First-charge instabilities of layered-layered lithium-ion-battery materials Croy, Jason R.; Iddir, Hakim; Gallagher, Kevin Physical Chemistry Chemical Physics, Vol. 17, Issue 37 https://doi.org/10.1039/C5CP02943K	journal	January 2015
In situ investigations of a Li-rich Mn–Ni layered oxide for Li-ion batteries Simonin, Loïc; Colin, Jean-François; Ranieri, Vincent Journal of Materials Chemistry, Vol. 22, Issue 22 https://doi.org/10.1039/c2jm31205k	journal	January 2012
In situ X-ray absorption spectroscopic study of Li-rich layered cathode material Li[Ni0.17Li0.2Co0.07Mn0.56]O2 Ito, Atsushi; Sato, Yuichi; Sanada, Takashi Journal of Power Sources, Vol. 196, Issue 16 https://doi.org/10.1016/j.jpowsour.2010.09.105	journal	August 2011
Electronic structure and properties of Li-insertion materials: ${Li}_{2} Ru O_{3}$ and $Ru O_{2}$ Johannes, M. D.; Stux, A. M.; Swider-Lyons, K. E. Physical Review B, Vol. 77, Issue 7 https://doi.org/10.1103/PhysRevB.77.075124	journal	February 2008
Structural and Electrochemical Evidence of Layered to Spinel Phase Transformation of Li and Mn Rich Layered Cathode Materials of the Formulae xLi[Li _1/3 Mn _2/3 ]O ₂ .(1-x)LiMn _1/3 Ni _1/3 Co _1/3 O ₂ (x = 0.2, 0.4, 0.6) upon Cycling Nayak, Prasant Kumar; Grinblat, Judith; Levi, Mikhael Journal of The Electrochemical Society, Vol. 161, Issue 10 https://doi.org/10.1149/2.0101410jes	journal	January 2014
Direct observation of the partial formation of a framework structure for Li-rich layered cathode material Li[Ni0.17Li0.2Co0.07Mn0.56]O2 upon the first charge and discharge Ito, Atsushi; Shoda, Kaoru; Sato, Yuichi Journal of Power Sources, Vol. 196, Issue 10 https://doi.org/10.1016/j.jpowsour.2010.12.079	journal	May 2011
Structural and Chemical Evolution of Li- and Mn-Rich Layered Cathode Material Zheng, Jianming; Xu, Pinghong; Gu, Meng Chemistry of Materials, Vol. 27, Issue 4 https://doi.org/10.1021/cm5045978	journal	February 2015
Correlation Between Oxygen Vacancy, Microstrain, and Cation Distribution in Lithium-Excess Layered Oxides During the First Electrochemical Cycle Fell, Christopher R.; Qian, Danna; Carroll, Kyler J. Chemistry of Materials, Vol. 25, Issue 9 https://doi.org/10.1021/cm4000119	journal	April 2013
Structure and electrochemistry of Li1±yNiO2 and a new Li2NiO2 phase with the Ni (OH)2 structure Dahn, J. Solid State Ionics, Vol. 44, Issue 1-2 https://doi.org/10.1016/0167-2738(90)90049-W	journal	December 1990
Electrochemically Induced Cation Disorder and Phase Transformations in Lithium Intercalation Oxides Chiang, Yet-Ming; Wang, Haifeng; Jang, Young-Il Chemistry of Materials, Vol. 13, Issue 1 https://doi.org/10.1021/cm000569z	journal	January 2001
Antiphase inversion domains in lithium cobaltite thin films deposited on single-crystal sapphire substrates Zheng, S. J.; Fisher, C. A. J.; Hitosugi, T. Acta Materialia, Vol. 61, Issue 20 https://doi.org/10.1016/j.actamat.2013.09.004	journal	December 2013
Topological defect dynamics in operando battery nanoparticles Ulvestad, A.; Singer, A.; Clark, J. N. Science, Vol. 348, Issue 6241 https://doi.org/10.1126/science.aaa1313	journal	June 2015
XRD and XAFS study on structure and cation valence state of layered ruthenium oxide electrodes, Li2RuO3 and Li2Mn0.4Ru0.6O3, upon electrochemical cycling Mori, Daisuke; Kobayashi, Hironori; Okumura, Toyoki Solid State Ionics, Vol. 285 https://doi.org/10.1016/j.ssi.2015.09.025	journal	February 2016
Lattice-tuned magnetism of ${Ru}^{4 +} (4 d^{4})$ ions in single crystals of the layered honeycomb ruthenates ${Li}_{2} {RuO}_{3}$ and ${Na}_{2} {RuO}_{3}$ Wang, J. C.; Terzic, J.; Qi, T. F. Physical Review B, Vol. 90, Issue 16 https://doi.org/10.1103/PhysRevB.90.161110	journal	October 2014
Double-hole-induced oxygen dimerization in transition metal oxides Chen, Shiyou; Wang, Lin-Wang Physical Review B, Vol. 89, Issue 1 https://doi.org/10.1103/PhysRevB.89.014109	journal	January 2014
Influence of Ti ⁴⁺ on the Electrochemical Performance of Li-Rich Layered Oxides - High Power and Long Cycle Life of Li ₂ Ru _{1– x} Ti _x O ₃ Cathodes Kalathil, Abdul Kareem; Arunkumar, Paulraj; Kim, Da Hye ACS Applied Materials & Interfaces, Vol. 7, Issue 13 https://doi.org/10.1021/am507951x	journal	March 2015
Lithium Rich Composition of Li ₂ RuO ₃ and Li ₂ Ru _1-x Ir _x O ₃ Layered Materials as Li-Ion Battery Cathode Sarkar, S.; Mahale, P.; Mitra, S. Journal of The Electrochemical Society, Vol. 161, Issue 6 https://doi.org/10.1149/2.030406jes	journal	January 2014
Structural Characterization of Layered Li _x Ni _0.5 Mn _0.5 O ₂ (0 < x ≤ 2) Oxide Electrodes for Li Batteries Johnson, Christopher S.; Kim, Jeom-Soo; Kropf, A. Jeremy Chemistry of Materials, Vol. 15, Issue 12 https://doi.org/10.1021/cm0204728	journal	June 2003
Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes Liu, H.; Strobridge, F. C.; Borkiewicz, O. J. Science, Vol. 344, Issue 6191 https://doi.org/10.1126/science.1252817	journal	June 2014

