An In Situ One‐Pot Synthetic Approach towards Multivariate Zirconium MOFs

Sun, Yujia; Sun, Lixian; Feng, Dawei; Zhou, Hong‐Cai

doi:10.1002/ange.201602274

Title: An In Situ One‐Pot Synthetic Approach towards Multivariate Zirconium MOFs

Journal Article · Thu Apr 21 00:00:00 EDT 2016 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201602274· OSTI ID:1401205

Sun, Yujia ^[1]; Sun, Lixian ^[2]; Feng, Dawei ^[1];

^[1]

Department of Chemistry Texas A&,M University College Station TX 77843 USA
Guangxi Key Laboratory of Information Materials, Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials School of Material Science &, Engineering Guilin University of Electronic Technology Guilin Guangxi 541004 China

Abstract Chemically highly stable MOFs incorporating multiple functionalities are of great interest for applications under harsh environments. Herein, we presented a facile one‐pot synthetic strategy to incorporate multiple functionalities into stable Zr‐MOFs from mixed ligands of different geometry and connectivity. Via our strategy, tetratopic tetrakis(4‐carboxyphenyl)porphyrin (TCPP) ligands were successfully integrated into UiO‐66 while maintaining the crystal structure, morphology, and ultrahigh chemical stability of UiO‐66. The amount of incorporated TCPP is controllable. Through various combinations of BDC derivatives and TCPP, 49 MOFs with multiple functionalities were obtained. Among them, MOFs modified with FeTCPPCl were demonstrated to be catalytically active for the oxidation of ABTS. We anticipate our strategy to provide a facile route to introduce multiple functionalities into stable Zr‐MOFs for a wide variety of potential applications.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0001015

OSTI ID:: 1401205

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 128 Journal Issue: 22; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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