Cold sintering process of Li 1.5 Al 0.5 Ge 1.5 (PO 4 ) 3 solid electrolyte

Berbano, Seth S.; Guo, Jing; Guo, Hanzheng; Lanagan, Michael T.; Randall, Clive A.

doi:10.1111/jace.14727

Title: Cold sintering process of Li _1.5 Al _0.5 Ge _1.5 (PO ₄ ) ₃ solid electrolyte

Journal Article · Sat Mar 04 00:00:00 EST 2017 · Journal of the American Ceramic Society

DOI:https://doi.org/10.1111/jace.14727· OSTI ID:1401766

^[1];

^[1]; Guo, Hanzheng ^[1]; Lanagan, Michael T. ^[2]; Randall, Clive A. ^[1]

Center for Dielectrics &, Piezoelectrics Materials Research Institute The Pennsylvania State University University Park Pennsylvania, Department of Materials Science &, Engineering The Pennsylvania State University University Park Pennsylvania
Center for Dielectrics &, Piezoelectrics Materials Research Institute The Pennsylvania State University University Park Pennsylvania, Department of Materials Science &, Engineering The Pennsylvania State University University Park Pennsylvania, Department of Engineering Science &, Mechanics Millennium Science Complex The Pennsylvania State University University Park Pennsylvania

Abstract The recently developed technique of cold sintering process (CSP) enables densification of ceramics at low temperatures, i.e., <300°C. CSP employs a transient aqueous solvent to enable liquid phase‐assisted densification through mediating the dissolution‐precipitation process under a uniaxial applied pressure. Using CSP in this study, 80% dense Li _1.5 Al _0.5 Ge _1.5 (PO ₄ ) ₃ (LAGP) electrolytes were obtained at 120°C in 20 minutes. After a 5 minute belt furnace treatment at 650°C, 50°C above the crystallization onset, Li‐ion conductivity was 5.4 × 10 ⁻⁵ S/cm at 25°C. Another route to high ionic conductivities ~10 ⁻⁴ S/cm at 25°C is through a composite LAGP ‐ (PVDF‐HFP) co‐sintered system that was soaked in a liquid electrolyte. After soaking 95, 90, 80, 70, and 60 vol% LAGP in 1 M LiPF ₆ EC‐DMC (50:50 vol%) at 25°C, Li‐ion conductivities were 1.0 × 10 ⁻⁴ S/cm at 25°C with 5 to 10 wt% liquid electrolyte. This paper focuses on the microstructural development and impedance contributions within solid electrolytes processed by (i) Crystallization of bulk glasses, (ii) CSP of ceramics, and (iii) CSP of ceramic‐polymer composites. CSP may offer a new route to enable multilayer battery technology by avoiding the detrimental effects of high temperature heat treatments.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 1401766

Journal Information:: Journal of the American Ceramic Society, Journal Name: Journal of the American Ceramic Society Vol. 100 Journal Issue: 5; ISSN 0002-7820

Publisher:: Wiley-BlackwellCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 78 works

Citation information provided by
Web of Science

References (48)

