Flash sintering of a three‐phase alumina, spinel, and yttria‐stabilized zirconia composite
- Department of Chemical Engineering and Material Science University of California Irvine California
- Department of Mechanical Engineering University of Colorado at Boulder Boulder Colorado
Abstract Three‐phase ceramic composites constituted from equal volume fractions of α‐Al 2 O 3 , MgAl 2 O 4 spinel, and cubic 8 mol% Y 2 O 3 ‐stabilized ZrO 2 (8 YSZ ) were flash‐sintered under the influence of DC electric fields. The temperature for the onset of rapid densification (flash sintering) was measured using a constant heating rate at fields of 50‐500 V/cm. The experiments were carried out by heating the furnace at a constant rate. Flash sintering occurred at a furnace temperature of 1350°C at a field of 100 V/cm, which dropped to 1150°C at a field of 500 V/cm. The sintered densities ranged from 90% to 96%. Higher electric fields inhibited grain growth due to the lowering of the flash temperature and an accelerated sintering rate. During flash sintering, alumina reacted with the spinel phase to form a high‐alumina spinel solid solution, identified by electron dispersive spectroscopy and from a decrease in the spinel lattice parameter as measured by X‐ray diffraction. It is proposed that the solid solution reaction was promoted by a combination of electrical field and Joule heating.
- Sponsoring Organization:
- USDOE
- Grant/Contract Number:
- DE‐NE0000711
- OSTI ID:
- 1400834
- Journal Information:
- Journal of the American Ceramic Society, Journal Name: Journal of the American Ceramic Society Vol. 100 Journal Issue: 7; ISSN 0002-7820
- Publisher:
- Wiley-BlackwellCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Web of Science
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