Tuning Optical Properties of Encapsulated Clusters of Gold Nanoparticles through Stimuli‐Triggered Controlled Aggregation

Dergunov, Sergey A.; Kim, Mariya D.; Shmakov, Sergey N.; Richter, Andrew G.; Weigand, Steven; Pinkhassik, Eugene

doi:10.1002/chem.201601072

Title: Tuning Optical Properties of Encapsulated Clusters of Gold Nanoparticles through Stimuli‐Triggered Controlled Aggregation

Journal Article · Mon May 09 00:00:00 EDT 2016 · Chemistry - A European Journal

DOI:https://doi.org/10.1002/chem.201601072· OSTI ID:1400756

^[1]; Kim, Mariya D. ^[1];

^[1]; Richter, Andrew G. ^[2]; Weigand, Steven ^[3];

^[1]

Department of Chemistry University of Connecticut 55 North Eagleville Road Storrs 06269 CT USA
Department of Physics and Astronomy Valparaiso University Valparaiso IN 46383 USA
DND-CAT Advanced Photon Source, ANL Bldg. 432 9700 S. Cass Ave. Argonne Illinois 60439 USA

Abstract Gold nanoparticles entrapped in the hollow polymer nanocapsules undergo pH‐mediated controlled aggregation. Encapsulated clusters of nanoparticles show absorbance at higher wavelengths compared with individual nanoparticles. The size of the aggregates is controlled by the number of nanoparticles entrapped in individual nanocapsules. Such controlled aggregation may permit small biocompatible nanoparticles exhibit desirable properties for biomedical applications that are typically characteristic of large nanoparticles.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1400756

Journal Information:: Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Vol. 22 Journal Issue: 23; ISSN 0947-6539

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

Citation Metrics:

Cited by: 4 works

Citation information provided by
Web of Science

References (37)