A Super High Lithium Ion Conducting Solid Electrolyte of Grain Boundary Modified Li _1.4 Ti _1.6 Al _0.4 (PO ₄ ) ₃ Takahashi, K.; Ohmura, J.; Im, D. Journal of The Electrochemical Society, Vol. 159, Issue 4 https://doi.org/10.1149/2.018204jes	journal	January 2012
Atomic-scale origin of the large grain-boundary resistance in perovskite Li-ion-conducting solid electrolytes Ma, Cheng; Chen, Kai; Liang, Chengdu Energy & Environmental Science, Vol. 7, Issue 5 https://doi.org/10.1039/c4ee00382a	journal	January 2014
A high conductivity oxide–sulfide composite lithium superionic conductor Rangasamy, Ezhiylmurugan; Sahu, Gayatri; Keum, Jong Kahk J. Mater. Chem. A, Vol. 2, Issue 12 https://doi.org/10.1039/C3TA15223E	journal	January 2014
Nanoionics: ion transport and electrochemical storage in confined systems Maier, J. Nature Materials, Vol. 4, Issue 11, p. 805-815 https://doi.org/10.1038/nmat1513	journal	November 2005
XLII. On certain curious motions observable at the surfaces of wine and other alcoholic liquors Thomson, James The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, Vol. 10, Issue 67 https://doi.org/10.1080/14786445508641982	journal	November 1855
The Stone Age Revisited: Building a Monolithic Inorganic Lithium-Ion Battery Delaizir, Gaelle; Viallet, Virginie; Aboulaich, Abdelmaula Advanced Functional Materials, Vol. 22, Issue 10 https://doi.org/10.1002/adfm.201102479	journal	February 2012
Performance of Bellcore's plastic rechargeable Li-ion batteries Tarascon, J.-M.; Gozdz, A. S.; Schmutz, C. Solid State Ionics, Vol. 86-88, Issue Part 1, p. 49-54 https://doi.org/10.1016/0167-2738(96)00330-X	journal	July 1996
Cold Sintering Process: A Novel Technique for Low-Temperature Ceramic Processing of Ferroelectrics Guo, Hanzheng; Baker, Amanda; Guo, Jing Journal of the American Ceramic Society, Vol. 99, Issue 11 https://doi.org/10.1111/jace.14554	journal	October 2016
Enhancement of the Grain Boundary Conductivity in Ceramic Li _0.34 La _0.55 TiO ₃ Electrolytes in a Moisture-Free Processing Environment Aguesse, Frederic; López del Amo, Juan Miguel; Roddatis, Vladimir Advanced Materials Interfaces, Vol. 1, Issue 7 https://doi.org/10.1002/admi.201300143	journal	July 2014
Lithium conducting glass ceramic with Nasicon structure Leo, C. J.; Chowdari, B. V. R.; Rao, G. V. Subba Materials Research Bulletin, Vol. 37, Issue 8 https://doi.org/10.1016/S0025-5408(02)00793-6	journal	July 2002
Protocol for Ultralow-Temperature Ceramic Sintering: An Integration of Nanotechnology and the Cold Sintering Process Guo, Hanzheng; Baker, Amanda; Guo, Jing ACS Nano, Vol. 10, Issue 11 https://doi.org/10.1021/acsnano.6b03800	journal	July 2016
Cold Sintering: A Paradigm Shift for Processing and Integration of Ceramics Guo, Jing; Guo, Hanzheng; Baker, Amanda L. Angewandte Chemie, Vol. 128, Issue 38 https://doi.org/10.1002/ange.201605443	journal	August 2016
Effect of Surface Microstructure on Electrochemical Performance of Garnet Solid Electrolytes Cheng, Lei; Chen, Wei; Kunz, Martin ACS Applied Materials & Interfaces, Vol. 7, Issue 3 https://doi.org/10.1021/am508111r	journal	January 2015
Analyzing results of impedance spectroscopy using novel evolutionary programming techniques Tesler, A. B.; Lewin, D. R.; Baltianski, S. Journal of Electroceramics, Vol. 24, Issue 4 https://doi.org/10.1007/s10832-009-9565-z	journal	February 2009
Harnessing evolutionary programming for impedance spectroscopy analysis: A case study of mixed ionic-electronic conductors Hershkovitz, Shany; Baltianski, Sioma; Tsur, Yoed Solid State Ionics, Vol. 188, Issue 1 https://doi.org/10.1016/j.ssi.2010.10.004	journal	April 2011
Lithium Thiophosphate Glasses and Glass-Ceramics as Solid Electrolytes: Processing, Microstructure, and Properties Berbano, Seth S.; Mirsaneh, Mehdi; Lanagan, Michael T. International Journal of Applied Glass Science, Vol. 4, Issue 4 https://doi.org/10.1111/ijag.12037	journal	August 2013
On creep enhanced by a liquid phase Pharr, G. M.; Ashby, M. F. Acta Metallurgica, Vol. 31, Issue 1 https://doi.org/10.1016/0001-6160(83)90072-X	journal	January 1983
Materials that can replace liquid electrolytes in Li batteries: Superionic conductivities in Li1.7Al0.3Ti1.7Si0.4P2.6O12. Processing combustion synthesized nanopowders to free standing thin films Yi, Eongyu; Wang, Weimin; Mohanty, Som Journal of Power Sources, Vol. 269 https://doi.org/10.1016/j.jpowsour.2014.07.029	journal	December 2014
The Brick Layer Model Revisited: Introducing the Nano-Grain Composite Model Kidner, Neil J.; Perry, Nicola H.; Mason, Thomas O. Journal of the American Ceramic Society, Vol. 91, Issue 6 https://doi.org/10.1111/j.1551-2916.2008.02445.x	journal	June 2008
Hydrothermal-Assisted Cold Sintering Process: A New Guidance for Low-Temperature Ceramic Sintering Guo, Hanzheng; Guo, Jing; Baker, Amanda ACS Applied Materials & Interfaces, Vol. 8, Issue 32 https://doi.org/10.1021/acsami.6b07481	journal	August 2016
Dynamics and stability of thin liquid films Craster, R. V.; Matar, O. K. Reviews of Modern Physics, Vol. 81, Issue 3 https://doi.org/10.1103/RevModPhys.81.1131	journal	August 2009
Chalcogenide-based lithium solid electrolytes processed by the Powder-in-a-tube method Berbano, Seth S.; Fofana, Malick Y.; Randall, Clive A. Materials Letters, Vol. 141 https://doi.org/10.1016/j.matlet.2014.11.047	journal	February 2015
Sulfide Solid Electrolyte with Favorable Mechanical Property for All-Solid-State Lithium Battery Sakuda, Atsushi; Hayashi, Akitoshi; Tatsumisago, Masahiro Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep02261	journal	July 2013
Correlation between micro-structural properties and ionic conductivity of Li1.5Al0.5Ge1.5(PO4)3 ceramics Mariappan, Chinnasamy R.; Yada, Chihiro; Rosciano, Fabio Journal of Power Sources, Vol. 196, Issue 15 https://doi.org/10.1016/j.jpowsour.2011.03.065	journal	August 2011
