Electrochemically Controlled Ion‐exchange Property of Carbon Nanotubes/Polypyrrole Nanocomposite in Various Electrolyte Solutions

Choi, Daiwon; Zhu, Chengzhou; Fu, Shaofang; Du, Dan; Engelhard, Mark H.; Lin, Yuehe

doi:10.1002/elan.201600466

Electrochemically Controlled Ion‐exchange Property of Carbon Nanotubes/Polypyrrole Nanocomposite in Various Electrolyte Solutions

Journal Article · Thu Sep 15 00:00:00 EDT 2016 · Electroanalysis

DOI:https://doi.org/10.1002/elan.201600466· OSTI ID:1401711

Choi, Daiwon ^[1]; Zhu, Chengzhou ^[2]; Fu, Shaofang ^[2]; Du, Dan ^[2]; Engelhard, Mark H. ^[1]; Lin, Yuehe ^[3]

Pacific Northwest National Laboratory 902 Battelle Boulevard P.O. Box 999 Richland WA 99352 USA
School of Mechanical and Materials Engineering Washington State University, Pullman Washington 99164-2920 United States
Pacific Northwest National Laboratory 902 Battelle Boulevard P.O. Box 999 Richland WA 99352 USA, School of Mechanical and Materials Engineering Washington State University, Pullman Washington 99164-2920 United States

Abstract

The electrochemically controlled ion‐exchange properties of multi‐wall carbon nanotube (MWNT)/electronically conductive polypyrrole (PPy) polymer composite in the various electrolyte solutions have been investigated. The ion‐exchange behavior, rate and capacity of the electrochemically deposited polypyrrole with and without carbon nanotube (CNT) were compared and characterized using cyclic voltammetry (CV), chronoamperometry (CA), electrochemical quartz crystal microbalance (EQCM), X‐ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). It has been found that the presence of carbon nanotube backbone resulted in improvement in ion‐exchange rate, stability of polypyrrole, and higher anion loading capacity per PPy due to higher surface area, electronic conductivity, porous structure of thin film, and thinner film thickness providing shorter diffusion path. Chronoamperometric studies show that electrically switched anion exchange could be completed more than 10 times faster than pure PPy thin film. The anion selectivity of CNT/PPy film is demonstrated using X‐ray photoelectron spectroscopy (XPS).

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

OSTI ID:: 1401711

Alternate ID(s):: OSTI ID: 1372965

Journal Information:: Electroanalysis, Journal Name: Electroanalysis Journal Issue: 3 Vol. 29; ISSN 1040-0397

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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