Magnetic nanoparticles for drug delivery Arruebo, Manuel; Fernández-Pacheco, Rodrigo; Ibarra, M. Ricardo Nano Today, Vol. 2, Issue 3 https://doi.org/10.1016/S1748-0132(07)70084-1	journal	June 2007
In vivo toxicity, biodistribution, and clearance of glutathione-coated gold nanoparticles Simpson, Carrie A.; Salleng, Kenneth J.; Cliffel, David E. Nanomedicine: Nanotechnology, Biology and Medicine, Vol. 9, Issue 2 https://doi.org/10.1016/j.nano.2012.06.002	journal	February 2013
Size-Selective Yolk-Shell Nanoreactors with Nanometer-Thin Porous Polymer Shells Jia, Ying; Shmakov, Sergey N.; Register, Paul Chemistry - A European Journal, Vol. 21, Issue 36 https://doi.org/10.1002/chem.201501968	journal	July 2015
Synthesis, Characterization, and Long-Term Stability of Hollow Polymer Nanocapsules with Nanometer-Thin Walls Dergunov, Sergey A.; Kesterson, Katrina; Li, Wei Macromolecules, Vol. 43, Issue 18 https://doi.org/10.1021/ma1012418	journal	September 2010
Dimers of Silver Nanospheres: Facile Synthesis and Their Use as Hot Spots for Surface-Enhanced Raman Scattering Li, Weiyang; Camargo, Pedro H. C.; Lu, Xianmao Nano Letters, Vol. 9, Issue 1 https://doi.org/10.1021/nl803621x	journal	January 2009
Fluorescence Lifetime Measurements and Biological Imaging Berezin, Mikhail Y.; Achilefu, Samuel Chemical Reviews, Vol. 110, Issue 5 https://doi.org/10.1021/cr900343z	journal	May 2010
PEGylation and Zwitterionization: Pros and Cons in the Renal Clearance and Tumor Targeting of Near-IR-Emitting Gold Nanoparticles Liu, Jinbin; Yu, Mengxiao; Ning, Xuhui Angewandte Chemie International Edition, Vol. 52, Issue 48 https://doi.org/10.1002/anie.201304465	journal	October 2013
Facile Directed Assembly of Hollow Polymer Nanocapsules within Spontaneously Formed Catanionic Surfactant Vesicles Kim, Mariya D.; Dergunov, Sergey A.; Richter, Andrew G. Langmuir, Vol. 30, Issue 24 https://doi.org/10.1021/la404026w	journal	January 2014
Simultaneous templating of polymer nanocapsules and entrapped silver nanoparticles Shmakov, Sergey N.; Pinkhassik, Eugene Chemical Communications, Vol. 46, Issue 39 https://doi.org/10.1039/c0cc01988g	journal	January 2010
Gold nanoparticles as computerized tomography (CT) contrast agents Xi, Da; Dong, Sheng; Meng, Xiaoxi RSC Advances, Vol. 2, Issue 33 https://doi.org/10.1039/c2ra21263c	journal	January 2012
In vivo tumor targeting and spectroscopic detection with surface-enhanced Raman nanoparticle tags Qian, Ximei; Peng, Xiang-Hong; Ansari, Dominic O. Nature Biotechnology, Vol. 26, Issue 1 https://doi.org/10.1038/nbt1377	journal	December 2007
Functionalization of Imprinted Nanopores in Nanometer-Thin Organic Materials Dergunov, Sergey A.; Pinkhassik, Eugene Angewandte Chemie, Vol. 120, Issue 43 https://doi.org/10.1002/ange.200803261	journal	October 2008
Gold Nanoparticles in Chemical and Biological Sensing Saha, Krishnendu; Agasti, Sarit S.; Kim, Chaekyu Chemical Reviews, Vol. 112, Issue 5 https://doi.org/10.1021/cr2001178	journal	February 2012
Functionalization of hollow nanoparticles for nanoreactor applications Lee, Jihwan; Kim, Soo Min; Lee, In Su Nano Today, Vol. 9, Issue 5 https://doi.org/10.1016/j.nantod.2014.09.003	journal	October 2014
Role of Hydrogen Bonding in the pH-Dependent Aggregation of Colloidal Gold Particles Bearing Solution-Facing Carboxylic Acid Groups Preston, Thomas C.; Nuruzzaman, Mohammad; Jones, Nathan D. The Journal of Physical Chemistry C, Vol. 113, Issue 32 https://doi.org/10.1021/jp903284h	journal	July 2009
Directed Assembly of Vesicle-Templated Polymer Nanocapsules under Near-Physiological Conditions Kim, Mariya D.; Dergunov, Sergey A.; Pinkhassik, Eugene Langmuir, Vol. 31, Issue 8 https://doi.org/10.1021/la5046095	journal	January 2015
Synergistic self-assembly of scaffolds and building blocks for directed synthesis of organic nanomaterials Dergunov, Sergey A.; Richter, Andrew G.; Kim, Mariya D. Chemical Communications, Vol. 49, Issue 94 https://doi.org/10.1039/c3cc45847d	journal	January 2013
New Strategies for Fluorescent Probe Design in Medical Diagnostic Imaging Kobayashi, Hisataka; Ogawa, Mikako; Alford, Raphael Chemical Reviews, Vol. 110, Issue 5 https://doi.org/10.1021/cr900263j	journal	May 2010
Selectively Initiated Ship-In-A-Bottle Assembly of Yolk–Shell Nanostructures Shmakov, Sergey N.; Jia, Ying; Pinkhassik, Eugene Chemistry of Materials, Vol. 26, Issue 2 https://doi.org/10.1021/cm403442k	journal	December 2013
Phagocytosis Independent Extracellular Nanoparticle Clearance by Human Immune Cells Bartneck, Matthias; Keul, Heidrun A.; Zwadlo-Klarwasser, Gabriele Nano Letters, Vol. 10, Issue 1 https://doi.org/10.1021/nl902830x	journal	January 2010
Gold nanoparticles: Optical properties and implementations in cancer diagnosis and photothermal therapy Huang, Xiaohua; El-Sayed, Mostafa A. Journal of Advanced Research, Vol. 1, Issue 1 https://doi.org/10.1016/j.jare.2010.02.002	journal	January 2010
Organization of 'nanocrystal molecules' using DNA Alivisatos, A. Paul; Johnsson, Kai P.; Peng, Xiaogang Nature, Vol. 382, Issue 6592 https://doi.org/10.1038/382609a0	journal	August 1996
Controlled Assembly of Biocompatible Metallic Nanoaggregates Using a Small Molecule Crosslinker Van Haute, Desiree; Longmate, Julia M.; Berlin, Jacob M. Advanced Materials, Vol. 27, Issue 35 https://doi.org/10.1002/adma.201501602	journal	July 2015
PEGylation and Zwitterionization: Pros and Cons in the Renal Clearance and Tumor Targeting of Near-IR-Emitting Gold Nanoparticles Liu, Jinbin; Yu, Mengxiao; Ning, Xuhui Angewandte Chemie, Vol. 125, Issue 48 https://doi.org/10.1002/ange.201304465	journal	October 2013
Functionalization of Imprinted Nanopores in Nanometer-Thin Organic Materials Dergunov, Sergey A.; Pinkhassik, Eugene Angewandte Chemie International Edition, Vol. 47, Issue 43 https://doi.org/10.1002/anie.200803261	journal	October 2008
Nanoparticle contrast agents for computed tomography: a focus on micelles: NANOPARTICLE CONTRAST AGENTS FOR CT Cormode, David P.; Naha, Pratap C.; Fayad, Zahi A. Contrast Media & Molecular Imaging, Vol. 9, Issue 1 https://doi.org/10.1002/cmmi.1551	journal	January 2014
The biodistribution of gold nanoparticles designed for renal clearance Alric, Christophe; Miladi, Imen; Kryza, David Nanoscale, Vol. 5, Issue 13 https://doi.org/10.1039/c3nr00012e	journal	January 2013
Unique Gold Nanoparticle Aggregates as a Highly Active Surface-Enhanced Raman Scattering Substrate Schwartzberg, Adam M.; Grant, Christian D.; Wolcott, Abraham The Journal of Physical Chemistry B, Vol. 108, Issue 50 https://doi.org/10.1021/jp048430p	journal	December 2004
Nanocapsules with “invisible” walls Dergunov, Sergey A.; Miksa, Beata; Ganus, Bill Chemical Communications, Vol. 46, Issue 9 https://doi.org/10.1039/b918845b	journal	January 2010
Size-dependent clearance of gold nanoparticles from lungs of Sprague–Dawley rats after short-term inhalation exposure Han, Sung Gu; Lee, Jong Seong; Ahn, Kangho Archives of Toxicology, Vol. 89, Issue 7 https://doi.org/10.1007/s00204-014-1292-9	journal	June 2014
Formation of Spherical Nanostructures by the Controlled Aggregation of Gold Colloids Hussain, Irshad; Wang, Zhenxin; Cooper, Andrew I. Langmuir, Vol. 22, Issue 7 https://doi.org/10.1021/la053126o	journal	March 2006
pH-Induced Aggregation of Gold Nanoparticles for Photothermal Cancer Therapy Nam, Jutaek; Won, Nayoun; Jin, Ho Journal of the American Chemical Society, Vol. 131, Issue 38 https://doi.org/10.1021/ja902062j	journal	September 2009
Structure−Activity Relationships in Gold Nanoparticle Dimers and Trimers for Surface-Enhanced Raman Spectroscopy Wustholz, Kristin L.; Henry, Anne-Isabelle; McMahon, Jeffrey M. Journal of the American Chemical Society, Vol. 132, Issue 31 https://doi.org/10.1021/ja104174m	journal	July 2010
Reversible Controlled Assembly of Thermosensitive Polymer-Coated Gold Nanoparticles Durand-Gasselin, Céline; Sanson, Nicolas; Lequeux, Nicolas Langmuir, Vol. 27, Issue 20 https://doi.org/10.1021/la2023852	journal	October 2011
A DNA-based method for rationally assembling nanoparticles into macroscopic materials Mirkin, Chad A.; Letsinger, Robert L.; Mucic, Robert C. Nature, Vol. 382, Issue 6592, p. 607-609 https://doi.org/10.1038/382607a0	journal	August 1996
Safety profile and cellular uptake of biotemplated nanocapsules with nanometre-thin walls Zhou, Qunfang; Dergunov, Sergey A.; Zhang, Yi Nanoscale, Vol. 3, Issue 6 https://doi.org/10.1039/c1nr10311c	journal	January 2011
Gold and Silver Nanoparticles in Sensing and Imaging: Sensitivity of Plasmon Response to Size, Shape, and Metal Composition Lee, Kyeong-Seok; El-Sayed, Mostafa A. The Journal of Physical Chemistry B, Vol. 110, Issue 39 https://doi.org/10.1021/jp062536y	journal	October 2006