Cited By (3)

Eliminating Transition Metal Migration and Anionic Redox to Understand Voltage Hysteresis of Lithium‐Rich Layered Oxides Han, Miao; Jiao, Junyu; Liu, Zepeng Advanced Energy Materials, Vol. 10, Issue 8 https://doi.org/10.1002/aenm.201903634	journal	January 2020
Improving the Electrochemical Performance of Li ₂ RuO ₃ through Chemical Substitution: A Case Study of ( x )LiCoO ₂ ‐(1‐ x )Li ₂ RuO ₃ Solid Solution ( x ≤0.4) Neelakantaiah, Ramesha R.; Dasari, Bosu Babu; Ette, Pedda Masthanaiah ChemElectroChem, Vol. 7, Issue 1 https://doi.org/10.1002/celc.201902059	journal	December 2019
Cracks Formation in Lithium-Rich Cathode Materials for Lithium-Ion Batteries during the Electrochemical Process Cheng, Tao; Ma, Zhongtao; Gu, Run Energies, Vol. 11, Issue 10 https://doi.org/10.3390/en11102712	journal	October 2018

Similar Records

Three-layer Aurivillius phases containing magnetic transition metal cations : Bi{sub 2-x}Sr{sub 2+x}(Nb,Ta){sub 2+x}M{sub 1-x}O{sub 12}, M = Ru{sub 4+}, Ir{sub 4+}, Mn{sub 4+}, x {approx} 0.5.

Journal Article · Mon Jan 01 00:00:00 EST 2007 · J. Solid State Chem. · OSTI ID:1405938

Sharma, N; Wrighter, G E; Chen, P Y; +3 more

Synthesis and electrochemical properties of layer-structured 0.5Li(Ni{sub 0.5}Mn{sub 0.5})O{sub 2}{emdash}0.5Li(Li{sub 1/3}Mn{sub2/3})O{sub 2} solid mixture.

Journal Article · Mon Nov 24 00:00:00 EST 2003 · J. Power Sources · OSTI ID:1405938

Kang, S -H; Amine, K

Structure, Chemistry, and Charge Transfer Resistance of the Interface between Li₇La₃Zr₂O₁₂ Electrolyte and LiCoO₂ Cathode

Journal Article · Wed Jul 25 00:00:00 EDT 2018 · Chemistry of Materials · OSTI ID:1405938

Vardar, Gulin; Bowman, William J.; Lu, Qiyang; +13 more

Related Subjects

25 ENERGY STORAGE
36 MATERIALS SCIENCE
National Synchrotron Light Source
lithium-ion batteries
cathode
lithium rich layered oxides

Title: Correlations between Transition Metal Chemistry, Local Structure and Global Structure in Li2Ru0.5Mn0.5O3 Investigated in a Wide Voltage Window

Citation Formats

References (80)

Cited By (3)

Similar Records

Related Subjects

Title: Correlations between Transition Metal Chemistry, Local Structure and Global Structure in Li₂Ru_0.5Mn_0.5O₃ Investigated in a Wide Voltage Window