Ordered PdCu‐Based Nanoparticles as Bifunctional Oxygen‐Reduction and Ethanol‐Oxidation Electrocatalysts

Jiang, Kezhu; Wang, Pengtang; Guo, Shaojun; Zhang, Xu; Shen, Xuan; Lu, Gang; Su, Dong; Huang, Xiaoqing

doi:10.1002/ange.201603022

Title: Ordered PdCu‐Based Nanoparticles as Bifunctional Oxygen‐Reduction and Ethanol‐Oxidation Electrocatalysts

Journal Article · Thu Jun 02 00:00:00 EDT 2016 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201603022· OSTI ID:1400560

Jiang, Kezhu ^[1]; Wang, Pengtang ^[1];

^[2]; Zhang, Xu ^[3]; Shen, Xuan ^[4]; Lu, Gang ^[3]; Su, Dong ^[4]; Huang, Xiaoqing ^[1]

College of Chemistry, Chemical Engineering and Materials Science Soochow University Jiangsu 215123 China
Department of Materials Science &, Engineering, College of Engineering Peking University Beijing 100871 China
Department of Physics and Astronomy California State University Northridge CA USA
Center for Functional Nanomaterials Brookhaven National Laboratory Upton NY 11973 USA

Abstract The development of superior non‐platinum electrocatalysts for enhancing the electrocatalytic activity and stability for the oxygen‐reduction reaction (ORR) and liquid fuel oxidation reaction is very important for the commercialization of fuel cells, but still a great challenge. Herein, we demonstrate a new colloidal chemistry technique for making structurally ordered PdCu‐based nanoparticles (NPs) with composition control from PdCu to PdCuNi and PtCuCo. Under the dual tuning on the composition and intermetallic phase, the ordered PdCuCo NPs exhibit better activity and much enhanced stability for ORR and ethanol‐oxidation reaction (EOR) than those of disordered PdCuM NPs, the commercial Pt/C and Pd/C catalysts. The density functional theory (DFT) calculations reveal that the improved ORR activity on the PdCuM NPs stems from the catalytically active hollow sites arising from the ligand effect and the compressive strain on the Pd surface owing to the smaller atomic size of Cu, Co, and Ni.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0012704

OSTI ID:: 1400560

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 128 Journal Issue: 31; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (35)

