Optimization of CdTe thin‐film solar cell efficiency using a sputtered, oxygenated CdS window layer

Kephart, Jason M.; Geisthardt, Russell M.; Sampath, W. S.

doi:10.1002/pip.2578

Optimization of CdTe thin‐film solar cell efficiency using a sputtered, oxygenated CdS window layer

Journal Article · Wed Jan 21 00:00:00 EST 2015 · Progress in Photovoltaics

DOI:https://doi.org/10.1002/pip.2578· OSTI ID:1401119

Kephart, Jason M. ^[1]; Geisthardt, Russell M. ^[2]; Sampath, W. S. ^[1]

Colorado State University Mechanical Engineering Fort Collins CO USA
Colorado State University Physics Fort Collins CO USA

Abstract

A major source of loss in cadmium sulfide/cadmium telluride (CdS/CdTe) solar cells results from light absorbed in the CdS window layer, which is not converted to electrical current. This film can be made more transparent by oxygen incorporation during sputter deposition at ambient temperature. Prior to this work, this material has not produced high‐efficiency devices on tin oxide‐coated soda‐lime‐glass substrates used industrially. Numerous devices were fabricated over a variety of process conditions to produce an optimized device. Although the material does not show a consistent increase in band gap with oxygenation, absorption in this layer can be virtually eliminated over the relevant spectrum, leading to an increase in short‐circuit current. Meanwhile, fill factor is maintained, and open‐circuit voltage increases relative to baseline devices with sublimated CdS. The trend of device parameters with oxygenation and thickness is consistent with an increasing conduction band offset at the window/CdTe interface. Optimization considering both initial efficiency and stability resulted in a National Renewable Energy Laboratory verified 15.2%‐efficient cell on 3.2‐mm soda‐lime glass. This window material was shown to be compatible with SnO ₂ ‐based transparent conducting oxide and high resistance transparent coated substrates using in‐line compatible processes. Copyright © 2015 John Wiley & Sons, Ltd

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Sponsoring Organization:: USDOE

OSTI ID:: 1401119

Journal Information:: Progress in Photovoltaics, Journal Name: Progress in Photovoltaics Journal Issue: 11 Vol. 23; ISSN 1062-7995

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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