Similar Records

Tuning Optical Properties of Encapsulated Clusters of Gold Nanoparticles through Stimuli-Triggered Controlled Aggregation

Journal Article · Mon May 09 00:00:00 EDT 2016 · Chemistry - A European Journal · OSTI ID:1400756

Dergunov, Sergey A.; Kim, Mariya D.; Shmakov, Sergey N.; +3 more

Solvent-mediated plasmon-tuning in a gold nanoparticle-poly(ionic liquid) composite.

Journal Article · Tue May 01 00:00:00 EDT 2007 · Adv. Functional Mater. · OSTI ID:1400756

Batra, D; Seifert, S; Varela, L; +1 more

Multi-stimuli responsive tetra-PPO₆₀-PEO₂₀ ethylene diamine block copolymer enables pH, temperature, and solvent regulation of Au nanoparticle composite plasmonic response

Journal Article · Mon Nov 04 00:00:00 EST 2019 · Polymer Chemistry · OSTI ID:1400756

Diouf, Sokhna Issa-Yacine Faye; Williams, Darrick Joseph; Seifert, Sönke; +4 more

Title: Tuning Optical Properties of Encapsulated Clusters of Gold Nanoparticles through Stimuli‐Triggered Controlled Aggregation

Citation Formats

References (37)

Similar Records

Related Subjects