Spinel LiNi0.5Mn1.5O4 Cathode for High-Energy Aqueous Lithium-Ion Batteries

Wang, Fei; Suo, Liumin; Liang, Yujia; Yang, Chongyin; Han, Fudong; Gao, Tao; Sun, Wei; Wang, Chunsheng

doi:10.1002/aenm.201600922

Spinel LiNi_0.5Mn_1.5O₄ Cathode for High-Energy Aqueous Lithium-Ion Batteries

Journal Article · Wed Dec 14 00:00:00 EST 2016 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201600922· OSTI ID:1533058

Wang, Fei ^[1]; Suo, Liumin ^[2]; Liang, Yujia ^[2]; Yang, Chongyin ^[2]; Han, Fudong ^[2]; Gao, Tao ^[2]; Sun, Wei ^[2]; Wang, Chunsheng ^[2]

Univ. of Maryland, College Park, MD (United States). Dept. of Chemical and Biomolecular Engineering; DOE/OSTI
Univ. of Maryland, College Park, MD (United States). Dept. of Chemical and Biomolecular Engineering

A 2.9 V intrinsic safe aqueous LiNi_0.5Mn_1.5O₄/Mo₆S₈ full cell delivers 80 W h kg^-1 energy density with capacity decay of 0.075% per cycle (5 C). After the electrolyte pH value adjustment, almost full capacity of LiNi_0.5Mn_1.5O₄ (125 mA h kg^-1) is achieved, and 126 W h kg^-1 energy density is provided for LiNi_0.5Mn_1.5O₄/Mo₆S₈ cell, representing one of the highest voltage and energy density among all the aqueous batteries.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Maryland, College Park, MD (United States)

Sponsoring Organization:: USDOE; USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: AR0000389

OSTI ID:: 1533058

Alternate ID(s):: OSTI ID: 1401255

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 8 Vol. 7; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

25 ENERGY STORAGE
LiNi0.5Mn1.5O4
aqueous lithium-ion batteries
high energy density
high voltage
water-in-salt electrolyte