Structurally ordered intermetallic platinum–cobalt core–shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts Wang, Deli; Xin, Huolin L.; Hovden, Robert Nature Materials, Vol. 12, Issue 1, p. 81-87 https://doi.org/10.1038/nmat3458	journal	October 2012
Newly Developed Stepwise Electroless Deposition Enables a Remarkably Facile Synthesis of Highly Active and Stable Amorphous Pd Nanoparticle Electrocatalysts for Oxygen Reduction Reaction Poon, Kee Chun; Tan, Desmond C. L.; Vo, Thang D. T. Journal of the American Chemical Society, Vol. 136, Issue 14 https://doi.org/10.1021/ja500275r	journal	February 2014
A Seed-Based Diffusion Route to Monodisperse Intermetallic CuAu Nanocrystals Chen, Wei; Yu, Rong; Li, Lingling Angewandte Chemie International Edition, Vol. 49, Issue 16 https://doi.org/10.1002/anie.200906835	journal	March 2010
Changing the Activity of Electrocatalysts for Oxygen Reduction by Tuning the Surface Electronic Structure Stamenkovic, Vojislav; Mun, Bongjin Simon; Mayrhofer, Karl J. J. Angewandte Chemie International Edition, Vol. 45, Issue 18 https://doi.org/10.1002/anie.200504386	journal	April 2006
Materials for fuel-cell technologies Steele, Brian C. H.; Heinzel, Angelika Nature, Vol. 414, Issue 6861, p. 345-352 https://doi.org/10.1038/35104620	journal	November 2001
Nanocrystalline intermetallics on mesoporous carbon for direct formic acid fuel cell anodes Ji, Xiulei; Lee, Kyu Tae; Holden, Reanne Nature Chemistry, Vol. 2, Issue 4, p. 286-293 https://doi.org/10.1038/nchem.553	journal	February 2010
Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs Gasteiger, Hubert A.; Kocha, Shyam S.; Sompalli, Bhaskar Applied Catalysis B: Environmental, Vol. 56, Issue 1-2, p. 9-35 https://doi.org/10.1016/j.apcatb.2004.06.021	journal	March 2005
Pt-based nanoarchitecture and catalyst design for fuel cell applications Jung, Namgee; Chung, Dong Young; Ryu, Jaeyune Nano Today, Vol. 9, Issue 4 https://doi.org/10.1016/j.nantod.2014.06.006	journal	August 2014
Enhanced Cycling Stability of Hybrid Li–Air Batteries Enabled by Ordered Pd ₃ Fe Intermetallic Electrocatalyst Cui, Zhiming; Li, Longjun; Manthiram, Arumugam Journal of the American Chemical Society, Vol. 137, Issue 23 https://doi.org/10.1021/jacs.5b03865	journal	June 2015
Catalysts by Platonic design Strasser, P. Science, Vol. 349, Issue 6246 https://doi.org/10.1126/science.aac7861	journal	July 2015
Bioinspired copper catalyst effective for both reduction and evolution of oxygen Wang, Jiong; Wang, Kang; Wang, Feng-Bin Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6285	journal	October 2014
Gold-promoted structurally ordered intermetallic palladium cobalt nanoparticles for the oxygen reduction reaction Kuttiyiel, Kurian A.; Sasaki, Kotaro; Su, Dong Nature Communications, Vol. 5, Article No. 5185 https://doi.org/10.1038/ncomms6185	journal	November 2014
Strongly Coupled Pd Nanotetrahedron/Tungsten Oxide Nanosheet Hybrids with Enhanced Catalytic Activity and Stability as Oxygen Reduction Electrocatalysts Lu, Yizhong; Jiang, Yuanyuan; Gao, Xiaohui Journal of the American Chemical Society, Vol. 136, Issue 33 https://doi.org/10.1021/ja5041094	journal	August 2014
Nanocatalyst Superior to Pt for Oxygen Reduction Reactions: The Case of Core/Shell Ag(Au)/CuPd Nanoparticles Guo, Shaojun; Zhang, Xu; Zhu, Wenlei Journal of the American Chemical Society, Vol. 136, Issue 42 https://doi.org/10.1021/ja508256g	journal	October 2014
Changing the Activity of Electrocatalysts for Oxygen Reduction by Tuning the Surface Electronic Structure Stamenkovic, Vojislav; Mun, Bongjin Simon; Mayrhofer, Karl J. J. Angewandte Chemie, Vol. 118, Issue 18 https://doi.org/10.1002/ange.200504386	journal	April 2006
Platinum-Based Oxygen Reduction Electrocatalysts Wu, Jianbo; Yang, Hong Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar300359w	journal	April 2013
Palladium-Based Electrocatalysts for Alcohol Oxidation in Half Cells and in Direct Alcohol Fuel Cells Bianchini, Claudio; Shen, Pei Kang Chemical Reviews, Vol. 109, Issue 9 https://doi.org/10.1021/cr9000995	journal	September 2009
Boosting Oxygen Reduction Reaction Activity of Palladium by Stabilizing Its Unusual Oxidation States in Perovskite Zhu, Yinlong; Zhou, Wei; Chen, Yubo Chemistry of Materials, Vol. 27, Issue 8 https://doi.org/10.1021/acs.chemmater.5b00450	journal	April 2015
Electrocatalyst approaches and challenges for automotive fuel cells Debe, Mark K. Nature, Vol. 486, Issue 7401 https://doi.org/10.1038/nature11115	journal	June 2012
