Controllable Synthesis of Ultrathin Transition‐Metal Hydroxide Nanosheets and their Extended Composite Nanostructures for Enhanced Catalytic Activity in the Heck Reaction

Fan, Hua; Huang, Xing; Shang, Lu; Cao, Yitao; Zhao, Yufei; Wu, Li‐Zhu; Tung, Chen‐Ho; Yin, Yadong; Zhang, Tierui

doi:10.1002/anie.201508939

Controllable Synthesis of Ultrathin Transition‐Metal Hydroxide Nanosheets and their Extended Composite Nanostructures for Enhanced Catalytic Activity in the Heck Reaction

Journal Article · Thu Dec 03 00:00:00 EST 2015 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201508939· OSTI ID:1400944

Fan, Hua ^[1]; Huang, Xing ^[2]; Shang, Lu ^[2]; Cao, Yitao ^[1]; Zhao, Yufei ^[2]; Wu, Li‐Zhu ^[2]; Tung, Chen‐Ho ^[2]; Yin, Yadong ^[3]; Zhang, Tierui ^[2]

Key Laboratory of Photochemical Conversion and Optoelectronic Materials Technical Institute of Physics and Chemistry Chinese Academy of Sciences Beijing 100190 P.R. China, University of Chinese Academy of Sciences Beijing 100049 P.R. China
Key Laboratory of Photochemical Conversion and Optoelectronic Materials Technical Institute of Physics and Chemistry Chinese Academy of Sciences Beijing 100190 P.R. China
Department of Chemistry University of California Riverside CA 92521 USA

Abstract

We report an effective and universal approach for the preparation of ultrathin single‐ or multiple‐component transition‐metal hydroxide (TMH) nanosheets with thickness below 5 nm. The unique synthesis benefits from the gradual decomposition of the preformed metal–boron (M‐B, M=Fe, Co, Ni, NiCo) composite nanospheres which facilitates the formation of ultrathin nanosheets by the oxidation of the metal and the simultaneous release of boron species. The high specific surface area of the sheets associated with their ultrathin nature promises a wide range of applications. For example, we demonstrate the remarkable adsorption ability of Pb ^II and As ^V in waste water by the ultrathin FeOOH nanosheets. More interestingly, the process can be extended simply to the synthesis of composite structures of metal alloy hollow shells encapsulated by TMH nanosheets, which show excellent catalytic activity in the Heck reaction.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0002247

OSTI ID:: 1400944

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 6 Vol. 55; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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