Crosslinked poly(ethylene oxide) containing siloxanes fabricated through thiol‐ene photochemistry

Kusuma, Victor A.; Roth, Elliot A.; Clafshenkel, William P.; Klara, Steven S.; Zhou, Xu; Venna, Surendar R.; Albenze, Erik; Luebke, David R.; Mauter, Meagan S.; Koepsel, Richard R.; Russell, Alan J.; Hopkinson, David; Nulwala, Hunaid B.

doi:10.1002/pola.27594

Crosslinked poly(ethylene oxide) containing siloxanes fabricated through thiol‐ene photochemistry

Journal Article · Mon Mar 16 00:00:00 EDT 2015 · Journal of Polymer Science. Part A, Polymer Chemistry

DOI:https://doi.org/10.1002/pola.27594· OSTI ID:1400510

Kusuma, Victor A. ^[1]; Roth, Elliot A. ^[1]; Clafshenkel, William P. ^[2]; Klara, Steven S. ^[3]; Zhou, Xu ^[1]; Venna, Surendar R. ^[1]; Albenze, Erik ^[1]; Luebke, David R. ^[1]; Mauter, Meagan S. ^[3]; Koepsel, Richard R. ^[2]; Russell, Alan J. ^[2]; Hopkinson, David ^[1]; Nulwala, Hunaid B. ^[4]

U.S. Department of Energy, National Energy Technology Laboratory 626 Cochrans Mill Rd. Pittsburgh Pennsylvania 15236
Institute for Complex Engineered Systems Carnegie Mellon University 4400 Fifth Avenue Pittsburgh Pennsylvania 15213
Department of Chemical Engineering Carnegie Mellon University 5000 Forbes Avenue Pittsburgh Pennsylvania 15213
U.S. Department of Energy, National Energy Technology Laboratory 626 Cochrans Mill Rd. Pittsburgh Pennsylvania 15236, Department of Chemistry Carnegie Mellon University 4400 Fifth Avenue Pittsburgh Pennsylvania 15213

ABSTRACT

Homogenous amphiphilic crosslinked polymer films comprising of poly(ethylene oxide) and polysiloxane were synthesized utilizing thiol‐ene “ click ” photochemistry. A systematic variation in polymer composition was Carried out to obtain high quality films with varied amount of siloxane and poly(ethylene oxide). These films showed improved gas separation performance with high gas permeabilities with good CO ₂ /N ₂ selectivity. Furthermore, the resulting films were also tested for its biocompatibility, as a carrier media which allow human adult mesenchymal stem cells to retain their capacity for osteoblastic differentiation after transplantation. The obtained crosslinked films were characterized using differential scanning calorimetry, dynamic mechanical analysis, thermogravimetric analysis, FTIR, Raman‐IR , and small angle X‐ray scattering. The synthesis ease and commercial availability of the starting materials suggests that these new crosslinked polymer networks could find applications in wide range of applications. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53 , 1548–1557

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

OSTI ID:: 1400510

Alternate ID(s):: OSTI ID: 1221810

Journal Information:: Journal of Polymer Science. Part A, Polymer Chemistry, Journal Name: Journal of Polymer Science. Part A, Polymer Chemistry Journal Issue: 13 Vol. 53; ISSN 0887-624X

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: United States

Language:: English

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