Just a Dream—or Future Reality? Gasteiger, Hubert A.; Marković, Nenad M Science, Vol. 324, Issue 5923, p. 48-49 https://doi.org/10.1126/science.1172083	journal	April 2009
Design of Pd/PANI/Pd Sandwich-Structured Nanotube Array Catalysts with Special Shape Effects and Synergistic Effects for Ethanol Electrooxidation Wang, An-Liang; Xu, Han; Feng, Jin-Xian Journal of the American Chemical Society, Vol. 135, Issue 29 https://doi.org/10.1021/ja403101r	journal	July 2013
Five-Fold Twinned Pd ₂ NiAg Nanocrystals with Increased Surface Ni Site Availability to Improve Oxygen Reduction Activity Liu, Suli; Zhang, Qinghua; Li, Yafei Journal of the American Chemical Society, Vol. 137, Issue 8 https://doi.org/10.1021/ja5129154	journal	February 2015
Crystal phase-controlled synthesis, properties and applications of noble metal nanomaterials Fan, Zhanxi; Zhang, Hua Chemical Society Reviews, Vol. 45, Issue 1 https://doi.org/10.1039/C5CS00467E	journal	January 2016
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode Nørskov, J. K.; Rossmeisl, J.; Logadottir, A. The Journal of Physical Chemistry B, Vol. 108, Issue 46 https://doi.org/10.1021/jp047349j	journal	November 2004
A Seed-Based Diffusion Route to Monodisperse Intermetallic CuAu Nanocrystals Chen, Wei; Yu, Rong; Li, Lingling Angewandte Chemie, Vol. 122, Issue 16 https://doi.org/10.1002/ange.200906835	journal	March 2010
Review of Pt-Based Bimetallic Catalysis: From Model Surfaces to Supported Catalysts Yu, Weiting; Porosoff, Marc D.; Chen, Jingguang G. Chemical Reviews, Vol. 112, Issue 11, p. 5780-5817 https://doi.org/10.1021/cr300096b	journal	August 2012
Newly-Designed Complex Ternary Pt/PdCu Nanoboxes Anchored on Three-Dimensional Graphene Framework for Highly Efficient Ethanol Oxidation Hu, Chuangang; Cheng, Huhu; Zhao, Yang Advanced Materials, Vol. 24, Issue 40 https://doi.org/10.1002/adma.201200498	journal	August 2012
A metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions Zhang, Jintao; Zhao, Zhenghang; Xia, Zhenhai Nature Nanotechnology, Vol. 10, Issue 5 https://doi.org/10.1038/nnano.2015.48	journal	April 2015
Palladium-Based Nanomaterials: Synthesis and Electrochemical Applications Chen, Aicheng; Ostrom, Cassandra Chemical Reviews, Vol. 115, Issue 21 https://doi.org/10.1021/acs.chemrev.5b00324	journal	September 2015
Freestanding palladium nanosheets with plasmonic and catalytic properties Huang, Xiaoqing; Tang, Shaoheng; Mu, Xiaoliang Nature Nanotechnology, Vol. 6, Issue 1 https://doi.org/10.1038/nnano.2010.235	journal	December 2010
Small palladium islands embedded in palladium–tungsten bimetallic nanoparticles form catalytic hotspots for oxygen reduction Hu, Guangzhi; Nitze, Florian; Gracia-Espino, Eduardo Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6253	journal	October 2014
Platinum-based nanocages with subnanometer-thick walls and well-defined, controllable facets Zhang, L.; Roling, L. T.; Wang, X. Science, Vol. 349, Issue 6246 https://doi.org/10.1126/science.aab0801	journal	July 2015
Alloys of platinum and early transition metals as oxygen reduction electrocatalysts Greeley, J.; Stephens, I. E. L.; Bondarenko, A. S. Nature Chemistry, Vol. 1, Issue 7, p. 552-556 https://doi.org/10.1038/nchem.367	journal	September 2009
An oxygen reduction electrocatalyst based on carbon nanotube–graphene complexes Li, Yanguang; Zhou, Wu; Wang, Hailiang Nature Nanotechnology, Vol. 7, Issue 6 https://doi.org/10.1038/nnano.2012.72	journal	May 2012
Thin metal nanostructures: synthesis, properties and applications Fan, Zhanxi; Huang, Xiao; Tan, Chaoliang Chemical Science, Vol. 6, Issue 1 https://doi.org/10.1039/C4SC02571G	journal	January 2015

Similar Records

Ordered PdCu-Based Nanoparticles as Bifunctional Oxygen-Reduction and Ethanol-Oxidation Electrocatalysts

Journal Article · Thu Jun 02 00:00:00 EDT 2016 · Angewandte Chemie (International Edition) · OSTI ID:1400560

Jiang, Kezhu; Wang, Pengtang; Guo, Shaojun; +5 more

PdCu Nanoalloy Electrocatalysts in Oxygen Reduction Reaction: Role of Composition and Phase State in Catalytic Synergy

Journal Article · Mon Nov 16 00:00:00 EST 2015 · ACS Applied Materials and Interfaces · OSTI ID:1400560

Wu, Jinfang; Shan, Shiyao; Luo, Jin; +3 more

Building Durable Multimetallic Electrocatalysts from Intermetallic Seeds

Journal Article · Wed Dec 30 00:00:00 EST 2020 · Accounts of Chemical Research · OSTI ID:1400560

Bueno, Sandra A.; Ashberry, Hannah M.; Shafei, Ibrahim; +1 more

Title: Ordered PdCu‐Based Nanoparticles as Bifunctional Oxygen‐Reduction and Ethanol‐Oxidation Electrocatalysts

Citation Formats

References (35)

Similar Records

Related Subjects