Fast Li+ ion conducting glass-ceramics in the system Li2O–Al2O3–GeO2–P2O5 Fu, J. Solid State Ionics, Vol. 104, Issue 3-4 https://doi.org/10.1016/S0167-2738(97)00434-7	journal	December 1997
High-power all-solid-state batteries using sulfide superionic conductors Kato, Yuki; Hori, Satoshi; Saito, Toshiya Nature Energy, Vol. 1, Issue 4 https://doi.org/10.1038/nenergy.2016.30	journal	March 2016
Dielectric Properties of Lithium Molybdate Ceramic Fabricated at Room Temperature Kähäri, Hanna; Teirikangas, Merja; Juuti, Jari Journal of the American Ceramic Society, Vol. 97, Issue 11 https://doi.org/10.1111/jace.13277	journal	October 2014
Lithium-Ion Cells Assembled with Flexible Hybrid Membrane Containing Li ⁺ -Conducting Lithium Aluminum Germanium Phosphate Kim, Seul-Ki; Jung, Yun-Chae; Kim, Duck-Hyun Journal of The Electrochemical Society, Vol. 163, Issue 6 https://doi.org/10.1149/2.0831606jes	journal	January 2016
Chemical Sorption of Carbon Dioxide (CO ₂ ) on Lithium Oxide (Li ₂ O) Mosqueda, Hugo A.; Vazquez, Carmen; Bosch, Pedro Chemistry of Materials, Vol. 18, Issue 9 https://doi.org/10.1021/cm060122b	journal	May 2006
Increase in grain boundary ionic conductivity of Li1.5Al0.5Ge1.5(PO4)3 by adding excess lithium Chung, Habin; Kang, Byoungwoo Solid State Ionics, Vol. 263 https://doi.org/10.1016/j.ssi.2014.05.016	journal	October 2014
Ultra-thin Solid-State Li-Ion Electrolyte Membrane Facilitated by a Self-Healing Polymer Matrix Whiteley, Justin M.; Taynton, Philip; Zhang, Wei Advanced Materials, Vol. 27, Issue 43 https://doi.org/10.1002/adma.201502636	journal	September 2015
Interfacial turbulence: Hydrodynamic instability and the marangoni effect Sternling, C. V.; Scriven, L. E. AIChE Journal, Vol. 5, Issue 4 https://doi.org/10.1002/aic.690050421	journal	December 1959
Further observations on creep enhanced by a liquid phase in porous potassium chloride Sheikh, Gh. R.; Pharr, G. M. Acta Metallurgica, Vol. 33, Issue 2 https://doi.org/10.1016/0001-6160(85)90140-3	journal	February 1985
Electrical Properties and Sinterability for Lithium Germanium Phosphate Li _{1+ x} M _x Ge _{2− x} (PO ₄ ) ₃ , M = Al, Cr, Ga, Fe, Sc, and In Systems Aono, Hiromichi; Sugimoto, Eisuke; Sadaoka, Yoshihiko Bulletin of the Chemical Society of Japan, Vol. 65, Issue 8 https://doi.org/10.1246/bcsj.65.2200	journal	August 1992
Pressure solution and the force of crystallization: a phenomenological theory Weyl, Peter K. Journal of Geophysical Research, Vol. 64, Issue 11 https://doi.org/10.1029/JZ064i011p02001	journal	November 1959
Origins of concentration gradients for diffusiophoresis Velegol, Darrell; Garg, Astha; Guha, Rajarshi Soft Matter, Vol. 12, Issue 21 https://doi.org/10.1039/C6SM00052E	journal	January 2016
Synthesis and lithium-ion conductivity for perovskite-type Li3/8Sr7/16Ta3/4Zr1/4O3 solid electrolyte by powder-bed sintering Inada, Ryoji; Kimura, Keisuke; Kusakabe, Koji Solid State Ionics, Vol. 261 https://doi.org/10.1016/j.ssi.2014.04.005	journal	August 2014
Cold Sintering Process of Composites: Bridging the Processing Temperature Gap of Ceramic and Polymer Materials Guo, Jing; Berbano, Seth S.; Guo, Hanzheng Advanced Functional Materials, Vol. 26, Issue 39 https://doi.org/10.1002/adfm.201602489	journal	August 2016
New, Highly Ion-Conductive Crystals Precipitated from Li₂S-P₂S₅ Glasses Mizuno, F.; Hayashi, A.; Tadanaga, K. Advanced Materials, Vol. 17, Issue 7, p. 918-921 https://doi.org/10.1002/adma.200401286	journal	April 2005
Coupling between pressure solution creep and diffusive mass transport in porous rocks: COUPLED PRESSURE SOLUTION AND MASS TRANSFER Gundersen, Elisabeth; Renard, François; Dysthe, Dag Kristian Journal of Geophysical Research: Solid Earth, Vol. 107, Issue B11 https://doi.org/10.1029/2001JB000287	journal	November 2002
Colloid Transport by Interfacial Forces Anderson, J. L. Annual Review of Fluid Mechanics, Vol. 21, Issue 1 https://doi.org/10.1146/annurev.fl.21.010189.000425	journal	January 1989
Utilizing the Cold Sintering Process for Flexible-Printable Electroceramic Device Fabrication Baker, Amanda; Guo, Hanzheng; Guo, Jing Journal of the American Ceramic Society, Vol. 99, Issue 10 https://doi.org/10.1111/jace.14467	journal	August 2016
Grain Boundaries in a Lithium Aluminum Titanium Phosphate-Type Fast Lithium Ion Conducting Glass Ceramic: Microstructure and Nonlinear Ion Transport Properties Gellert, Michael; Gries, Katharina I.; Yada, Chihiro The Journal of Physical Chemistry C, Vol. 116, Issue 43 https://doi.org/10.1021/jp305309r	journal	October 2012
Elaboration of controlled size Li1.5Al0.5Ge1.5(PO4)3 crystallites from glass-ceramics Kubanska, A.; Castro, L.; Tortet, L. Solid State Ionics, Vol. 266 https://doi.org/10.1016/j.ssi.2014.07.013	journal	November 2014
Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction Bachman, John Christopher; Muy, Sokseiha; Grimaud, Alexis Chemical Reviews, Vol. 116, Issue 1 https://doi.org/10.1021/acs.chemrev.5b00563	journal	December 2015
Effect of nanoscopic confinement on improvement in ion conduction and stability properties of an intercalated polymer nanocomposite electrolyte for energy storage applications Mohapatra, Saumya R.; Thakur, Awalendra K.; Choudhary, R. N. P. Journal of Power Sources, Vol. 191, Issue 2 https://doi.org/10.1016/j.jpowsour.2009.01.100	journal	June 2009
Controlled crystallization and ionic conductivity of a nanostructured LiAlGePO4 glass–ceramic Cruz, Ana Milena; Ferreira, Eduardo Bellini; Rodrigues, Ana Candida M. Journal of Non-Crystalline Solids, Vol. 355, Issue 45-47 https://doi.org/10.1016/j.jnoncrysol.2009.07.012	journal	November 2009
Lithium Ion-Conducting Glass?Ceramics of Li _1.5 Al _0.5 Ge _1.5 (PO ₄ ) ₃ ?xLi ₂ O (x=0.0?0.20) with Good Electrical and Electrochemical Properties Xu, Xiaoxiong; Wen, Zhaoyin; Wu, Xiangwei Journal of the American Ceramic Society, Vol. 90, Issue 9 https://doi.org/10.1111/j.1551-2916.2007.01827.x	journal	September 2007

Similar Records

Ceramic–Salt Composite Electrolytes from Cold Sintering

Journal Article · Mon Apr 01 00:00:00 EDT 2019 · Advanced Functional Materials · OSTI ID:1401766

Lee, Wonho; Lyon, Christopher K.; Seo, Joo‐Hwan; +6 more

High-temperature X-ray analysis of phase evolution in lithium ion conductor Li{sub 1.5}Al{sub 0.5}Ge{sub 1.5}(PO{sub 4}){sub 3}

Journal Article · Sat Jun 15 00:00:00 EDT 2013 · Materials Characterization · OSTI ID:1401766

He, Kun; Wang, Yanhang; Zu, Chengkui; +5 more

Molecular Engineering of Biorefining Lignin Waste for Solid-State Electrolyte

Journal Article · Wed Jun 29 00:00:00 EDT 2022 · ACS Sustainable Chemistry & Engineering · OSTI ID:1401766

Li, Qiang; Cao, Daxian; Naik, Mandar T.; +9 more

Title: Cold sintering process of Li 1.5 Al 0.5 Ge 1.5 (PO 4 ) 3 solid electrolyte

Citation Formats

References (48)

Similar Records

Related Subjects

Title: Cold sintering process of Li _1.5 Al _0.5 Ge _1.5 (PO ₄ ) ₃ solid electrolyte